ACRAMITE® 480 SC - Arysta LifeScience Australia

1 SAFETY DATA SHEET. acramite 480 SC. Version Revision Date: MSDS Number: Country: AU. 400000004589 Language: EN. SECTION 1. PRODUCT AND COMPANY IDENTIFICATION. Product name : acramite 480 SC. Product code : 400000004589. Details of the supplier of the safety data sheet Company: Arysta LifeScience Australia Pty Ltd c/o Level 3, 70 Hindmarsh Square Adelaide SA. Australia 5000. Telephone : + 61 8 8112 0900. Prepared by Further information for the safety data sheet : Emergency telephone number Emergency telephone number: +61 2801 44558, ORICA : 1800 033 111 (24 hr Service). For advice, contact a Poisons Information Centre (Phone: Australia 131 126 or New Zealand 0800 764 766) or a doctor at once. For additional emergency telephone numbers see section 16 of the Safety Data Sheet. Recommended use of the chemical and restrictions on use Recommended use : Plant protection agent Acaricide Restrictions on use : Agriculture For professional users only.

2 APVMA No: 55264. SECTION 2. HAZARDS IDENTIFICATION. GHS Classification Skin sensitisation : Category 1. GHS Label element 1 / 20. SAFETY DATA SHEET. acramite 480 SC. Version Revision Date: MSDS Number: Country: AU. 400000004589 Language: EN. Hazard pictograms : Signal word : Warning Hazard statements : H317 May cause an allergic skin reaction. Precautionary statements : Prevention: P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves. Response: P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P333 + P313 If skin irritation or rash occurs: Get medical advice/. attention. P363 Wash contaminated clothing before reuse. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Other hazards which do not result in classification Hazardous substance Dangerous goods Very toxic to aquatic life with long lasting effects.

3 SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS. Substance / Mixture : Mixture Chemical nature : Bifenazate - 480 g/L. Hazardous components Chemical Name CAS-No. Concentration (% w/w). Bifenazate 149877-41-8 >= 30 - < 60. SECTION 4. FIRST AID MEASURES. General advice : For advice, contact a Poisons Information Centre (Phone: Australia 131 126 or New Zealand 0800 764 766) or a doctor at once. If inhaled : Remove to fresh air. Obtain medical attention. In case of skin contact : Remove contaminated clothing and shoes. Wash off with warm water and soap. 2 / 20. SAFETY DATA SHEET. acramite 480 SC. Version Revision Date: MSDS Number: Country: AU. 400000004589 Language: EN. If symptoms persist, call a physician. In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If symptoms persist, call a physician.

4 If swallowed : Do NOT induce vomiting. Rinse mouth with water. Obtain medical attention. Most important symptoms and : sensitising effects effects, both acute and delayed Symptoms may be delayed. sensitising effects May cause damage to organs through prolonged or repeated exposure. Notes to physician : The first aid procedure should be established in consultation with the doctor responsible for industrial medicine. SECTION 5. FIREFIGHTING MEASURES. Suitable extinguishing media : Extinguishing media - large fires Alcohol-resistant foam (on small fires). Carbon dioxide (CO2). Dry chemical Unsuitable extinguishing media : Water spray jet Specific hazards during fire- : Burning produces irritant fumes. fighting Exposure to decomposition products may be a hazard to health. Specific extinguishing methods : Use extinguishing measures that are appropriate to local circum- stances and the surrounding environment.

5 Prevent fire extinguishing water from contaminating surface water or the ground water system. Special protective equipment for : In the event of fire, wear self-contained breathing apparatus. firefighters Use personal protective equipment. SECTION 6. ACCIDENTAL RELEASE MEASURES. Personal precautions, protective : Wear suitable protective equipment. equipment and emergency pro- Avoid contact with skin and eyes. cedures Environmental precautions : Should not be released into the environment. Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration. Methods and materials for con- : Dam up. 3 / 20. SAFETY DATA SHEET. acramite 480 SC. Version Revision Date: MSDS Number: Country: AU. 400000004589 Language: EN. tainment and cleaning up Soak up with inert absorbent material ( sand, silica gel, acid binder, universal binder, sawdust).

6 Pick up and transfer to properly labelled containers. Large spills should be collected mechanically (remove by pumping). for disposal. SECTION 7. HANDLING AND STORAGE. Advice on safe handling : Handle in accordance with good industrial hygiene and safety prac- tice. Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Use with adequate ventilation. Wash thoroughly after handling. Conditions for safe storage : Keep in a dry, cool place. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION. Components with workplace control parameters Contains no substances with occupational exposure limit values. Personal protective equipment Respiratory protection : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Hand protection Remarks : Chemical resistant protective gloves Eye protection : Safety glasses with side-shields Skin and body protection : Impervious clothing SECTION 9.

7 PHYSICAL AND CHEMICAL PROPERTIES. Appearance : liquid Colour : off-white, to, tan Odour : sweet Odour Threshold : No data available pH : 5-9. Melting point/range : Not applicable Boiling point/boiling range : > 100 C. 4 / 20. SAFETY DATA SHEET. acramite 480 SC. Version Revision Date: MSDS Number: Country: AU. 400000004589 Language: EN. Flash point : > 400 C. does not flash Evaporation rate : No data available Upper explosion limit : Not explosive Lower explosion limit : Not explosive Vapour pressure : similar to water Relative vapour density : No data available Relative density : (20 C). Density : g/cm3 (25 C). Solubility(ies). Water solubility : dispersible Solubility in other solvents : No data available Partition coefficient: n- : No data available octanol/water Auto-ignition temperature : > 400 C. Decomposition temperature : No data available Viscosity Viscosity, dynamic : 300 - 800 (20 - 25 C).

8 Viscosity, kinematic : not determined Explosive properties : Not explosive Self-Accelerating decomposition : Method: No information available. temperature (SADT). Surface tension : 43 mN/m, 25 C. Oxidizing potential : The substance or mixture is not classified as oxidizing. SECTION 10. STABILITY AND REACTIVITY. Reactivity : No dangerous reaction known under conditions of normal use. Chemical stability : Stable under normal conditions. Possibility of hazardous reac- : Hazardous polymerisation does not occur. tions Conditions to avoid : Extremes of temperature and direct sunlight. 5 / 20. SAFETY DATA SHEET. acramite 480 SC. Version Revision Date: MSDS Number: Country: AU. 400000004589 Language: EN. Incompatible materials : Oxidizing agents Strong acids and strong bases Hazardous decomposition prod- : Burning produces noxious and toxic fumes.

9 Ucts SECTION 11. TOXICOLOGICAL INFORMATION. Acute toxicity Product: Acute oral toxicity : LD50 (Rat, male): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat): > mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhala- tion toxicity Acute dermal toxicity : LD50 (Rabbit, male and female): > 5,000 mg/kg Method: OECD Test Guideline 402. Components: Bifenazate: Acute oral toxicity : LD50 (Rat, male and female): > 5,000 mg/kg Method: OECD Test Guideline 401. GLP: yes LD50 (Mouse, male and female): > 5,000 mg/kg Method: OECD Test Guideline 401. GLP: yes Acute inhalation toxicity : LC50 (Rat, male and female): > mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: OECD Test Guideline 403. GLP: yes Assessment: The substance or mixture has no acute inhala- tion toxicity Remarks: An LC50/inhalation/4h/rat could not be determined because no mortality of rats was observed at the maximum achievable concentration.

10 Acute dermal toxicity : LD50 (Rat, male and female): > 5,000 mg/kg Method: OECD Test Guideline 402. GLP: yes Skin corrosion/irritation Product: Species: Rabbit 6 / 20. SAFETY DATA SHEET. acramite 480 SC. Version Revision Date: MSDS Number: Country: AU. 400000004589 Language: EN. Method: OECD Test Guideline 404. Result: No skin irritation Components: Bifenazate: Species: Rabbit Exposure time: 4 h Assessment: No skin irritation Method: OECD Test Guideline 404. Result: No skin irritation GLP: yes Serious eye damage/eye irritation Product: Species: Rabbit Result: No eye irritation Method: OECD Test Guideline 405. Components: Bifenazate: Species: Rabbit Result: No eye irritation Exposure time: 48 h Assessment: No eye irritation Method: OECD Test Guideline 405. GLP: yes Respiratory or skin sensitisation Product: Species: Guinea pig Method: Maximisation Test (GPMT).