Aqua Silk Chlorine-Free Shock Oxidizer - Appatek

1 M A T E R I A L S A F E T Y D A T A S H E E TPage 1 of 6 aqua silk Chlorine-Free Shock Oxidizer1. Product And Company IdentificationSupplierManufacturerAdvant is TechnologiesAdvantis Technologies1400 Bluegrass Lakes Parkway1400 Bluegrass Lakes ParkwayAlpharetta, GA 30004 United StatesAlpharetta, GA 30004 United StatesTelephone Number: (770) 521-5999 Telephone Number: (770) 521-5999 FAX Number: (770) 521-5959 FAX Number: (770) 521-5959 Web Site: Site: Emergency Contacts & Phone NumberManufacturer Emergency Contacts & Phone NumberCHEMTREC - DAY OR NIGHT: (800) 424-9300 CHEMTREC - DAY OR NIGHT: (800) 424-9300 Issue Date: 12/15/2008 Product Name: aqua silk Chlorine-Free Shock OxidizerCAS Number: Not EstablishedChemical Family: Hydrogen PeroxideMSDS Number: 373 SynonymsDihydrogen dioxide (solution)2. Composition/Information On IngredientsIngredientCASP ercent OfNameNumberTotal WeightHYDROGEN listed in this section have been determined to be hazardous as defined in 29 CFR Materialsdetermined to be health hazards are listed if they comprise 1% or more of the composition.

2 Materials identified ascarcinogens are listed if they comprise or more of the composition. Information on proprietary materials is available in29 CFR (i)(1).Hazards Identification (Pictograms)3. Hazards IdentificationPrimary Routes(s) Of EntryInhalation, skin, eyes, ingestionEye HazardsCorrosive. Burns can occur following exposure. Direct contact may cause impairment of vision, corneal damageand/or blindness. Rinsing of the eye should take place HazardsNot expected to be absorbed through the skin. Moderate skin HazardsHarmful if swallowed. Irritation and/or burns can occur to the entire gastrointestinal tract, including the stomach andintestines, characterized by nausea, vomiting, diarrhea, abdominal pain, bleeding, and/or tissue ulceration. Ingestionmay cause severe damage to the gastrointestinal tract with the potential to cause perforation. may cause rapidrelease of oxygen which may expand the esophagus or stomach resulting in severe A T E R I A L S A F E T Y D A T A S H E E TPage 2 of 6 aqua silk Chlorine-Free Shock Oxidizer3.

3 Hazards Identification - ContinuedInhalation HazardsInhalation of mist or vapor may cause irritation and/or burns to the mucous membranes of the respiratory Aggravated By ExposurePre-existing eye disease, respiratory diseases include asthma and bronchitis, dermatitis may be aggravatedfollowing Aid (Pictograms)4. First Aid MeasuresEyeImmediately flush eyes with plenty of water for at least 15 minutes. Seek medical attention skin with water for 15 minutes. Take off all contaminated clothing. Seek medical attention if a physician immediately. DO NOT induce vomiting unless directed to do so by a physician. Never giveanything by mouth to an unconscious inhaled, remove to fresh air. Seek medical attention if breathing becomes difficult or if respiratory irritationdevelops. If not breathing, give artificial respiration. Call for medical Fire Fighting MeasuresFlash Point: NA FAutoignition Point: NA FFlammability Class: Not known to be flammableFire And Explosion HazardsMaterial will not ignite or burn.

4 Oxygen is a decomposition product of hydrogen peroxide. The generation of oxygenwill increase the burning rate of ignitable MediaWater sprayFire Fighting InstructionsFirefighters should wear self-contained breathing apparatus and full protective gear. Water can be used to cool andprotect exposed Accidental Release MeasuresAir Release: Vapors may be supressed by the use of water fog. Contain all liquid for treatment and/or disposal as a(potential) hazardous Release: This material is heavier than water. This material is soluble in water. Notify all downstream users ofpossible contamination. Divert water flow around spill if possible and safe to do Release: Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Dilutespilled material with large amounts of water. Do not place spill materials back in their original containers. Place incontainers compatible for this material in a liquid form.

5 After removal, flush contaminated area thoroughly with A T E R I A L S A F E T Y D A T A S H E E TPage 3 of 6 aqua silk Chlorine-Free Shock Oxidizer6. Accidental Release Measures - ContinuedHazardous concentrations in air may be found in local spill area and immediately downwind. Remove all sources ofignition. Stop source of spill as soon as possible and notify appropriate personnel. Use appropriate personal protectiveequipment (PPE).Handling & Storage (Pictograms)7. Handling And StorageHandling PrecautionsDo not take internally. Avoid contact with eyes, skin, and clothing. Upon contact with skin or eyes, wash off withwater. Avoid breathing mist or PrecautionsKeep product tightly sealed in original containers. Store product in a cool, dry, well-ventilated area. Store away fromcombustible or flammable products. Keep product packaging clean and free of all contamination, including, pool treatment products, acids, organic materials, nitrogen-containing compounds, dry powder fireextinguishers (containing mono-ammonium phosphate), oxidizers, all corrosive liquids, flammable or combustiblematerials, , catalytic decomposition will occur in contact with certain metals, such as iron, copper, chromium, brass,bronze, lead, silver, manganese, or their salts.

6 Decomposed by alkalies and even ordinary dust or rust, bases,reducing agents, alcohols and containers retain product residue (liquid and/or vapor) and can be Clothing (Pictograms)8. Exposure Controls/Personal ProtectionEngineering ControlsUse with adequate general and local exhaust ventilation. Local exhaust ventilation or other engineering controls arenormally required when handling or using this product to keep airborne exposures below the TLV, PEL or otherrecommended exposure ProtectionUse chemical goggles and a faceshield. Emergency eyewash should be provided in the immediate work ProtectionWear impervious gloves to avoid skin ProtectionWear a NIOSH approved respirator if levels above the exposure limits are possible. NIOSH approved full-face positivepressure supplied-air ProtectionProtective Clothing Type: Butyl rubber, Natural rubber, Nitrile, Viton TMIngredient(s) - Exposure LimitsHYDROGEN PEROXIDEM A T E R I A L S A F E T Y D A T A S H E E TPage 4 of 6 aqua silk Chlorine-Free Shock Oxidizer8.

7 Exposure Controls/Personal Protection - ContinuedIngredient(s) - Exposure Limits - Continued ACGIH: 1 ppm TWA OSHA Z1: 1 ppm PEL, mg/m3 PEL NIOSH-IDLH: 75 ppm9. Physical And Chemical PropertiesAppearanceColorless LiquidOdorNoneChemical Type: MixturePhysical State: LiquidBoiling Point: 219 F 104 CSpecific Gravity: Weight: Volitales: 100 Vapor Pressure: hPapH Factor: : Soluble10. Stability And ReactivityConditions To Avoid (Stability)Contamination, avoid concentrating hydrogen peroxide, concentrated hydrogen peroxide solutions are reactive, oftenviolently, with a wide range of inorganic and organic chemicals. Sparks, open flame, other ignition sources, andelevated MaterialsStrong reducing agents. Contact with combustible materials may cause a fire. Copper and copper alloys, ferrousmetals, brass, Decomposition ProductsOxygen is a decomposition product of hydrogen peroxide.

8 The generation of oxygen will increase the burning rate ofignitable and Reactivity Summary:May become unstable at elevated temperatures and/or pressure. Not sensitive to mechanical Shock . Not sensitive tostatic Toxicological InformationAcute StudiesIrritating to skin and corrosive to eyes, respiratory tract and gastrointestinal EffectsCorrosive to EffectsModerate skin irritant. Not a skin LD50 (35% Hydrogen Peroxide) = 2,000 mg/kg RabbitDermal LD50 for this product believed to be <2,000 mg/kg RabbitAcute Oral EffectsLD50 (35% Hydrogen Peroxide) = 1,232 mg/kg RatM A T E R I A L S A F E T Y D A T A S H E E TPage 5 of 6 aqua silk Chlorine-Free Shock Oxidizer11. Toxicological Information - ContinuedAcute Oral Effects - ContinuedOral LD50 Value for this product believed to be, <1,232 RatAcute Inhalation EffectsInhalation LC50 8 hour (90% Hydrogen Peroxide) >2,000 ppm RatInhalation LC50 4 hour (50% Hydrogen Peroxide) > mg/L RatChronic/CarcinogenicityThere are no known or reported effects from chronic exposure.

9 The International Agency for Research on Cancer(IARC) has classified this product or a component of this product as a Group 3 substance, Unclassifiable as to itsCarcinogenity to EffectsThis chemical is not known or reported to affect reproductive function or fetal (Genetic Effects)This product has been tested for mutagenicity. Tests revealed both positive and negative results. Based on theweight of the evidence, we judge this product NOT to be a mutagenic Ecological InformationEcotoxicological InformationModerately toxic to fish and other aquatic Toxicity - Fish And InvertebratesEcological Toxicity Values for: HYDROGEN PEROXIDE (H2O2)Fathead minnow (Pimephales promelas) = 96 Hour LC50 = mg/lChannel catfish (Ictalurus punctatus rafinesque) = 96 Hour LC50 = mg/lRainbow trout (Salmo gairdneri) = 48 Hour lethal >40 mg/lDaphnia magna = 24 hour EC50 = mg/lDaphnia pulex = 48 Hour LC50 = mg/l13.

10 Disposal ConsiderationsIf this product becomes a waste, it meets the criteria of a hazardous waste as defined under 40 CFR 261 and would havethe following EPA hazardous waste number: D001 Dispose of material as hazardous waste. Dispose in accordance with applicable federal, state and local Transport InformationProper Shipping NameHydrogen Peroxide, Aqueous SolutionHazard , PGIIS econdary Hazard Class8 DOT Identification NumberUN2014M A T E R I A L S A F E T Y D A T A S H E E TPage 6 of 6 aqua silk Chlorine-Free Shock OxidizerDOT (Pictograms)15. Regulatory Regulatory InformationToxic Substances Control Act (TSCA): The components of this product are listed on the TSCA Inventory of ExistingChemical Hazard ClassesAcute Health HazardFire HazardIngredient(s) - State RegulationsHYDROGEN PEROXIDE New Jersey - Environmental Hazard Pennsylvania - Environmental Hazard Massachusetts - Hazardous SubstanceCanadian Regulatory InformationWHMIS01 1988 Threshold Limits: 1%English List no.