Transcription of プラスチックの分析マニュアル - AIST
1 1 2021 3 ( version) FT-IR DSC GC-MS NMR GPC NMR GC-MS MALDI-TOF MS X X NMR NMR FT-IR GPC FT-IR GC-MS MALDI-TOF MS ESR SEM GPC EPMA SEM-EDX SEM-EPMS FT-IR XPS TOF-SIMS GPC GC-MS GC-MS LC-MS 2 FT-IR GC-MS SEM-EDX XPS TOF-SIMS TEM AFM FT-IR GC-MS GC-MS LC-MS TOF-SIMS 2 3 1 2011 2 2010 3 2015 2015 4 JFE 5
2 6 7 8 9 OKI 10 11 UBE 3 1 2 FT-IR DSC GC-MS FT-IR 1- IR 1 1, , , , , , C=O CONH O-H C-H 4 PP PP Bio-Rad DSC 1- PE PP PS PA 1 1.
3 PE HDPE PE LLDPE PE HPLDPE PE V-LDPE PP PP PP PE EPR PP /1- GPS PS HIPS PS SPS 1 PA PA PET PBT PTT PET-G GC-MS 1- GC-MS 1 GC-MS -6 -6,6 -6,10 FT-IR 3 DSC -6 -6,10 GC-MS 3 2 GC-MS ABS GC-MS 5 3 #overview01 GC-MS F-search NMR 1- NMR 1 1 1 1H-NMR NMR GPC NMR MALDI-TOF MS GC-TOF MS GPC SEC 1- GPC SEC 1 1 NMR 1- NMR 1 1 NMR 2 13C-NMR UBE
4 13C-NMR GC-TOF MS 6 GC-MS GC-TOF MS 1- 1 GC-TOF MS MSTips , (EI) (FI) TOF GC GC-TOF MS ABS 060 122 80 PEG MALDI-TOF MS 1- 1 2019(1) (2019) KMD Kendrick mass defect Kendrick m/z Kendrick KM KM KM KM KMD x KM y KMD C3H6O KMD 2 PPO PEO 1 KMD ( )
5 KMD 7 X X X TEM AFM X 1- X 1- WAXD SAXS 1-100nm 1 X 1 NMR NMR 1- NMR 1H 3 1 NMR TN378 NMR NMR 1 TRCNews 201606-03 400 C NMR PPS NMR FT-IR 1- FT-IR 1 TN326 8 200 m FT-IR Ge-ATR 3 3 RH R R O2 ROO ROO RH ROOH R COOH ROOH RO OH RO R CHO R COR Chromophore RH H R Chromophore COOH C=O R 9
6 2 4 GPC 1- GPC 1 80 1 69 (2006) PC PC GPC 2 IR GPC Mark-Houwink FT-IR 1- IR 10 1 FTIR CFRP ABS FTIR1 ATR 2 TN346 EVA 362 GC-MS 1- UV GC-MS 1 GC-MS 100 C 1 UV GC-MS 2 UV-Py-GC/MS TN349 - -GC/MS EGA-MS
7 MALDI-TOF MS 1- MALDI-TOF-MS KMD 1 MALDI-TOF-MS PET MSTips KMD 67(10) 589 (2018) MALDI-TOF MS ESR 1- ESR 1 ESR TN463 11 ESR 2 ESR News LDPE PP PS PC ESR GPC 1- 1 TN323 324 3 180 C 1 30 1
8 SEM 1- 1 SEM 1 12 2 GPC 1- 1 PVC 1 SEM 2 90(10) 482 2017 PC ABS PU PMMA EPMA 1- 1 1 EPMA 50 m 1 IR SEM-EDX GC MS SEM-EDX 1- SEM-EPMA 1- 1 PP 1 SEM-EDX 2 PP 1 13 SEM-XMA EPMA Si Mg X CT LLDPE FT-IR
9 FT-IR GC-MS LC-MS GC-MS 4 IR EDX EDS AES XPS ESCA TOF-SIMS m 5nm 5nm 1-2nm % 1% ppm 200mm mm 25mm 7mm 80mm 10mm : 50mm 10m 50g 1 m 1 m 300 m 5 m 50 m 14 EDX(EDS) X 1- AES 1- XPS ESCA X 1- TOF-SIMS 1- FT-IR 1- KBr IR PVC 1 IR SEM-EDX Cl Cu Zn THF - LC 2 1 XPS 1- X XPS nm 1 TN442 C1s C-C C-H C=C C-OH C-O-C H-C=O C=O HO-C=O RO-C=O TN458 TOF-SIMS 1- 1 TN060 100 C 24 15 TOF-SIMS 2 TN152 TOF-SIMS GPC 1.
10 GPC SEC 1 LLDPE 1 LLDPE THF GPC >C=C< >C=O -N=N- -N=O -OH -OR -NH2 -NHR -SO3H -COOH CERI News 2005 2 229 NOx ABS PVC 16 290nm IR NMR ESR SEC LC/MS GC/MS GC/MS LC/MS NMR 1- News Letter M05006 2 M5-M8(2010)
