3DJH Safety Data Sheet - sds.chemtel.net

1 3 DJH Safety data Sheetaccording to 1907/2006/EC (REACH), 1272/2008/EC (CLP), andOSHA GHS3 ULQWLQJ GDWH $SULO 5 HYLVLRQ $SULO SECTION 1: Identification of the substance/mixture and of the company/undertaking Product identifier Trade name: Break-Free CLP Liquid Article number: &/3 &/3 &/3 &/3 &/3 &/3 &/3 &/3 &/3 &/3 &/3 &/3 &/3 &/3 &/3 &/3 &/3 &/3 &/3 &/3 36 %8/. &/3 3 &/3 36 &/3 36 Relevant identified uses of the substance or mixture and uses advised against Sector of Use68 3 URIHVVLRQDO XVHV 3 XEOLF GRPDLQ DGPLQLVWUDWLRQ HGXFDWLRQ HQWHUWDLQPHQW VHUYLFHV FUDIWVPHQ 68 &RQVXPHU XVHV 3 ULYDWH KRXVHKROGV JHQHUDO SXEOLF FRQVXPHUV Product category3& /XEULFDQWV JUHDVHV UHOHDVH SURGXFWV Application of the substance / the mixture:/XEULFDQW Uses advised against:&RQWDFW PDQXIDFWXUHU Details of the supplier of the Safety data Sheet Manufacturer/Supplier:6 DIDULODQG //& ,QWHUQDWLRQDO 3 DUNZD\-DFNVRQYLOOH )/ 86$&XVWRPHU &DUH Emergency telephone number:&KHP7HO ,QF SECTION 2: Hazards identification Classification of the substance or mixture Classification according to Regulation (EC) No 1272/20087KH SURGXFW LV QRW FODVVLILHG DV KD]DUGRXV DFFRUGLQJ WR *+6 UHJXODWLRQV $VS 7R[ + 0D\ EH IDWDO LI VZDOORZHG DQG HQWHUV DLUZD\V Additional information.

2 7 KHUH DUH QR RWKHU KD]DUGV QRW RWKHUZLVH FODVVLILHG WKDW KDYH EHHQ LGHQWLILHG RI WKH PL[WXUH FRQVLVWV RI FRPSRQHQW V RI XQNQRZQ WR[LFLW\ Label elements Labelling according to Regulation (EC) No 1272/20087 KLV SURGXFW GRHV QRW KDYH D FODVVLILFDWLRQ DFFRUGLQJ WR WKH &/3 UHJXODWLRQ 7KH SURGXFW LV QRW FODVVLILHG DV KD]DUGRXV DFFRUGLQJ WR 26+$ *+6 UHJXODWLRQV ZLWKLQ WKH 8 QLWHG 6 WDWHV 7KH SURGXFW LV FODVVLILHG DQG ODEHOOHG DFFRUGLQJ WR WKH &/3 UHJXODWLRQ &RQW G RQ SDJH 3 DJH Safety data Sheetaccording to 1907/2006/EC (REACH), 1272/2008/EC (CLP), andOSHA GHS3 ULQWLQJ GDWH $SULO 5 HYLVLRQ $SULO Trade name:Break-Free CLP Liquid &RQW G IURP SDJH Hazard pictograms*+6 Signal word'DQJHU Hazard-determining components of labelling:1 RQH GHFHQH GLPHU K\GURWUHDWHG Hazard statements+ 0D\ EH IDWDO LI VZDOORZHG DQG HQWHUV DLUZD\V Precautionary statements3 3 ,) 6:$//2:(' ,PPHGLDWHO\ FDOO D 32,621 &(17(5 GRFWRU 3 'R 127 LQGXFH YRPLWLQJ 3 6 WRUH ORFNHG XS 3 'LVSRVH RI FRQWHQWV FRQWDLQHU LQ DFFRUGDQFH ZLWK ORFDO UHJLRQDO QDWLRQDO LQWHUQDWLRQDOUHJXODWLRQV NFPA ratings (scale 0 - 4) +HDOWK )LUH 5 HDFWLYLW\ HMIS-ratings (scale 0 - 4) +($/7+ ),5( 5($&7,9,7< +HDOWK )LUH 5 HDFWLYLW\ Other hazards Results of PBT and vPvB assessment PBT:1RW DSSOLFDEOH vPvB:1RW DSSOLFDEOH SECTION 3: Composition/information on ingredients Mixtures Components: GHFHQH GLPHU K\GURWUHDWHG $VS 7R[ + $FXWH 7R[ + RUJDQLF FDOFLXP VDOW Additional information:)RU WKH ZRUGLQJ RI WKH OLVWHG +D]DUG 6 WDWHPHQWV UHIHU WR VHFWLRQ &RQW G RQ SDJH 3 DJH Safety data Sheetaccording to 1907/2006/EC (REACH), 1272/2008/EC (CLP), andOSHA GHS3 ULQWLQJ GDWH $SULO 5 HYLVLRQ $SULO Trade name:Break-Free CLP Liquid &RQW G IURP SDJH )RU WKH OLVWHG LQJUHGLHQW V WKH LGHQWLW\ DQG RU H[DFW SHUFHQWDJHV DUH EHLQJ ZLWKKHOG DV D WUDGH VHFUHW SECTION 4.]]

3 First aid measures Description of first aid measures General information:1R VSHFLDO PHDVXUHV UHTXLUHG After inhalation:6 XSSO\ IUHVK DLU FRQVXOW GRFWRU LQ FDVH RI FRPSODLQWV 3 URYLGH R[\JHQ WUHDWPHQW LI DIIHFWHG SHUVRQ KDV GLIILFXOW\ EUHDWKLQJ ,Q FDVH RI XQFRQVFLRXVQHVV SODFH SDWLHQW VWDEO\ LQ VLGH SRVLWLRQ IRU WUDQVSRUWDWLRQ After eye contact:5 HPRYH FRQWDFW OHQVHV LI ZRUQ 5 LQVH RSHQHG H\H IRU VHYHUDO PLQXWHV XQGHU UXQQLQJ ZDWHU ,I V\PSWRPV SHUVLVW FRQVXOW D GRFWRU After swallowing:5 LQVH RXW PRXWK DQG WKHQ GULQN SOHQW\ RI ZDWHU 'R QRW LQGXFH YRPLWLQJ FDOO IRU PHGLFDO KHOS LPPHGLDWHO\ Most important symptoms and effects, both acute and delayed*DVWULF RU LQWHVWLQDO GLVRUGHUV Hazards:0D\ EH IDWDO LI VZDOORZHG DQG HQWHUV DLUZD\V Indication of any immediate medical attention and special treatment needed,I VZDOORZHG JDVWULF LUULJDWLRQ ZLWK DGGHG DFWLYDWHG FDUERQ ,I VZDOORZHG RU LQ FDVH RI YRPLWLQJ GDQJHU RI HQWHULQJ WKH OXQJV SECTION 5: Firefighting measures Extinguishing media Suitable extinguishing agents:)RDP)LUH H[WLQJXLVKLQJ SRZGHU*DVHRXV H[WLQJXLVKLQJ DJHQWV&DUERQ GLR[LGH:DWHU KD]H RU IRJ For Safety reasons unsuitable extinguishing agents::DWHU ZLWK IXOO MHW Special hazards arising from the substance or mixture)RUPDWLRQ RI WR[LF JDVHV LV SRVVLEOH GXULQJ KHDWLQJ RU LQ FDVH RI ILUH Advice for firefighters Protective equipment::HDU VHOI FRQWDLQHG UHVSLUDWRU\ SURWHFWLYH GHYLFH :HDU IXOO\ SURWHFWLYH VXLW Additional information:1R IXUWKHU UHOHYDQW LQIRUPDWLRQ DYDLODEOH SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures)RU ODUJH VSLOOV ZHDU SURWHFWLYH FORWKLQJ &RQW G RQ SDJH 3 DJH Safety data Sheetaccording to 1907/2006/EC (REACH), 1272/2008/EC (CLP), andOSHA GHS3 ULQWLQJ GDWH $SULO 5 HYLVLRQ $SULO Trade name.]]]]

4 Break-Free CLP Liquid &RQW G IURP SDJH )RU ODUJH VSLOOV XVH UHVSLUDWRU\ SURWHFWLYH GHYLFH DJDLQVW WKH HIIHFWV RI IXPHV GXVW DHURVRO (QVXUH DGHTXDWH YHQWLODWLRQ3 DUWLFXODU GDQJHU RI VOLSSLQJ RQ OHDNHG VSLOOHG SURGXFW Environmental precautions'R QRW DOORZ SURGXFW WR UHDFK VHZDJH V\VWHP RU DQ\ ZDWHU FRXUVH Methods and material for containment and cleaning up$EVRUE ZLWK OLTXLG ELQGLQJ PDWHULDO VDQG GLDWRPLWH DFLG ELQGHUV XQLYHUVDO ELQGHUV VDZGXVW 6 HQG IRU UHFRYHU\ RU GLVSRVDO LQ VXLWDEOH UHFHSWDFOHV Reference to other sections6HH 6 HFWLRQ IRU LQIRUPDWLRQ RQ VDIH KDQGOLQJ 6HH 6 HFWLRQ IRU LQIRUPDWLRQ RQ SHUVRQDO SURWHFWLRQ HTXLSPHQW 6HH 6 HFWLRQ IRU GLVSRVDO LQIRUPDWLRQ SECTION 7: Handling and storage Precautions for safe handling8VH RQO\ LQ ZHOO YHQWLODWHG DUHDV $YRLG VSODVKHV RU VSUD\ LQ HQFORVHG DUHDV 3 UHYHQW IRUPDWLRQ RI DHURVROV Information about fire - and explosion protection:1R VSHFLDO PHDVXUHV UHTXLUHG Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles:$YRLG VWRUDJH QHDU H[WUHPH KHDW LJQLWLRQ VRXUFHV RU RSHQ IODPH 3 URWHFW IURP KXPLGLW\ DQG ZDWHU Information about storage in one common storage facility:6 WRUH DZD\ IURP IRRGVWXIIV 'R QRW VWRUH WRJHWKHU ZLWK R[LGLVLQJ DQG DFLGLF PDWHULDOV Further information about storage conditions.]]

5 HHS FRQWDLQHU WLJKWO\ VHDOHG Specific end use(s)1R IXUWKHU UHOHYDQW LQIRUPDWLRQ DYDLODEOH SECTION 8: Exposure controls/personal protection Control parameters Ingredients with limit values that require monitoring at the workplace:7KH SURGXFW GRHV QRW FRQWDLQ DQ\ UHOHYDQW TXDQWLWLHV RI PDWHULDOV ZLWK FULWLFDO YDOXHV WKDW KDYH WR EHPRQLWRUHG DW WKH ZRUNSODFH DNELs:1R IXUWKHU UHOHYDQW LQIRUPDWLRQ DYDLODEOH PNECs:1R IXUWKHU UHOHYDQW LQIRUPDWLRQ DYDLODEOH Exposure controls Engineering measures3 URYLGH DGHTXDWH YHQWLODWLRQ Personal protective equipment: General protective and hygienic measures:$YRLG FORVH RU ORQJ WHUP FRQWDFW ZLWK WKH VNLQ $YRLG FRQWDFW ZLWK WKH H\HV &RQW G RQ SDJH 3 DJH Safety data Sheetaccording to 1907/2006/EC (REACH), 1272/2008/EC (CLP), andOSHA GHS3 ULQWLQJ GDWH $SULO 5 HYLVLRQ $SULO Trade name:Break-Free CLP Liquid &RQW G IURP SDJH .HHS DZD\ IURP IRRGVWXIIV EHYHUDJHV DQG IHHG :DVK KDQGV EHIRUH EUHDNV DQG DW WKH HQG RI ZRUN Respiratory protection:1RW UHTXLUHG XQGHU QRUPDO FRQGLWLRQV RI XVH 8VH VXLWDEOH UHVSLUDWRU\ SURWHFWLYH GHYLFH LQ FDVH RI LQVXIILFLHQW YHQWLODWLRQ 8VH VXLWDEOH UHVSLUDWRU\ SURWHFWLYH GHYLFH ZKHQ KLJK FRQFHQWUDWLRQV DUH SUHVHQW Protection of hands.

6 5 XEEHU JORYHV7KH JORYH PDWHULDO KDV WR EH LPSHUPHDEOH DQG UHVLVWDQW WR WKH SURGXFW WKH VXEVWDQFH WKH SUHSDUDWLRQ 6 HOHFWLRQ RI WKH JORYH PDWHULDO RQ FRQVLGHUDWLRQ RI WKH SHQHWUDWLRQ WLPHV UDWHV RI GLIIXVLRQ DQG WKHGHJUDGDWLRQ 6 HQVLELOLVDWLRQ E\ WKH FRPSRQHQWV LQ WKH JORYH PDWHULDOV LV SRVVLEOH Material of gloves7KH VHOHFWLRQ RI WKH VXLWDEOH JORYHV GRHV QRW RQO\ GHSHQG RQ WKH PDWHULDO EXW DOVR RQ IXUWKHU PDUNV RITXDOLW\ DQG YDULHV IURP PDQXIDFWXUHU WR PDQXIDFWX UHU $V WKH SURGXFW LV D SUHSDUDWLRQ RI VHYHUDOVXEVWDQFHV WKH UHVLVWDQFH RI WKH JORYH PDWHULDO FDQ QRW EH FDOFXODWHG LQ DGYDQFH DQG KDV WKHUHIRUH WR EHFKHFNHG SULRU WR WKH DSSOLFDWLRQ %XW\O UXEEHU %51 LWULOH UXEEHU 1%51 HRSUHQH JORYHV1 DWXUDO UXEEHU 15 Penetration time of glove material7KH H[DFW EUHDN WKURXJK WLPH KDV WR EH IRXQG RXW E\ WKH PDQXIDFWXUHU RI WKH SURWHFWLYH JORYHV DQG KDV WREH REVHUYHG Eye protection:6 DIHW\ JODVVHV)ROORZ UHOHYDQW QDWLRQDO JXLGHOLQHV FRQFHUQLQJ WKH XVH RI SURWHFWLYH H\HZHDU Body protection:1RW UHTXLUHG XQGHU QRUPDO FRQGLWLRQV RI XVH 3 URWHFWLRQ PD\ EH UHTXLUHG IRU VSLOOV Limitation and supervision of exposure into the environment:1R VSHFLDO UHTXLUHPHQWV Risk management measures:6HH 6 HFWLRQ IRU DGGLWLRQDO LQIRUPDWLRQ 1R VSHFLDO UHTXLUHPHQWV SECTION 9: Physical and chemical properties Information on basic physical and chemical properties AppearanceForm:/LTXLGC olour:'DUN JUHHQ Odour:&KDUDFWHULVWLF Odour threshold:1RW GHWHUPLQHG &RQW G RQ SDJH 3 DJH Safety data Sheetaccording to 1907/2006/EC (REACH), 1272/2008/EC (CLP), andOSHA GHS3 ULQWLQJ GDWH $SULO 5 HYLVLRQ $SULO Trade name:Break-Free CLP Liquid &RQW G IURP SDJH pH-value:1RW GHWHUPLQHG Melting point/Melting range:1RW GHWHUPLQHG Boiling point/Boiling range:1RW GHWHUPLQHG Flash point:!]

7 & ! ) Flammability (solid, gaseous):1RW DSSOLFDEOH Auto/Self-ignition temperature:! & ! ) Decomposition temperature:1RW GHWHUPLQHG Self-igniting:3 URGXFW LV QRW VHOI LJQLWLQJ Danger of explosion:3 URGXFW GRHV QRW SUHVHQW DQ H[SORVLRQ KD]DUG Explosion limitsLower:1RW GHWHUPLQHG Upper:1RW GHWHUPLQHG Vapour pressure at 20 C (68 F): K3D PP +J Density at 20 C (68 F): J FP OEV JDO Relative density:1RW GHWHUPLQHG Vapour density:1RW GHWHUPLQHG Evaporation rate:1RW GHWHUPLQHG Solubility in / Miscibility withwater:)XOO\ PLVFLEOH Partition coefficient (n-octanol/water):1RW GHWHUPLQHG ViscosityDynamic:1RW GHWHUPLQHG Kinematic:1RW GHWHUPLQHG Other information1R IXUWKHU UHOHYDQW LQIRUPDWLRQ DYDLODEOH SECTION 10: Stability and reactivity Reactivity1R IXUWKHU UHOHYDQW LQIRUPDWLRQ DYDLODEOH Chemical stability Thermal decomposition / conditions to be avoided:1R GHFRPSRVLWLRQ LI XVHG DQG VWRUHG DFFRUGLQJ WR VSHFLILFDWLRQV Possibility of hazardous reactions5 HDFWV ZLWK VWURQJ R[LGLVLQJ DJHQWV 5 HDFWV ZLWK VWURQJ DFLGV &DQ IRUP H[SORVLYH PL[WXUHV LQ DLU LI KHDWHG DERYH IODVK SRLQW DQG RU ZKHQ VSUD\HG RU DWRPLVHG Conditions to avoid6 WRUH DZD\ IURP R[LGLVLQJ DJHQWV Incompatible materials1R IXUWKHU UHOHYDQW LQIRUPDWLRQ DYDLODEOH Hazardous decomposition products&DUERQ PRQR[LGH DQG FDUERQ GLR[LGH &RQW G RQ SDJH 3 DJH Safety data Sheetaccording to 1907/2006/EC (REACH), 1272/2008/EC (CLP), andOSHA GHS3 ULQWLQJ GDWH $SULO 5 HYLVLRQ $SULO Trade name:Break-Free CLP Liquid &RQW G IURP SDJH 1 LWURJHQ R[LGHV'DQJHU RI IRUPLQJ WR[LF S\URO\VLV SURGXFWV SECTION 11: Toxicological information Information on toxicological effects Acute toxicity:%DVHG RQ DYDLODEOH GDWD WKH FODVVLILFDWLRQ FULWHULD DUH QRW PHW LD/LC50 values relevant for classification:1 RQH Primary irritant effect Skin corrosion/irritation.]]]]]]]]

8 6 OLJKW LUULWDQW HIIHFW RQ VNLQ DQG PXFRXV PHPEUDQHV Serious eye damage/irritation:6 OLJKW LUULWDQW HIIHFW RQ H\HV Respiratory or skin sensitisation:%DVHG RQ DYDLODEOH GDWD WKH FODVVLILFDWLRQ FULWHULD DUH QRW PHW Carcinogenic categories IARC (International Agency for Research on Cancer):1 RQH RI WKH LQJUHGLHQWV DUH OLVWHG NTP (National Toxicology Program):1 RQH RI WKH LQJUHGLHQWV DUH OLVWHG OSHA-Ca (Occupational Safety & Health Administration):1 RQH RI WKH LQJUHGLHQWV DUH OLVWHG Acute effects (acute toxicity, irritation and corrosivity):0D\ EH IDWDO LI VZDOORZHG DQG HQWHUV DLUZD\V Germ cell mutagenicity:%DVHG RQ DYDLODEOH GDWD WKH FODVVLILFDWLRQ FULWHULD DUH QRW PHW Carcinogenicity:%DVHG RQ DYDLODEOH GDWD WKH FODVVLILFDWLRQ FULWHULD DUH QRW PHW Reproductive toxicity:%DVHG RQ DYDLODEOH GDWD WKH FODVVLILFDWLRQ FULWHULD DUH QRW PHW STOT-single exposure:%DVHG RQ DYDLODEOH GDWD WKH FODVVLILFDWLRQ FULWHULD DUH QRW PHW STOT-repeated exposure:%DVHG RQ DYDLODEOH GDWD WKH FODVVLILFDWLRQ FULWHULD DUH QRW PHW Aspiration hazard:0D\ EH IDWDO LI VZDOORZHG DQG HQWHUV DLUZD\V SECTION 12: Ecological information Toxicity Aquatic toxicity:1R IXUWKHU UHOHYDQW LQIRUPDWLRQ DYDLODEOH Persistence and degradability%LRGHJUDGDEOH Bioaccumulative potential1R IXUWKHU UHOHYDQW LQIRUPDWLRQ DYDLODEOH Mobility in soil1R IXUWKHU UHOHYDQW LQIRUPDWLRQ DYDLODEOH Ecotoxical effects: Remark:'XH WR PHFKDQLFDO DFWLRQV RI WKH SURGXFW H J DJJOXWLQDWLRQV GDPDJHV PD\ RFFXU Additional ecological information: General notes:'XH WR DYDLODEOH GDWD RQ HOLPLQDELOLW\ GHFRPSRVLWLRQ DQG ELRDFFXPXODWLRQ SRWHQWLDO SURORQJHG WHUPGDPDJH RI WKH HQYLURQPHQW FDQ QRW EH H[FOXGHG Results of PBT and vPvB assessment PBT:1RW DSSOLFDEOH &RQW G RQ SDJH 3 DJH Safety data Sheetaccording to 1907/2006/EC (REACH), 1272/2008/EC (CLP), andOSHA GHS3 ULQWLQJ GDWH $SULO 5 HYLVLRQ $SULO Trade name.]

9 Break-Free CLP Liquid &RQW G IURP SDJH vPvB:1RW DSSOLFDEOH Other adverse effects1R IXUWKHU UHOHYDQW LQIRUPDWLRQ DYDLODEOH SECTION 13: Disposal considerations Waste treatment methods Recommendation6 PDOOHU TXDQWLWLHV FDQ EH GLVSRVHG RI ZLWK KRXVHKROG ZDVWH 3 URGXFW LV UHF\FODEOH DV D ZDVWH RLO 'HOLYHU XQXVHG DQG RU FRQWDPLQDWHG SURGXFW WR ZDVWH RLO FROOHFWRUV Waste disposal number of waste from residue/unused product Waste disposal number of contaminated packaging Uncleaned packaging: Recommendation:'LVSRVDO PXVW EH PDGH DFFRUGLQJ WR RIILFLDO UHJXODWLRQV Recommended cleansing agents::DWHU LI QHFHVVDU\ WRJHWKHU ZLWK FOHDQVLQJ DJHQWV SECTION 14: Transport information UN-Number DOT, ADR, IMDG, IATA1RW 5 HJXODWHG UN proper shipping name DOT, ADR, IMDG, IATA1RW 5 HJXODWHG Transport hazard class(es) DOT, ADR, IMDG, IATA Class1RW 5 HJXODWHG Packing group DOT, ADR, IMDG, IATA1RW 5 HJXODWHG Environmental hazards: Marine pollutant:1R Special precautions for user1RW DSSOLFDEOH Transport in bulk according to Annex IIof Marpol and the IBC Code1RW DSSOLFDEOH &RQW G RQ SDJH 3 DJH Safety data Sheetaccording to 1907/2006/EC (REACH), 1272/2008/EC (CLP), andOSHA GHS3 ULQWLQJ GDWH $SULO 5 HYLVLRQ $SULO Trade name:Break-Free CLP Liquid &RQW G IURP SDJH SECTION 15: Regulatory information Safety , health and environmental regulations/legislation specific for the substanceor mixture United States (USA) SARA Section 355 (extremely hazardous substances):1 RQH R