国内産野菜・果実類中の残留農薬実態調査（平成27

1 Ann. Rep. Tokyo Metr. Inst. Pub. Health,67, 901-907, 2016 a 169-0073 3-24-1 b c 27 a a a a a b a c a a a 27 4 28 3 32 80 27 51 64% 38 ppm ppm 6 4 2 4 22 TPP 1) 2) 27 1.

2 27 4 28 3 32 80 Table 1 Table 1. List of Investigated Crops Crop No. of Tested Vegetable Bitter melon [NIGAURI] Broccoli Cabbage Carrot Cauliflower Chinese cabbage Chinese yam [YAMATOIMO] Crowndaisy [SHUNGIKU] Cucumber Eggplant Japanese radish [DAIKON] (root) Lettuce Lotus root [RENKON] Potato Potherb Mustard [MIZUNA] Spinach [HORENSOU] To ma t o Welsh onoin [NEGI] 128415118172151210 2 Subtotal 62 Fruit Apple Cherry Citrus iyo[IYOKAN] Grape Japanese apricot [UME] Japanese pear Kiwifruit Mandarin orange Melon Peach Persimmon [KAKI] Plum Strawberry Watermelon21131111112111 Subtotal 18 Total 80 Table 1.

3 List of Investigated Crops Crop No. of Tested Vegetable Bitter melon [NIGAURI] Broccoli Cabbage Carrot Cauliflower Chinese cabbage Chinese yam [YAMATOIMO] Crown daisy [SHUNGIKU] Cucumber Eggplant Japanese radish [DAIKON] (root) Lettuce Lotus root [RENKON] Potato Potherb Mustard [MIZUNA] Spinach [HORENSOU] To ma t o Welsh onoin [NEGI] 128415118172151210 2 Subtotal 62 Fruit Apple Cherry Citrus iyo[IYOKAN] Grape Japanese apricot [UME] Japanese pear Kiwifruit Mandarin orange Melon Peach Persimmon [KAKI] Plum Strawberry Watermelon21131111112111 Subtotal 18 Total 80 Ann. Rep. Tokyo Metr. Inst. Pub. Health, 67, 223-229, 2016 Ann. Rep. Tokyo Metr. Inst. Pub. Health, 67, 2016 902 Table 2.

4 List of Surveyed Pesticides1 Organophosphorus pesticides (92) 2)[Insecticide] acephate, azinphos-ethyl, azinphos-methyl, bromophos, bromophos-ethyl, cadusafos, chlorfenvinphos (CVP-E and -Z), chlorpyrifos, chlorpyrifos-oxon, chlorpyrifos-methyl, cyanofenphos (CYP), cyanophos (CYAP), demeton-O, demeton-S, demeton-S-methyl, demeton-S-methyl sulfone, dialifos (dialifor), diazinon, dichlofenthion (ECP), dichlorvos (DDVP), dimethoate, dimethylvinphos (-E and -Z), dioxabenzofos (salithion), dioxathion, disulfoton (ethylthiodemeton), disulfoton-sulfone, disulfoton-sulfoxide, EPBP, EPN, EPN-oxon, ethion, ethoprophos (mocap), etrimfos, fenamiphos, fenchlorphos, fenitrothion (MEP), fenthion (MPP), fenthion-oxon sulfone (MPP-oxon sulfone), fenthion-oxon sulfoxide (MPP-oxon sulfoxide), fenthion-sulfone (MPP-sulfone), fenthion-sulfoxide (MPP-sulfoxide), fonofos, formothion, fosthiazate, heptenophos, isazofos, isocarbophos, isofenphos, isoxathion, leptophos, malaoxon, malathion, mecarbam, methacrifos, methamidophos, methidathion (DMTP), mevinphos (phosdrin), monocrotophos, naled (BRP), omethoate, oxydeprofos (ESP), oxydeprofos-sulfone (ESP-sulfone), parathion, parathion-methyl, phenthoate (PAP), phorate, phosfolan, phosalone, phosphamidon, phosmet (PMP), pirimiphos-methyl, profenofos, propaphos, propaphos-sulfone, prothiofos, prothiofos-oxon, pyraclofos, pyridaphenthion, quinalphos, sulfotep, terbufos, tetrachlorvinphos (CVMP), thiometon, triazophos, trichlorfon (DEP), vamidothion, vamidothion-sulfone [Fungicide] edifenphos (EDDP), iprobenfos (IBP), tolclofos-methyl [Herbicide] butamifos, piperophos Organochlorine pesticides (39) [Insecticide] aldrin, BHC (HCH) ( -, -, - and -), chlordane cis- and trans-)

5 , chlorfenapyr, chlorfenson, chloropropylate, DDT (p,p'-DDD, p,p'-DDE and o,p'-,p,p'-DDT), o,p'-DDD, dicofol, dieldrin, endosulfan (-I, -II), endosulfan sulfate, endrin, fipronil, heptachlor, heptachlor-epoxide, methoxychlor, tetradifon [Fungicide] captafol, captan, chloroneb, chlorothalonil(TPN), dichlofluanid, dicloran(CNA), folpet, iprodione, iprodione metabolite, phthalide, procymidone, quintozene (PCNB), tecnazene, vinclozolin [Herbicide] bifenox, chlormethoxynil (chlomethoxyfen), chlornitrofen (CNP), chlorthal-dimethyl, clodinafop-propargyl, diclofop-methyl [Bactericide] nitrapyrin Carbamate pesticides (26) [Insecticide] aldicarb, aldoxycarb (aldicarb sulfone), aminocarb, bendiocarb, carbaryl (NAC), carbofuran, fenobucarb (BPMC), fenothiocarb, fenoxycarb, indoxacarb, isoprocarb (MIPC), methiocarb, methomyl, methoxyfenozide, metolcarb (MTMC), oxamyl, pirimicarb, propoxur (PHC), thiodicarb, XMC, xylylcarb (MPMC) [Fungicide] diethofencarb [Herbicide] chlorpropham (CIPC), esprocarb, thiobencarb, tri-allate Pyrethroid pesticides (16) [Insecticide] acrinathrin, allethrin, bifenthrin, cyfluthrin, cyhalothrin, cypermethrin, deltamethrin, fenpropathrin, fenvalerate, flucythrinate, fluvalinate, halfenprox, permethrin, silafluofen, tefluthrin, tralomethrin Organonitrogen and Other pesticides (122) [Insecticide] acetamiprid, bromopropylate, buprofezin, clothianidin, dinotefuran, etoxazole, flonicamid, fluacrypyrim, hexythiazox, imidacloprid, nitenpyram, nitenpyram metabolite (CPF)

6 , penthiopyrad, pyridaben, pyridalyl, pyrimidifen, pyriproxyfen, tebufenozide, tebufenpyrad, thiacloprid, thiacloprid amide, thiamethoxam [Fungicide] azaconazole, azoxystrobin, benalaxyl, bitertanol, boscalid, cyproconazole, cyprodinil, diclobutrazol, difenoconazole, diniconazole, epoxiconazole, fenamidone, fenarimol, fenbuconazole, fenoxanil, fluazinam, fludioxonil, flusilazole, flutolanil, flutriafol, hexaconazole, imazalil, isoprothiolane, kresoxim-methyl, mepronil, metalaxyl, myclobutanil,nitrothal-isopropyl, o-phenylphenol (OPP), oxadixyl, penconazole, prochloraz, prochloraz metabolite (2,4,6-trichloraphenol), propiconazole, pyraclostrobin, pyrifenox, pyrimethanil, quinoxyfen, tebuconazole, tetraconazole, thiabendazole (TBZ), thifluzamide, tolylfluanid, triadimefon, triadimenol, tricyclazole, trifloxystrobin, triflumizole, triflumizole metabolite [Herbicide] acetochlor, alachlor, atrazine, benfluralin, benoxacor, bromacil, bromobutide, butachlor, butafenacil, cafenstrole, carfentrazone-ethyl, clomeprop, cloquintocet-mexy , cyanazine, cyhalofop-butyl, dichlobenil, diflufenican, dimethenamid, dithiopyr, ethalfluralin, flamprop-methyl, flumiclorac-pentyl, flumioxazin, lactofen, mefenacet, mefenpyr diethyl, metolachlor, metribuzin, naproanilide, norflurazon, oxadiazon, oxyfluorfen, pendimethalin, picolinafen, pretilachlor, prometryn, propachlor, propanil, propazine, propyzamide, pyraflufen-ethyl, quinoclamine, simazine, terbacil, terbutylazine, thenylchlor, thiazopyr, trifluralin [Plant growth regulator] dimethipin, paclobutrazol [Insecticide synergist] piperonyl butoxide Total 295 kinds1)

7 Includes metabolites, 2) Values in parentheses are indicated the number of pesticide 224 67, 2016 9032. 295 Table 2 3. 1) GC-2010 FPD Agilent 7890 NPD ECD 2) Agilent 7890A/5975C Accu TOF GCv GCMS-QP2010 Plus 3) Waters Xevo TQD System, SCIEX 5500Q TRAP System 4000Q TRAP System Triple Quad 5500 System. 4. 3) 4) ppm 32 80 27 51 64% 38 ppm ppm 1. 18 62 Table 3 14 34 13 12 25 ppm 55% 1/500 2/5 5) 8 2 2 1 1 5 2 6 2 2 2)

8 Ppm 1 27 7~9 5 3 4 3 ppm 8 6 MEP 5 ppm 1 3 27 1 4 1 5 10 8 3 6 ppm 1 2008 EU 2010 2012 7) 27 4 2 8) 2002 9) 10) 2) 27 , ppm 10 3 ppm 2.

9 14 18 Table 4 13 17 16 12 28 ppm 94% 1/2500 /8225 Ann. Rep. Tokyo Metr. Inst. Pub. Health, 67, 2016 904 Table. 3 Pesticide Residue Detected in Domestic VegetablesCrops No. of Samples No. of Positive Sample Part Pesticide (ppm) Broccoli 2 1 A (W)1)Flonicamid (5)2)Cabbage 8 2 A (W) Boscalid Tr3)(5) B (W) Iprodione Tr( ) Carrot 4 1 A (W) Iprodione Tr( ) Cauliflower 1 1 A (W) Methomyl (2) Chinese cabbage 5 3 A (W) Boscalid (40), Dinotefuran (2), Flonicamid Tr(2), Pyraclostrobin Tr(3) B (W) Flonicamid (2), Metalaxyl Tr( ), Methomyl (2) C (W) Boscalid (40), Imidacloprid Tr( ), Pyraclostrobin Tr(3) Crowndaisy 1 1 A (W) Dinotefuran (20) Cucumber 8 8 A (W) Metalaxyl (1), Procymidone Tr(5) B (W) Imidacloprid Tr(1), Iprodione Tr( ) C (W) Imidacloprid Tr(1), MEP Tr( ), MEP-oxon ( ) D (W) Clothianidin (2), Metalaxyl Tr(1) E (W) Boscalid (5), Diethofencarb ( ) F (W) Acetamiprid (2) G (W) Chlorfenapyr ( ), Dinotefuran (2)

10 , Procymidone (5) H (W) Chlorfenapyr ( ), Clothianidin Tr(2), Dinotefuran (2), Imidacloprid (1), Procymidone (5) Eggplant 1 1 A (W) Dinotefuran (2) Lettuce 2 2 A (W) Oxamyl ( ), Thiamethoxam Tr(3) B (W) Thiamethoxam (3) Potato 5 1 A (W) Acephate Tr( ) Potherb Mustard 1 1 A (W) Clothianidin Tr(10), Dinotefuran (10) Spinach 2 2 A (W) Imidacloprid (15) B (W) Chlorfenapyr Tr(3), Clothianidin (40), Dinotefuran (15) Tomato 10 8 A (W) Azoxystrobin Tr(3), Boscalid (5) B (W) Azoxystrobin Tr(3), Imidacloprid Tr(2), Pentiopyrad Tr(3) C (W) Azoxystrobin (3), Dinotefuran (2), Triflumizole )(2) D (W) Boscalid (5), Diethofencarb ( ), Dinotefuran Tr(2) E (W) Flonicamid (2) F (W) Triflumizole )(2) G (W) Flonicamid Tr(2), Fludioxonil (5) H (W) Boscalid (5), Dinotefuran Tr(2) Welsh onoin 2 2 A (W) Azoxystrobin (10), Clothianidin Tr(1) B (W) Flutolanil (1), Nitenpyram Tr(5) 1) Whole or unpeeled, 2) Values in parentheses indicate the Maximum Residue Limit (MRL) for pesticides in foods as of March 31th, 2016, 3) Tr.