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êT êN - ADAMA Agricultural Solutions

Page : 1. SAFETY DATA SHEET Revised edition no : 1. EU Regulation No. 1907/2006, Date : 3 / 9 / 2013. Annex II Supersedes : 23 / 7 / 2012. GALIGAN 240 EC H-0154-26783. SECTION 1. Identification of the substance/mixture and of the company/undertaking Product identifier Trade name : GALIGAN 240 EC. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses : Herbicide Uses advised against : None under normal conditions. Details of the supplier of the safety data sheet : ADAMA SOUTH AFRICA (PTY) LTD. 21 Viben Street Brackenfell 7560. Email : Emergency telephone number : +27 82 331 6463. +27 21 982 1460. SECTION 2. Hazards identification Classification of the substance or mixture Classification 67/548/EEC (DSD) - 1999/45/EC (DPD).

Page : 2 SAFETY DATA SHEET Revised edition no : 1 EU Regulation No. 1907/2006, Date : 3 / 9 / 2013 Annex II Supersedes : 23 / 7 / 2012 GALIGAN 240 EC H-0154-26783 SECTION 3. Composition/information on ingr

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Transcription of êT êN - ADAMA Agricultural Solutions

1 Page : 1. SAFETY DATA SHEET Revised edition no : 1. EU Regulation No. 1907/2006, Date : 3 / 9 / 2013. Annex II Supersedes : 23 / 7 / 2012. GALIGAN 240 EC H-0154-26783. SECTION 1. Identification of the substance/mixture and of the company/undertaking Product identifier Trade name : GALIGAN 240 EC. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses : Herbicide Uses advised against : None under normal conditions. Details of the supplier of the safety data sheet : ADAMA SOUTH AFRICA (PTY) LTD. 21 Viben Street Brackenfell 7560. Email : Emergency telephone number : +27 82 331 6463. +27 21 982 1460. SECTION 2. Hazards identification Classification of the substance or mixture Classification 67/548/EEC (DSD) - 1999/45/EC (DPD).

2 : R10. Repr. Cat. 2; R61. Xi; R38-41. N; R50-53. Label elements Labelling 1999/45/EC (DPD). T . N. Symbol(s). : T : Toxic N : Dangerous for the environment. R Phrase(s) : R10 - Flammable. R38 - Irritating to skin. R41 - Risk of serious damage to eyes. R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R61 - May cause harm to the unborn child. S Phrase(s) : S02 - Keep out of the reach of children. S13 - Keep away from food, drink and animal feedingstuffs. S20/21 - When using, do not eat, drink or smoke. S24/25 - Avoid contact with skin and eyes. S29 - Do not empty into drains. S39 - Wear eye/face protection. S46 - If swallowed seek medical advice immediately and show this container or label.

3 S60 - This material and its container must be disposed of as hazardous waste. S61 - Avoid release to the environment. Refer to special instructions/Safety data sheets. Other hazards Other hazards : None under normal conditions. ADAMA SOUTH AFRICA (PTY) LTD. 21 Viben Street Brackenfell 7560. Page : 2. SAFETY DATA SHEET Revised edition no : 1. EU Regulation No. 1907/2006, Date : 3 / 9 / 2013. Annex II Supersedes : 23 / 7 / 2012. GALIGAN 240 EC H-0154-26783. SECTION 3. Composition/information on ingredients Substance name Concentration % w/w CAS No EC No Index No REACH Reg. Classification Oxyfluorfen : 23 - 25 % 42874-03-3 255-983-0 ----- ---- N; R50-53. ---------------------------------- Aquatic Acute 1 - H400.

4 Aquatic Chronic 1 - H410. Calcium dodecylbenzene sulphonate : 3 -4% 26264-06-2 247-557-8 ----- ---- Xi; R38-41. ---------------------------------- Eye Dam 1 - H318. Skin Irrit. 2 - H315. N-methyl-2-pyrolidone : - % 872-50-4 212-828-1 606-021-00-7 ---- Repr. Cat. 2; R61. Xi; R36/37/38. ---------------------------------- Repr. 1B - H360D. Eye irrit 2 - H319. Skin Irrit. 2 - H315. STOT SE 3 - H335. Xylene : 58 - 64 % 1330-20-7 215-535-7 601-022-00-9 ---- R10. Xn; R20/21. Xi; R38. ---------------------------------- Flam. Liq. 3 - H226. Acute Tox. 4 - H312. Acute Tox. 4 - H332. Skin Irrit. 2 - H315. SECTION 4. First aid measures Description of first aid measures First aid measures : Remove victim from area of exposure.

5 Wash away remainder with plenty of water. Inhalation : Remove victim to fresh air. If breathing is difficult: artificial respiration . Get medical attention . Skin contact : Remove contaminated clothing . Wash away remainder with water and soap . Eye contact : Wash out with water with the eyelid held wide open for at least 15 minutes. Contact ophthalmologist immediately.. Ingestion : Wash out mouth with plenty of water. Get medical attention Never give anything by mouth to an unconscious person. Most important symptoms and effects, both acute and delayed Indication of any immediate medical attention and special treatment needed Note to physician : There is no specific antidote. Treat symptomatically and give supportive therapy.

6 Protection of first-aiders : Use appropriate protection (see section 8). SECTION 5. Fire-fighting measures Extinguishing media Suitable extinguishing media : Dry chemical , water spray , foam , carbon dioxide . Special hazards arising from the substance or mixture Specific hazards : Flashback may occur along vapour trail. Hazardous decomposition products : fluorine compounds Chloride compounds , and nitrogen oxides . Advice for fire-fighters Protection against fire : Self-contained breathing apparatus and total protection required in enclosed areas. ADAMA SOUTH AFRICA (PTY) LTD. 21 Viben Street Brackenfell 7560. Page : 3. SAFETY DATA SHEET Revised edition no : 1. EU Regulation No. 1907/2006, Date : 3 / 9 / 2013.

7 Annex II Supersedes : 23 / 7 / 2012. GALIGAN 240 EC H-0154-26783. SECTION 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For emergency responders : Wear suitable protective clothing. Environmental precautions Environmental precautions : Do not discharge into the environment. Methods and material for containment and cleaning up Clean up methods : Keep away from : open flame , sparks and heat . Absorb remainder in sand or other inert material. Dispose of this material and its container at hazardous or special waste collection points. Reference to other sections SECTION 7. Handling and storage Precautions for safe handling Handling : Avoid all unnecessary exposure.

8 Avoid contact with skin and eyes. Ventilation required. Keep away from : sparks , open flame and direct sunlight . Conditions for safe storage, including any incompatibilities Storage : Keep only in the original container . Keep in a cool, well-ventilated place away from direct sunlight . Specific end use(s). SECTION 8. Exposure controls/personal protection Control parameters TLV -TWA [ppm] : N-Methyl-2-pyrrolidone (UK ) :25. Xylene : (ACGIH) 100. Exposure controls : Ventilation required. When using do not eat, drink or smoke. Wash hands thoroughly after handling. Wash clothing separately before re-use. Personal protection : Wash clothing separately before re-use. Respiratory protection : Respiratory protection is not required if good ventilation is maintained Hand protection : Chemical resistant gloves Skin protection : Wear suitable protective clothing Chemicals resistant boots Eye protection : Safety goggles or face shield SECTION 9.

9 Physical and chemical properties Information on basic physical and chemical properties Appearance Physical state at 20 C : Liquid Colour : Amber Odour : Aromatic solvent. Odour threshold : Not available pH : 5-7 (CIPAC , MT ). Melting point / Freezing point : Melting point: 85-90 C. ADAMA SOUTH AFRICA (PTY) LTD. 21 Viben Street Brackenfell 7560. Page : 4. SAFETY DATA SHEET Revised edition no : 1. EU Regulation No. 1907/2006, Date : 3 / 9 / 2013. Annex II Supersedes : 23 / 7 / 2012. GALIGAN 240 EC H-0154-26783. SECTION 9. Physical and chemical properties (continued). Initial boiling point - boiling range : Not available Boiling point [ C] : 137-143 C ( Not available ). Flash point : C. Evaporation rate : Not available Flammability : Not applicable for liquids Explosion limits (lower - upper) : Not available Vapour pressure : mPa (25) C (Oxyfluorfen).

10 Vapour density : Not available Relative density : ( 20 C). Solubility : Emulsifiable concentrate Partition coefficient : n-octanol / water : (25 C) (Oxyfluorfen). Auto-ignition temperature : 450 ( Xylene ). Decomposition temperature : Not available Viscosity : 24 sec. (40 C). Explosive Properties : Xylene - Vapors may form explosive mixtures with air. Oxidising properties : Not oxidizing Other information : Surface tension : mN/m (40 C). SECTION 10. Stability and reactivity Reactivity : Stable under normal conditions. Chemical stability Stability : Not subject to polymerization . Possibility of hazardous reactions : Hazardous polymerization will not occur Conditions to avoid Incompatible materials Materials to avoid : Oxidizing agents , acids and nitrogen oxides.


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