安全ヅヺソサヺテ（ SDS

1 ITW PP F Japan Co., Ltd. 1 / 7 page SDS A . SDS . A . : 2014-09-24 : 2015-7-16 : 1.. A.. - A . B.. - : . - : . C. / / .. - / : ITW Polymers Adhesives, North America - : 30 Endicott Street, Danvers, MA 01933. / . - / : ITW . - : 564-0053 30-32. - : . - : 06-6330-7118. - FAX : 06-6330-7083. 2.. A. GHS . - / : 2. - : 1. - : 2. - : 3 . B.. - .. - H315 . - H317 . - H319 . - H335 .. 1) . - P261 / / / / / . - P264 . - P272 . - P280 / / / . 2) . - P302+P352 . - P321 . - P332+P313 / . - P333+P313 / . - P362 . - P363 . 3) . - . 4) . ITW PP F Japan Co., Ltd. 2 / 7 page SDS A . - P501 / / . C.. NFPA 0 4 . - : 2, : 0, : 0. 3.. - . - . CAS No. PRTR (%). Iron wire 7439-89-6 50-60. A - 25068-38-6 20-30. Silicon, Elemental 7440-21-3 10-20. - 1-10. Titanium fulleride (TiC20) 7440-32-6 1-10. *GHS . 4.. A.. - . - 15 . B.. - . C.. - . - . D.. - . - . E. / . - . F.. - . 5.. A.. - . B.. - . C.. - . D.. - .. E.. - . 6.. A.

2 - . ITW PP F Japan Co., Ltd. 3 / 7 page SDS A . - . - . B.. - . - 119 . C.. - . - . - . - . 7.. A.. - . B.. - . - . 8.. A.. - . ACGIH . - . B.. - .. C.. - .. - .. - .. - .. - . 9.. A.. - . - . B.. C.. D. pH 5% . E. / . F. >260 . G. > . H. <<1 =1 . I.. J. / . K.. L.. M. >1 =1 . N. ITW PP F Japan Co., Ltd. 4 / 7 page SDS A . O. / n- . P.. Q.. R.. S.. 10.. A.. - . B.. - . C.. - 148 .. D.. - . E.. - CO . 11.. A.. ( ). - . ( ). - . ( ). - . - . B.. * . - [Silicon] : LD50 3160 mg/kg bw IUCLID 2000 JIS . 5 . - [4,4'-(1-methylethylidene)bisphenol polymer with (chloromethyl)oxirane] : LD50 1,000. mg/kg 11,400 mg/kg 13,600 mg/kg ( CERI 2001-36 (2002)) . LD50 11,400 mg/kg . - [Titanium] : LD50 . 10000mg/kg IUCLID, 2000) (1982) . LD50 12g/kg . * . - [4,4'-(1-methylethylidene)bisphenol polymer with (chloromethyl)oxirane] : LD50 1,600. mg/kg (CERI 2001-36 (2002)) 4 .. - [Titanium] : . LD50 10000mg/kg IUCLID, 2000) . *.

3 - [Titanium] : LC . 4 IUCLID, 2000) . / . - [Iron] : . - [4,4'-(1-methylethylidene)bisphenol polymer with (chloromethyl)oxirane] : CERI 2001-36 (2002) . (2003) . 4 2 . - [Silicon] : . - [Titanium] : . IUCLID, 2000) .. - [Silicon] : Slightly irritating IUCLID 2000 2B . ITW PP F Japan Co., Ltd. 5 / 7 page SDS A . - [4,4'-(1-methylethylidene)bisphenol polymer with (chloromethyl)oxirane] : CERI 2001-36 (2002) .. 2B . - [Titanium] : . IUCLID, 2000) 2B .. - [4,4'-(1-methylethylidene)bisphenol polymer with (chloromethyl)oxirane] : . CERI 2001-36 (2002) (2003) .. 1 . - [Titanium] : . IUCLID, 2000).. - [Silicon] : .. * IARC. - . * OSHA. - . * ACGIH. - . * NTP. - . * EU CLP. - .. - [4,4'-(1-methylethylidene)bisphenol polymer with (chloromethyl)oxirane] : DFGOT (2003) . ( ) in vivo ( ) in vivo . ( ) . - [Titanium] : HSDB(2003) .. TA98 TA100 WP2uvrA DNA .. NTP DB, 2005) .. - [4,4'-(1-methylethylidene)bisphenol polymer with (chloromethyl)oxirane] : PATTY (4th, 2000) DFGOT (2003).

4 - [Titanium] : (1982) . 5mgTi/L) .. - [Silicon] : 25 mg HSDB 2009 .. - [4,4'-(1-methylethylidene)bisphenol polymer with (chloromethyl)oxirane] : . - [Titanium] : . HSDB, 2005) 3 .. - [Silicon] : 800 mg/kg/day 1 . HSDB 2009 .. - [Titanium] : 20 . X . DFGOT , 1991) 1 (1982) .. mgTi L .. - . 12.. A.. - .. ITW PP F Japan Co., Ltd. 6 / 7 page SDS A . - [4,4'-(1-methylethylidene)bisphenol polymer with (chloromethyl)oxirane] : 48 EC50= . - . B.. - .. - . C.. - .. - . D.. - . E.. - . F.. - [4,4'-(1-methylethylidene)bisphenol polymer with (chloromethyl)oxirane] : 1 BCF. 42 BOD 0% . 1 . 13.. A.. - . - . - . B.. - . 14.. A.. - . B.. - . C. ES . - . D.. - . E.. - . F.. - DOT . - : . - : . 15.. A.. - .. ITW PP F Japan Co., Ltd. 7 / 7 page SDS A . * . - A .. - 8 182 13 A . B.. - . EU . * . - [4,4'-(1-methylethylidene)bisphenol polymer with (chloromethyl)oxirane] : Xi; R36/38 R43 N; R51-53. * . - [4,4'-(1-methylethylidene)bisphenol polymer with (chloromethyl)oxirane] : R36/38, R43, R51/53.

5 * . - [4,4'-(1-methylethylidene)bisphenol polymer with (chloromethyl)oxirane] : S2, S28, S37/39, S61.. * OSHA . - . * CERCLA 103 ( ). - . * EPCRA 302 ( ). - . * EPCRA 304 ( ). - . * EPCRA 313 ( ). - .. - .. - .. - . 16.. A.. - SDS KOSHA NITE ESIS NLM SIDS IPCS . - . - .. - .. - . - GHS SDS JIS Z 7253. B.. - 2014-09-24. C.. - 2 times, 2015-7-16. D.. - DB . ITW Perforamnce Polymers Fluids Japan Co., Ltd. 1/7. SDS 0200. SDS . 0200. : 2014-09-24 : 2016-06-01 : 1.. A.. - 0200. B.. - : . - : . C. / / .. - / : ITW Polymers Adhesives, North America - : 30 Endicott Street, Danvers, MA 01933. / . - / : ITW . - : 564-0053 30-32. - : . - : 06-6330-7118. - FAX : 06-6330-7083. 2.. A. GHS . - / : 1. - : 1. - : 1. B.. - .. - H314 . - H317 . - H318 .. 1) . - P260 / / / / / . - P264 . - P272 . - P280 / / / . 2) . - P301+P330+P331 . - P302+P352 . - P303+P361+P353 / . / . - P304+P340 . - P305+P351+P338 .. - P310 . - P312 . - P321.

6 - P322 . ITW Perforamnce Polymers Fluids Japan Co., Ltd. 2/7. SDS 0200. - P333+P313 / . - P361 . - P363 . 3) . - P405 . 4) . - P501 / / . C.. NFPA 0 4 . - : 3, : 0, : 0. 3.. - . - . CAS No. PRTR (%). - 20-30. - - 10-20. 1,2-Ethanediamine, N1,N2-bis(2- 112-24-3 2-163 1 278 12. aminoethyl)- Titanium oxide (Tio2) 13463-67-7 1-558 30-40. Synthetic amorphous silica - 10-20. *GHS . 4.. A.. - . - 15 . - . B.. - . - . - . C.. - . - . D.. - . - . E. / . - . F.. - . 5.. A.. - . B.. - . C.. - . D.. - .. ITW Perforamnce Polymers Fluids Japan Co., Ltd. 3/7. SDS 0200. E.. - . 6.. A.. - . - . - . - . - . B.. - . - 119 . C.. - . - . - . - . 7.. A.. - . B.. - . - . - . - . 8.. A.. - . ACGIH . - [Titanium dioxide] : TWA 10 mg/m3. B.. - .. C.. - .. - .. - .. - .. - . 9.. A.. - . - . B.. ITW Perforamnce Polymers Fluids Japan Co., Ltd. 4/7. SDS 0200. C.. D. pH . E. / . F.. G. > . H. <1 =1 . I.. J. / . K.. L.. M. >1 =1 . N. O.

7 / n- . P.. Q.. R.. S.. 10.. A.. - . B.. - / .. C.. - . D.. - / .. E.. - . 11.. A.. ( ). - . ( ). - . ( ). - . - . - . B.. * . - [1,2-Ethanediamine, N,N'-bis(2-aminoethyl)-] : LD50 2500 2780 3750mg/kg SIDS(1998)) 4340mg/kg PATTY, 5th 2001 SIDS(1998)) JIS ( . - [Titanium dioxide] : LD50 20000mg/kg DFGOT(1991)) . * . - [1,2-Ethanediamine, N,N'-bis(2-aminoethyl)-] : LD50 550mg/kg(SIDS(1998)) 805mg/kg PATTY, 5th 2001 SIDS(1998)) . - [Titanium dioxide] : approxLD50 >10000mg/kg IUCLID (2000)) . * . - . / . - [1,2-Ethanediamine, N,N'-bis(2-aminoethyl)-] : . (SIDS(1998)) . - [Titanium dioxide] : 24 slightly irritating (IUCLID (2000)) . 24 not irritating (IUCLID (2000)) . ITW Perforamnce Polymers Fluids Japan Co., Ltd. 5/7. SDS 0200.. - [1,2-Ethanediamine, N,N'-bis(2-aminoethyl)-] : . (SIDS(1998)) (SIDS(1998)) . - [Titanium dioxide] : mild irritaton (IUCLID (2000)) 2 . 5 not irritating (IUCLID (2000)) .. - [1,2-Ethanediamine, N,N'-bis(2-aminoethyl)-].

8 - [1,2-Ethanediamine, N,N'-bis(2-aminoethyl)-] : Maximization Test . 80 90 sensitizing (SIDS(1998)) . (SIDS(1998)) . SIDS(1998) . - [Titanium dioxide] : Maurer optimisation test IUCLID. (2000)) 290 48 . IUCLID (2000)) List 2 .. * IARC. - [Titanium dioxide] : Group 2B. * OSHA. - . * ACGIH. - [Titanium dioxide] : A4. * NTP. - . * EU CLP. - .. - [1,2-Ethanediamine, N,N'-bis(2-aminoethyl)-] : in vivo . SIDS(1998)) in vitro . (,SIDS(1998)) . - [Titanium dioxide] : in vivo . NTPDB 2005 ) in vivo SCE. ( in vivo Ames . in vitro .. - [1,2-Ethanediamine, N,N'-bis(2-aminoethyl)-] : .. SIDS(1998) .. SIDS(1998) .. - [1,2-Ethanediamine, N,N'-bis(2-aminoethyl)-] : . SIDS(1998) . SIDS(1998) . - [Titanium dioxide] : 20000 mg/kg DFGOT 1991) . g 60kg 7560 mg/kg . 24 ACGIH (2001) .. HDSB 2005 .. - [1,2-Ethanediamine, N,N'-bis(2-aminoethyl)-] : 4 215mg/kg . SIDS(1998) . 10 . SIDS(1998) . SIDS(1998) .. - [Titanium dioxide] : 13 103 4.

9 25000 pppm 1250 mg/kg/day NTP TR (1979) . 20 . X (1991)) .. (1991) ACGIH (2001) IARC vol. 47 (1989) PATTY (5th, 2001) 2 250 mg/m3 5. days/week, 6 h/day IUCLID (2000) .. - . ITW Perforamnce Polymers Fluids Japan Co., Ltd. 6/7. SDS 0200. 12.. A.. - .. - [1,2-Ethanediamine, N,N'-bis(2-aminoethyl)-] : 48 EC50 mg/L.. - . B.. - .. - . C.. - .. - . D.. - . E.. - . F.. - [1,2-Ethanediamine, N,N'-bis(2-aminoethyl)-] : 3 OECD302B 28 . 0% SIDS, 2004 3 . 13.. A.. - . - . - . B.. - . 14.. A.. - . B.. - . C. ES . - . D.. - . E.. - . F.. - DOT . - : . - : . ITW Perforamnce Polymers Fluids Japan Co., Ltd. 7/7. SDS 0200. 15.. A.. - .. * . - 191 . * . - 191 . * . - . PRTR . - 1 278 . B.. - . EU . * . - [1,2-Ethanediamine, N,N'-bis(2-aminoethyl)-] : Xn; R21 C; R34 R43 R52-53. * . - [1,2-Ethanediamine, N,N'-bis(2-aminoethyl)-] : R21, R34, R43, R52/53. * . - [1,2-Ethanediamine, N,N'-bis(2-aminoethyl)-] : S1/2, S26, S36/37/39, S45, S61.

10 * OSHA . - . * CERCLA 103 ( ). - . * EPCRA 302 ( ). - . * EPCRA 304 ( ). - . * EPCRA 313 ( ). - .. - .. - .. - . 16.. A.. - SDS KOSHA NITE ESIS NLM SIDS IPCS . - . - .. - .. - . - GHS SDS JIS Z 7253. B.. - 2014-09-24. C.. - 6 times, 2016-06-01. D.. - DB.