APPENDIX D Laboratory Analytical Reports and Chain- of ...

1 Parsons APPENDIX D Laboratory Analytical Reports and Chain- of- custody Documents october 2009 semiannual Event aboratories, 29, 2009 Mary LucasParsons, West Walnut StreetPasadena, CA 91124-0002P09-10-1602 Calscience Work Order No.:Subject:DFSP NORWALK GWMC lient Reference:Dear Client:Enclosed is an Analytical report for the above-referenced project. The samplesincluded in this report were received 10/20/ 2009 and analyzed in accordance withthe attached otherwise noted, all Analytical testing was accomplished in accordance withthe guidelines established in our Quality Systems Manual, applicable standardoperating procedures, and other related documentation. The original report ofsubcontracted analysis, if any, is provided herein, and follows the standard Calsciencedata package. The results in this Analytical report are limited to the samples testedand any reproduction thereof must be made in its you have any questions regarding this report , please do not hesitate to contactthe ,Calscience EnvironmentalLaboratories, ClarkeProject Manager7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) ID: 1230 NELAP ID: 03220 CACSDLAC ID: 10109 SCAQMD ID: 93LA0830 Page 1 of 32 Work Order Case NarrativeProject Name: DFSP NORWALK GWMC alscience Work Order Number: 09-10-16021.

2 JP-5 EPA 8015B(M):The results for sample GMW-58 and the DUP sample were significantly different (2,200ug/L vs. 16,000 ug/L). This problem did not present itself with either the TPH gas or theVOCs analyses as those results compared quite favorably with each JP-5 bottles were examined and it was noted that the DUP bottle released asignificantly stronger odor upon opening the cap. The samples were both re-extracted andre-analyzed using aliquots obtained from the extra VOA vials remaining after the VOCs andTPH gas analyses had been completed. The discrepancy between the results was stillpresent after the re-analysis. As such, the original results are reported 2 of 32 Analytical Reportnvironmentalaboratories, , Received:100 West Walnut Street09-10-1602 Work Order No:Pasadena, CA 91124-0002 EPA 3510 CPreparation:EPA 8015B (M)Method:Project: DFSP NORWALK GWMPage 1 of 3 Lab SampleNumberDate/TimeCollectedQC Batch IDClient Sample NumberMatrixDatePreparedDate/TimeAnalyze dInstrument10/19/0910/22/0910/24/09 Aqueous091022B18 EXP-109-10-1602-2-JGC 2707:1908:03 QualParameterResultRLUnitsDFug/LTPH as JP51001 NDSurrogates:QualREC (%)Control LimitsDecachlorobiphenyl68-1409910/19/09 10/22/0910/24/09 Aqueous091022B18 EXP-209-10-1602-3-JGC 2707:3708:55 QualParameterResultRLUnitsDFug/LTPH as JP51001 NDSurrogates:QualREC (%)Control LimitsDecachlorobiphenyl68-1408710/19/09 10/22/0910/24/09 Aqueous091022B18 EXP-309-10-1602-4-JGC 2707:5509.

3 57 QualParameterResultRLUnitsDFug/LTPH as JP51001 NDSurrogates:QualREC (%)Control LimitsDecachlorobiphenyl68-1408010/19/09 10/22/0910/24/09 Aqueous091022B18 GMW-6109-10-1602-5-JGC 2708:1310:44 QualParameterResultRLUnitsDFug/LTPH as JP51001410 Surrogates:QualREC (%)Control LimitsDecachlorobiphenyl68-14095 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) - Reporting Limit , DF - Dilution Factor , Qual - QualifiersPage 3 of 32 Analytical Reportnvironmentalaboratories, , Received:100 West Walnut Street09-10-1602 Work Order No:Pasadena, CA 91124-0002 EPA 3510 CPreparation:EPA 8015B (M)Method:Project: DFSP NORWALK GWMPage 2 of 3 Lab SampleNumberDate/TimeCollectedQC Batch IDClient Sample NumberMatrixDatePreparedDate/TimeAnalyze dInstrument10/19/0910/22/0910/24/09 Aqueous091022B18 GMW-6009-10-1602-6-JGC 2708:3111:24 QualParameterResultRLUnitsDFug/LTPH as JP51001930 Surrogates:QualREC (%)Control LimitsDecachlorobiphenyl68-1408610/19/09 10/22/0910/24/09 Aqueous091022B18 GMW-4709-10-1602-7-JGC 2708:5012:12 QualParameterResultRLUnitsDFug/LTPH as JP510011200 Surrogates:QualREC (%)Control LimitsDecachlorobiphenyl68-1408310/19/09 10/22/0910/24/09 Aqueous091022B18 GMW-5709-10-1602-8-JGC 2709:0813:07 QualParameterResultRLUnitsDFug/LTPH as JP51001 NDSurrogates:QualREC (%)Control LimitsDecachlorobiphenyl68-1408210/19/09 10/22/0910/24/09 Aqueous091022B18 GMW-5809-10-1602-9-JGC 2709:2514.

4 33 QualParameterResultRLUnitsDFug/LTPH as JP510012200 Surrogates:QualREC (%)Control LimitsDecachlorobiphenyl68-14091 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) - Reporting Limit , DF - Dilution Factor , Qual - QualifiersPage 4 of 32 Analytical Reportnvironmentalaboratories, , Received:100 West Walnut Street09-10-1602 Work Order No:Pasadena, CA 91124-0002 EPA 3510 CPreparation:EPA 8015B (M)Method:Project: DFSP NORWALK GWMPage 3 of 3 Lab SampleNumberDate/TimeCollectedQC Batch IDClient Sample NumberMatrixDatePreparedDate/TimeAnalyze dInstrument10/19/0910/22/0910/24/09 Aqueous091022B18 DUP09-10-1602-10-JGC 2709:4300:00 QualParameterResultRLUnitsDFug/LTPH as JP5100116000 Surrogates:QualREC (%)Control LimitsDecachlorobiphenyl68-1409910/22/09 N/A10/24/09 Aqueous091022B18 Method Blank099-12-366-48GC 2703:07 QualParameterResultRLUnitsDFug/LTPH as JP51001 NDSurrogates:QualREC (%)Control LimitsDecachlorobiphenyl68-14096 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) - Reporting Limit , DF - Dilution Factor , Qual - QualifiersPage 5 of 32 Analytical Reportnvironmentalaboratories, , Received:100 West Walnut Street09-10-1602 Work Order No:Pasadena, CA 91124-0002 EPA 5030 BPreparation:EPA 8015B (M)Method:Project: DFSP NORWALK GWMPage 1 of 3 Lab SampleNumberDate/TimeCollectedQC Batch IDClient Sample NumberMatrixDatePreparedDate/TimeAnalyze dInstrument10/19/0910/22/0910/23/09 Aqueous091022B01 EXP-109-10-1602-2-GGC 1800:2708.

5 03 QualParameterResultRLUnitsDFug/LTPH as Gasoline1001 NDSurrogates:QualREC (%)Control Limits1,4-Bromofluorobenzene38-1348910/1 9/0910/22/0910/23/09 Aqueous091022B01 EXP-209-10-1602-3-GGC 1801:0308:55 QualParameterResultRLUnitsDFug/LTPH as Gasoline1001 NDSurrogates:QualREC (%)Control Limits1,4-Bromofluorobenzene38-1348910/1 9/0910/22/0910/23/09 Aqueous091022B01 EXP-309-10-1602-4-GGC 1801:3909:57 QualParameterResultRLUnitsDFug/LTPH as Gasoline1001 NDSurrogates:QualREC (%)Control Limits1,4-Bromofluorobenzene38-1348310/1 9/0910/22/0910/23/09 Aqueous091022B01 GMW-6109-10-1602-5-GGC 1802:1410:44-The sample chromatographic pattern for TPH does not match the chromatographic pattern of the specified standard. Quantitationof the unknown hydrocarbon(s) in the sample was based upon the specified (s):QualParameterResultRLUnitsDFug/LTPH as Gasoline1001620 Surrogates:QualREC (%)Control Limits1,4-Bromofluorobenzene38-134132 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) - Reporting Limit , DF - Dilution Factor , Qual - QualifiersPage 6 of 32 Analytical Reportnvironmentalaboratories, , Received:100 West Walnut Street09-10-1602 Work Order No:Pasadena, CA 91124-0002 EPA 5030 BPreparation:EPA 8015B (M)Method:Project: DFSP NORWALK GWMPage 2 of 3 Lab SampleNumberDate/TimeCollectedQC Batch IDClient Sample NumberMatrixDatePreparedDate/TimeAnalyze dInstrument10/19/0910/22/0910/23/09 Aqueous091022B01 GMW-6009-10-1602-6-GGC 1802:5011.

6 24-The sample chromatographic pattern for TPH does not match the chromatographic pattern of the specified standard. Quantitationof the unknown hydrocarbon(s) in the sample was based upon the specified (s):QualParameterResultRLUnitsDFug/LTPH as Gasoline10012600 Surrogates:QualREC (%)Control Limits21,4-Bromofluorobenzene38-13419210 /19/0910/22/0910/23/09 Aqueous091022B01 GMW-4709-10-1602-7-GGC 1803:2612:12 QualParameterResultRLUnitsDFug/LTPH as Gasoline1001170 Surrogates:QualREC (%)Control Limits1,4-Bromofluorobenzene38-13410110/ 19/0910/22/0910/23/09 Aqueous091022B01 GMW-5709-10-1602-8-GGC 1804:0113:07 QualParameterResultRLUnitsDFug/LTPH as Gasoline1001 NDSurrogates:QualREC (%)Control Limits1,4-Bromofluorobenzene38-1349010/1 9/0910/26/0910/26/09 Aqueous091026B01 GMW-5809-10-1602-9-IGC 1812:1514:33 QualParameterResultRLUnitsDFug/LTPH as Gasoline50051000 Surrogates.

7 QualREC (%)Control Limits1,4-Bromofluorobenzene38-13479 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) - Reporting Limit , DF - Dilution Factor , Qual - QualifiersPage 7 of 32 Analytical Reportnvironmentalaboratories, , Received:100 West Walnut Street09-10-1602 Work Order No:Pasadena, CA 91124-0002 EPA 5030 BPreparation:EPA 8015B (M)Method:Project: DFSP NORWALK GWMPage 3 of 3 Lab SampleNumberDate/TimeCollectedQC Batch IDClient Sample NumberMatrixDatePreparedDate/TimeAnalyze dInstrument10/19/0910/26/0910/26/09 Aqueous091026B01 DUP09-10-1602-10-IGC 1813:2600:00 QualParameterResultRLUnitsDFug/LTPH as Gasoline50051100 Surrogates:QualREC (%)Control Limits1,4-Bromofluorobenzene38-1348210/2 2/09N/A10/22/09 Aqueous091022B01 Method Blank099-12-247-3,618GC 1820:53 QualParameterResultRLUnitsDFug/LTPH as Gasoline1001 NDSurrogates:QualREC (%)Control Limits1,4-Bromofluorobenzene38-1348710/2 6/09N/A10/26/09 Aqueous091026B01 Method Blank099-12-247-3,623GC 1810:28 QualParameterResultRLUnitsDFug/LTPH as Gasoline1001 NDSurrogates:QualREC (%)Control Limits1,4-Bromofluorobenzene38-13481 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) - Reporting Limit , DF - Dilution Factor , Qual - QualifiersPage 8 of 32 Analytical Reportaboratories, , Received:100 West Walnut Street09-10-1602 Work Order No:Pasadena, CA 91124-0002 EPA 5030 BPreparation:EPA 8260 BMethod:Project:DFSP NORWALK GWMPage 1 of 12 Lab SampleNumberDate/TimeCollectedDatePrepar edDate/TimeAnalyzedQC Batch IDClient Sample NumberMatrixug/LUnits.

8 Instrument10/19/0910/21/0910/21/09 Aqueous091021L01TB09-10-1602-1-AGC/MS JJ16:4308:00-Results were evaluated to the MDL, concentrations >= to the MDL but < RL, if found, are qualified with a "J" (s):ResultResultParameterQualQualParamet erRLRLDFDFMDLMDLA cetone ,3-Dichloropropene ,3-Dichloropropene Chloride Disulfide ,1,1,2-Tetrachloroethane Tetrachloride ,1,2,2-Tetrachloroethane ,2,3-Trichlorobenzene ,2,4-Trichlorobenzene ,1,1-Trichloroethane ,1,2-Trichloro-1,2,2-Trifluoroethane ,1,2-Trichloroethane ,2-Dibromo-3-Chloropropane ,2-Dibromoethane ,2,3-Trichloropropane ,2-Dichlorobenzene ,2,4-Trimethylbenzene ,3-Dichlorobenzene ,3,5-Trimethylbenzene ,4-Dichlorobenzene Acetate Chloride ,1-Dichloroethane ,2-Dichloroethane ,1-Dichloroethene Ether (MTBE)

9 ,2-Dichloroethene Alcohol (TBA) ,2-Dichloroethene Ether (DIPE) ,2-Dichloropropane Ether (ETBE) ,3-Dichloropropane Ether (TAME) ,2-Dichloropropane ,1-Dichloropropene (%)REC (%)QualSurrogates:QualSurrogates:Control LimitsControlLimitsDibromofluoromethane8 0-1321201,2-Dichloroethane-d480-141116 Toluene-d880-120971,4-Bromofluorobenzene 76-12087 7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL:(714) 895-5494 FAX: (714) 894-7501RL - Reporting Limit , DF - Dilution Factor , Qual - 9 of 32 Analytical Reportaboratories, , Received:100 West Walnut Street09-10-1602 Work Order No:Pasadena, CA 91124-0002 EPA 5030 BPreparation:EPA 8260 BMethod:Project:DFSP NORWALK GWMPage 2 of 12 Lab SampleNumberDate/TimeCollectedDatePrepar edDate/TimeAnalyzedQC Batch IDClient Sample NumberMatrixug/LUnits:Instrument10/19/09 10/21/0910/21/09 Aqueous091021L01 EXP-109-10-1602-2-AGC/MS JJ17:1508:03-Results were evaluated to the MDL, concentrations >= to the MDL but < RL, if found, are qualified with a "J" (s).

10 ResultResultParameterQualQualParameterRL RLDFDFMDLMDLA cetone ,3-Dichloropropene ,3-Dichloropropene Chloride Disulfide ,1,1,2-Tetrachloroethane Tetrachloride ,1,2,2-Tetrachloroethane ,2,3-Trichlorobenzene ,2,4-Trichlorobenzene ,1,1-Trichloroethane ,1,2-Trichloro-1,2,2-Trifluoroethane ,1,2-Trichloroethane ,2-Dibromo-3-Chloropropane ,2-Dibromoethane ,2,3-Tri