Al2O3 Material Safety Data Sheet Chemical Name: Alumina ...

1 P. 1 0 2 0He a lt hFireRe a c t iv it yP e rs o n a lP ro t e c t io n200 EMaterial Safety Data SheetAlumina MSDSS ection 1: Chemical Product and Company IdentificationProduct Name: AluminaCatalog Codes: SLA1906 CAS#: 1344-28-1 RTECS: BD1200000 TSCA: TSCA 8(b) inventory: Aluminum oxideCI#: Not : Alumina , Activated, 80-200 MeshChemical Name: Aluminium OxideChemical Formula: Al2O3 Contact , Smith , Texas 77396US Sales: 1-800-901-7247 International Sales: 1-281-441-4400 Order Online: (24HR Emergency Telephone), call:1-800-424-9300 International CHEMTREC, call: 1-703-527-3887 For non-emergency assistance, call: 1-281-441-4400 Section 2: Composition and Information on IngredientsComposition:NameCAS #% by WeightAluminum oxide1344-28-1100 Toxicological Data on Ingredients: Aluminum oxide LD50: Not available.

2 LC50: Not 3: Hazards IdentificationPotential Acute Health Effects: Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of Chronic Health Effects:CARCINOGENIC EFFECTS: A4 (Not classifiable for human or animal.) by ACGIH. MUTAGENIC EFFECTS: Not EFFECTS: Classified None. for human. DEVELOPMENTAL TOXICITY: Not available. Repeated orprolonged exposure is not known to aggravate medical 4: First Aid MeasuresEye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Get medical Contact:p. 2In case of contact, immediately flush skin with plenty of water.

3 Cover the irritated skin with an emollient. Remove contaminatedclothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical Skin Contact:Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical :If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get Inhalation: Not :Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconsciousperson. If large quantities of this Material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,tie, belt or Ingestion: Not 5: Fire and Explosion DataFlammability of the Product: Temperature: Not Points: Not Limits: Not of Combustion: Not Hazards in Presence of Various Substances: Not Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available.

4 Risks of explosion of the product inpresence of static discharge: Not Fighting Media and Instructions: Not Remarks on Fire Hazards: Chlorine Trifluoride reacts violently with Aluminum Oxide producing a Remarks on Explosion Hazards: Not 6: Accidental Release MeasuresSmall Spill:Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water onthe contaminated surface and dispose of according to local and regional authority Spill:Use a shovel to put the Material into a convenient waste disposal container. Finish cleaning by spreading water on thecontaminated surface and allow to evacuate through the sanitary system.

5 Be careful that the product is not present at aconcentration level above TLV. Check TLV on the MSDS and with local 7: Handling and StoragePrecautions:Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Ifyou feel unwell, seek medical attention and show the label when possible. Avoid contact with skin and eyes. Keep away fromincompatibles such as oxidizing agents, : Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 24 C ( F).p. 3 Section 8: Exposure Controls/Personal ProtectionEngineering Controls:Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommendedexposure limits.

6 If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminantsbelow the exposure Protection:Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Protection in Case of a Large Spill:Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoidinhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling Limits:TWA: 10 (mg/m3) from ACGIH (TLV) [United States] Inhalation Total. TWA: 10 (mg/m3) [Canada] Inhalation Total. TWA:5 (mg/m3) from OSHA (PEL) [United States] Inhalation Respirable.

7 TWA: 15 from OSHA (PEL) [United States] InhalationTotal. TWA: 10 [United Kingdom (UK)] Inhalation Total. TWA: 4 [United Kingdom (UK)] Inhalation localauthorities for acceptable exposure 9: Physical and Chemical PropertiesPhysical state and appearance: Solid. (Solid crystalline powder.)Odor: : Not Weight: g/moleColor: (1% soln/water): Not Point: 2980 C (5396 F)Melting Point: 2072 C ( F)Critical Temperature: Not Gravity: 4 (Water = 1)Vapor Pressure: Not Density: Not : Not Threshold: Not Dist. Coeff.: Not (in Water): Not Properties: Not :Very slightly soluble in cold water. Insoluble in hot water. Practically insoluble in non-polar organic solvents.

8 Slowly soluble inaqueous alkalie solution-forming hydroxides. Very slightly soluble in acid, 10: Stability and Reactivity DataStability: The product is 4 Instability Temperature: Not of Instability: Incompatible materialsIncompatibility with various substances: Reactive with oxidizing agents, : Non-corrosive in presence of Remarks on Reactivity:Chlorine Trifluoride reacts violently with Aluminum Oxide producing a flame. Ethylene oxide may polymerize violently when incontact with highly catalytic surfaces such as pure Aluminum Oxide. Reacts with hot chlorinated Remarks on Corrosivity: Not : Will not 11: Toxicological InformationRoutes of Entry: Inhalation.

9 To Animals:LD50: Not available. LC50: Not Effects on Humans:CARCINOGENIC EFFECTS: A4 (Not classifiable for human or animal.) by ACGIH. TERATOGENIC EFFECTS: ClassifiedNone. for Toxic Effects on Humans: Hazardous in case of skin contact (irritant), of ingestion, of Remarks on Toxicity to Animals: Not Remarks on Chronic Effects on Humans: May cause cancer (tumorigenic) according to animal data. No humandata Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: May cause skin irritation. Eyes: Nuissance Dust. Dust may cause mechanical eyeirritation. Inhalation: Nuissance Dust. Material is irritating to mucous membranes and upper respiratory tract.

10 May causelung injury. Ingestion: May be harmful if swallowed. Ingestion of large amounts mat cause gastrointestinal tract irritation. It isexpected to be a low hazard for normal industrial 12: Ecological InformationEcotoxicity: Not and COD: Not of Biodegradation:Possibly hazardous short term degradation products are not likely. However, long term degradation products may of the Products of Biodegradation: The product itself and its products of degradation are not Remarks on the Products of Biodegradation: Not 13: Disposal ConsiderationsWaste Disposal:Waste must be disposed of in accordance with federal, state and local environmental control 14: Transport Informationp.