ACRAMITE® 480 SC - Arysta LifeScience Australia

1 SAFETY DATA SHEET. acramite 480 SC. Version Revision Date: MSDS Number: Country: AU. 400000004589 Language: EN. SECTION 1. PRODUCT AND COMPANY IDENTIFICATION. Product name : acramite 480 SC. Product code : 400000004589. Details of the supplier of the safety data sheet Company: Arysta LifeScience Australia Pty Ltd c/o Level 3, 70 Hindmarsh Square Adelaide SA. Australia 5000. Telephone : + 61 8 8112 0900. Prepared by Further information for the safety data sheet : Emergency telephone number Emergency telephone number: +61 2801 44558, ORICA : 1800 033 111 (24 hr Service). For advice, contact a Poisons Information Centre (Phone: Australia 131 126 or New Zealand 0800 764 766) or a doctor at once. For additional emergency telephone numbers see section 16 of the Safety Data Sheet. Recommended use of the chemical and restrictions on use Recommended use : Plant protection agent Acaricide Restrictions on use : Agriculture For professional users only. APVMA No: 55264. SECTION 2. HAZARDS IDENTIFICATION.

2 GHS Classification Skin sensitisation : Category 1. GHS Label element 1 / 20. SAFETY DATA SHEET. acramite 480 SC. Version Revision Date: MSDS Number: Country: AU. 400000004589 Language: EN. Hazard pictograms : Signal word : Warning Hazard statements : H317 May cause an allergic skin reaction. Precautionary statements : Prevention: P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves. Response: P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P333 + P313 If skin irritation or rash occurs: Get medical advice/. attention. P363 Wash contaminated clothing before reuse. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Other hazards which do not result in classification Hazardous substance Dangerous goods Very toxic to aquatic life with long lasting effects. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS. Substance / Mixture : Mixture Chemical nature : Bifenazate - 480 g/L.

3 Hazardous components Chemical Name CAS-No. Concentration (% w/w). Bifenazate 149877-41-8 >= 30 - < 60. SECTION 4. FIRST AID MEASURES. General advice : For advice, contact a Poisons Information Centre (Phone: Australia 131 126 or New Zealand 0800 764 766) or a doctor at once. If inhaled : Remove to fresh air. Obtain medical attention. In case of skin contact : Remove contaminated clothing and shoes. Wash off with warm water and soap. 2 / 20. SAFETY DATA SHEET. acramite 480 SC. Version Revision Date: MSDS Number: Country: AU. 400000004589 Language: EN. If symptoms persist, call a physician. In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If symptoms persist, call a physician. If swallowed : Do NOT induce vomiting. Rinse mouth with water. Obtain medical attention. Most important symptoms and : sensitising effects effects, both acute and delayed Symptoms may be delayed. sensitising effects May cause damage to organs through prolonged or repeated exposure.

4 Notes to physician : The first aid procedure should be established in consultation with the doctor responsible for industrial medicine. SECTION 5. FIREFIGHTING MEASURES. Suitable extinguishing media : Extinguishing media - large fires Alcohol-resistant foam (on small fires). Carbon dioxide (CO2). Dry chemical Unsuitable extinguishing media : Water spray jet Specific hazards during fire- : Burning produces irritant fumes. fighting Exposure to decomposition products may be a hazard to health. Specific extinguishing methods : Use extinguishing measures that are appropriate to local circum- stances and the surrounding environment. Prevent fire extinguishing water from contaminating surface water or the ground water system. Special protective equipment for : In the event of fire, wear self-contained breathing apparatus. firefighters Use personal protective equipment. SECTION 6. ACCIDENTAL RELEASE MEASURES. Personal precautions, protective : Wear suitable protective equipment. equipment and emergency pro- Avoid contact with skin and eyes.

5 Cedures Environmental precautions : Should not be released into the environment. Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration. Methods and materials for con- : Dam up. 3 / 20. SAFETY DATA SHEET. acramite 480 SC. Version Revision Date: MSDS Number: Country: AU. 400000004589 Language: EN. tainment and cleaning up Soak up with inert absorbent material ( sand, silica gel, acid binder, universal binder, sawdust). Pick up and transfer to properly labelled containers. Large spills should be collected mechanically (remove by pumping). for disposal. SECTION 7. HANDLING AND STORAGE. Advice on safe handling : Handle in accordance with good industrial hygiene and safety prac- tice. Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Use with adequate ventilation. Wash thoroughly after handling. Conditions for safe storage : Keep in a dry, cool place. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION. Components with workplace control parameters Contains no substances with occupational exposure limit values.

6 Personal protective equipment Respiratory protection : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Hand protection Remarks : Chemical resistant protective gloves Eye protection : Safety glasses with side-shields Skin and body protection : Impervious clothing SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES. Appearance : liquid Colour : off-white, to, tan Odour : sweet Odour Threshold : No data available pH : 5-9. Melting point/range : Not applicable Boiling point/boiling range : > 100 C. 4 / 20. SAFETY DATA SHEET. acramite 480 SC. Version Revision Date: MSDS Number: Country: AU. 400000004589 Language: EN. Flash point : > 400 C. does not flash Evaporation rate : No data available Upper explosion limit : Not explosive Lower explosion limit : Not explosive Vapour pressure : similar to water Relative vapour density : No data available Relative density : (20 C). Density : g/cm3 (25 C). Solubility(ies). Water solubility : dispersible Solubility in other solvents : No data available Partition coefficient: n- : No data available octanol/water Auto-ignition temperature : > 400 C.

7 Decomposition temperature : No data available Viscosity Viscosity, dynamic : 300 - 800 (20 - 25 C). Viscosity, kinematic : not determined Explosive properties : Not explosive Self-Accelerating decomposition : Method: No information available. temperature (SADT). Surface tension : 43 mN/m, 25 C. Oxidizing potential : The substance or mixture is not classified as oxidizing. SECTION 10. STABILITY AND REACTIVITY. Reactivity : No dangerous reaction known under conditions of normal use. Chemical stability : Stable under normal conditions. Possibility of hazardous reac- : Hazardous polymerisation does not occur. tions Conditions to avoid : Extremes of temperature and direct sunlight. 5 / 20. SAFETY DATA SHEET. acramite 480 SC. Version Revision Date: MSDS Number: Country: AU. 400000004589 Language: EN. Incompatible materials : Oxidizing agents Strong acids and strong bases Hazardous decomposition prod- : Burning produces noxious and toxic fumes. ucts SECTION 11. TOXICOLOGICAL INFORMATION.

8 Acute toxicity Product: Acute oral toxicity : LD50 (Rat, male): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat): > mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhala- tion toxicity Acute dermal toxicity : LD50 (Rabbit, male and female): > 5,000 mg/kg Method: OECD Test Guideline 402. Components: Bifenazate: Acute oral toxicity : LD50 (Rat, male and female): > 5,000 mg/kg Method: OECD Test Guideline 401. GLP: yes LD50 (Mouse, male and female): > 5,000 mg/kg Method: OECD Test Guideline 401. GLP: yes Acute inhalation toxicity : LC50 (Rat, male and female): > mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: OECD Test Guideline 403. GLP: yes Assessment: The substance or mixture has no acute inhala- tion toxicity Remarks: An LC50/inhalation/4h/rat could not be determined because no mortality of rats was observed at the maximum achievable concentration. Acute dermal toxicity : LD50 (Rat, male and female): > 5,000 mg/kg Method: OECD Test Guideline 402.

9 GLP: yes Skin corrosion/irritation Product: Species: Rabbit 6 / 20. SAFETY DATA SHEET. acramite 480 SC. Version Revision Date: MSDS Number: Country: AU. 400000004589 Language: EN. Method: OECD Test Guideline 404. Result: No skin irritation Components: Bifenazate: Species: Rabbit Exposure time: 4 h Assessment: No skin irritation Method: OECD Test Guideline 404. Result: No skin irritation GLP: yes Serious eye damage/eye irritation Product: Species: Rabbit Result: No eye irritation Method: OECD Test Guideline 405. Components: Bifenazate: Species: Rabbit Result: No eye irritation Exposure time: 48 h Assessment: No eye irritation Method: OECD Test Guideline 405. GLP: yes Respiratory or skin sensitisation Product: Species: Guinea pig Method: Maximisation Test (GPMT). Result: May cause sensitisation by skin contact. Remarks: Information given is based on data on the components and the toxicology of similar products. Components: Bifenazate: Test Type: Maximisation Test (GPMT). Species: Guinea pig Assessment: May cause sensitisation by skin contact.

10 Method: OECD Test Guideline 406. GLP: yes Chronic toxicity Germ cell mutagenicity Product: Germ cell mutagenicity - : Based on available data, the classification criteria are not met. 7 / 20. SAFETY DATA SHEET. acramite 480 SC. Version Revision Date: MSDS Number: Country: AU. 400000004589 Language: EN. Assessment Components: Bifenazate: Genotoxicity in vitro : Test Type: Ames test Metabolic activation: with and without metabolic activation Result: negative GLP: yes : Test Type: In Vitro mammalian Cell Gene Mutation Test Metabolic activation: with and without metabolic activation Result: negative GLP: yes : Test Type: Chromosome aberration test in vitro Metabolic activation: with and without metabolic activation Result: negative GLP: yes Genotoxicity in vivo : Test Type: In vivo micronucleus test Species: Mouse Cell type: Bone marrow Exposure time: 24 h Dose: 0, 96, 192, 384 mg/kg Result: negative GLP: yes Germ cell mutagenicity - : Animal testing did not show any mutagenic effects.