Transcription of 1．GPCとは？ GPC法（Gel Permeation …
1 GPC Gel Permeation chromatography 1 SEC (Size Exclusion chromatography ) GPC GPC
2 PS, PMMA, PEO 6 HFIP POM [ C] THF (PS) 40 PC CHCl3 PMMA CHCl3 PCL CHCl3 PS 40 PLA ABS ABS PS 50 DMF LiBr 10 mmol/L PEO PEG 50 PES PAN PAI PSF HFIP CF3 COONa 5 mmol/L PMMA 40 PA 6 66 610 6T 9T PET PBT (GFC) PEO PEG 35 40 PAM PVP 1 1 Z Mn Mw Mn 1 (Х ) Mw ( )
3 = M w = M M Mn Mw Mn Mw 1 10000 5 5000 10 1000 5 = 5 + 10 + 5 = 20 M = 10000 x 5( + 5000 x 10 ( ) + 1000x 5 ( ) = 105,000 M = 10000 x 10000 x 5( ) 5000 x 5000 x 10 ( ) }+ 1000x 1000 x 5 ( ) =560,000,000 Mn 105,000 / 20 5,250 Mw 755,000,000 /105,000 =7,190 Mw Mn = Mail.)
