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2. Hazards identification - SST Australia

Product Name: GLYSOWET 7/08/12 Page 1 of 4 Issue: Version MATERIAL SAFETY DATA SHEET 1. identification of the substance/preparation and of the company Product Name: GLYSOWET Supplier: SST Australia Pty Ltd ACN: 052 854 833 Address: 2032 Bayswater Village, Bayswater Vic; 3153 Australia Telephone Number: (03) 97206306 Facsimile: (03) 97206407 2. Hazards identification Hazard classification Hazardous Substance. NON-DANGEROUS GOODS. This material is classified as hazardous according to health criteria of Safe Work Australia . Classified as Non Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for transport by Road and Rail. Classified as a C2 (COMBUSTIBLE LIQUID) for the purpose of storage and handling, in accordance with the requirements of AS 1940. Refer to State Regulations for storage and transport requirements.

Product Name: GLYSOWET 7/08/12 Page 1 of 4 Issue: Version 3.2 MATERIAL SAFETY DATA SHEET 1. Identification of the substance/preparation and of the company

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Transcription of 2. Hazards identification - SST Australia

1 Product Name: GLYSOWET 7/08/12 Page 1 of 4 Issue: Version MATERIAL SAFETY DATA SHEET 1. identification of the substance/preparation and of the company Product Name: GLYSOWET Supplier: SST Australia Pty Ltd ACN: 052 854 833 Address: 2032 Bayswater Village, Bayswater Vic; 3153 Australia Telephone Number: (03) 97206306 Facsimile: (03) 97206407 2. Hazards identification Hazard classification Hazardous Substance. NON-DANGEROUS GOODS. This material is classified as hazardous according to health criteria of Safe Work Australia . Classified as Non Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for transport by Road and Rail. Classified as a C2 (COMBUSTIBLE LIQUID) for the purpose of storage and handling, in accordance with the requirements of AS 1940. Refer to State Regulations for storage and transport requirements.

2 Hazard category Xn Harmful Xi Irritant Risk phrase(s) R22 Harmful if swallowed. R38 Irritating to skin. R41 Risk of serious eye damage. R51/53 Toxic to aquatic organisms. May cause long-term effects in the aquatic environment.* * This risk phrase is provided for information only. Safety phrase(s) S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical Wear suitable gloves and eye/face protection. Poisons schedule (Aust): S5. 3. Composition/information on ingredients Product Description: A Tank mix adjuvant to improve wetting and spreading of pesticides Components CAS Number Proportion Tallow Amine Ethoxylate >90% 4. First-aid measures If poisoning occurs, contact a doctor or Poisons Information Centre. Phone Australia 13 1126; New Zealand 0800 764 766. Ingestion: Immediately rinse mouth with water.

3 If swallowed do NOT induce vomiting. Give water to drink. Seek immediate medical attention. Eye contact: If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. Transport to hospital or medical centre. Product Name: GLYSOWET 7/08/12 Page 2 of 4 Issue: Version Skin contact: If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. If irritation occurs seek medical attention. Wash contaminated clothing before re-use. Inhalation: Remove victim from exposure. Keep at rest until fully recovered. Seek medical advice. Medical attention and special treatment: Treat symptomatically. Can cause corneal burns. 5. Fire-fighting measures Suitable extinguishing media: For large fires use alcohol resistant foam, normal foam, water fog or fine water spray.

4 Do not use water jets. For small fires use foam, dry chemical, carbon dioxide or water spray. Hazards from combustion products: Combustible liquid. On burning will emit toxic fumes including those of ammonia and oxides of nitrogen and carbon. Precautions for fire fighters and special protective equipment: Heating can cause expansion or decomposition leading to violent rupture of containers. If safe to do so, remove containers from path of fire. Keep containers cool with water spray. Fire fighters to wear self-contained breathing apparatus if risk of exposure to vapour or products of combustion as well as structural fire fighters uniform. Hazchem code: 3Z 6. Accidental release measures Emergency procedures: Slippery when spilt. Avoid accidents, clean up immediately. Wear protective equipment to prevent skin and eye contamination. Do not touch or walk through spilled material. Methods and materials for containment and clean up procedures: Contain - prevent run off into drains and waterways.

5 Use absorbent (soil, sand or other inert material). Collect and seal in properly labeled drums for disposal. Wash area down with excess water to remove residual material. 7. Handling and storage Precautions for safe handling: Avoid skin and eye contact. Always wash hands before smoking, eating,drinking or using the toilet. Wash contaminated clothing and other protective equipment before storage or re-use. Do not dispose of material to sewers or waterways. Conditions for safe storage: Store in a cool place and out of direct sunlight. Store away from foodstuffs and oxidising agents. Keep containers closed at all times check regularly for leaks. Classified as a C2 (COMBUSTIBLE LIQUID) for the purpose of storage and handling, in accordance with the requirements of AS 1940. Refer to State Regulations for storage and transport requirements. This material is a Scheduled Poison S5 and must be stored, maintained and used in accordance with the relevant regulations.

6 8. Exposure controls/personal protection National exposure standards No value assigned for this specific material by Safe Work Australia . Biological limit values Not Relevant. Engineering controls: Use in a well ventilated area. Keep containers closed when not in use. Personal protective equipment: OVERALLS, SAFETY SHOES, CHEMICAL GOGGLES, GLOVES Wear overalls, chemical goggles and impervious gloves. If inhalation risk from spray mists exists wear a filter respirator suitable for organic particulates meeting the requirements of AS/NZS 1715 and AS/NZS 1716 Product Name: GLYSOWET 7/08/12 Page 3 of 4 Issue: Version 9. Physical and chemical properties Physical state: Clear Liquid Solubility: Dispersible in water. Specific Gravity: approx. @20 C Flash Point ( C): > 150 (OC) pH: 6-8 (1% aqueous solution) Freezing Point/Range ( C): <0 10. Stability and reactivity Chemical stability: Stable under normal conditions of use.

7 Conditions to avoid: Excessive heat will lead to accelerated oxidative degradation. Incompatible materials: Reacts with strong oxidising agents. Hazardous decomposition products: Ammonia and oxides of nitrogen and carbon. Hazardous reactions: None known. 11. Toxicological information No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product label. Symptoms that may arise if the product is mishandled are: Acute Effects Ingestion: Swallowing can result in irritation of the gastrointestinal tract. Eye contact: A severe eye irritant. Contamination of the eyes can result in permanent injury. Corrosive to eyes; contact can cause corneal burns. Skin contact: Contact with skin will result in irritation. Will have a degreasing action on the skin Repeated or prolonged skin contact may lead to irritant contact dermatitis. Inhalation: Inhalation of high concentrations of mist may produce respiratory irritation.

8 No information available for product. Acute toxicity / Chronic toxicity No LD50 data available for product, however for tallow amines, polyoxyethylene derivatives: Oral LD50 (rat): 620 mg/kg (1) Eye irritation (Draize, rabbit): Severe irritant (1) 12. Ecotoxicological information Ecotoxicity No LC50 data available for product, however for major component (polyethanoxy tallow amine) the following range is expected based on results for similar materials (2): LC50 (fish species): 5 10 mg/L EC50 (Daphnia species): 10 30 mg/L Toxic to aquatic organisms. Persistence/degradability The substance is not expected to be readily biodegradable according to the AS 4351 Part 2 test method. Mobility No data available for product. Avoid contaminating waterways. 13. Disposal considerations Disposal methods: Empty containers should be forwarded to an approved agent for recycling. Avoid unauthorised discharge to sewer. Special precautions for landfill or incineration: Material suitable for disposal by incineration or landfill through an approved agent.

9 Product Name: GLYSOWET 7/08/12 Page 4 of 4 Issue: Version 14. Transport information Considered Non Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for transport of dangerous goods by Road and Rail. For bulk shipments as Class 9, UN-No: 3082, Hazchem code 3Z Packing group: III Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, (CONTAINS TALLOW AMINE ETHOXYLATE) Segregation Dangerous Goods: Not to be loaded with explosives (Class 1), oxidising agents (Class ) or organic peroxides (Class ), however exemptions may apply. IMO Marine Marine Pollutant 15. Regulatory information Poisons Schedule S5 Country/Region Inventory Status Australia AICS All components listed Canada DSL All components listed Europe EINECS Components listed or exempt from listing Japan ENCS All components listed Korea ECL All components listed New Zealand NZIoC All components listed United States TSCA All components listed 16.

10 Other information Literary reference (1) RTECS #WW3150000, 05/2003. (2) Tenside Surfactant Detergents, 25 (1988) 2, pp 86 98. Reason(s) for Issue: CONTACT POINT: John Illingworth Phone: 9720 6306 or Mobile: 0418 844 861 All information contained in this document is as accurate as possible based on the information submitted by raw material suppliers. SST Australia Pty Ltd will not accept any responsibly for any damage that may result from reliance upon the information contained herein.


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