Atlas of Eh-pH diagrams - eosremediation.com

1 Atlas of Eh-pH diagramsIntercomparison of thermodynamic databasesGeological Survey of Japan Open File Report Institute of Advanced Industrial Science and TechnologyResearch Center for Deep Geological EnvironmentsNaoto TAKENOMay 2005 Contents1 Introduction72 Databases73 Method for constructing Eh-pH FACT/FACTSAGE .. SUPCRT/FLASK-AQ .. LLNL/GWB .. JNC- HATCHES/FLASK-AQ .. OECD/NEA .. OECD-NEAupdate .. 104 Explanation of the diagrams and tables105 Reliability and uncertainty116 Description of the softwares and their execution environments111 List of Tables1 Listofsoftwaresused .. 112 133 174 ListofAlspecies.

2 215 ListofAmspecies .. 256 297 328 ListofBspecies .. 359 3910 4311 ListofBispecies .. 4612 4813 ListofCspecies(1) .. 5014 ListofCspecies(2) .. 5115 5516 5917 6318 ListofClspecies .. 6619 ListofCmspecies .. 6920 7321 7722 8123 8524 8825 9026 9327 ListofFspecies .. 9728 ListofFespecies .. 10129 ListofFrspecies .. 10430 10631 10832 11033 11234 11535 11836 12137 ListofInspecies .. 12438 ListofKspecies .. 12739 13140 ListofLispecies .. 13541 13842 ListofMgspecies .. 14143 ListofMnspecies .. 14544 ListofMospecies.

3 14945 ListofNspecies .. 15346 15747 16148 16549 ListofNispecies .. 16950 17351 176252 ListofPspecies .. 17953 18354 18755 19056 ListofPmspecies .. 19257 19458 19659 19860 20161 20562 20863 21064 21265 21566 21967 22368 ListofScspecies .. 22669 ListofSespecies .. 22970 ListofSispecies .. 23371 23772 24173 ListofSrspecies .. 24574 24875 25176 25477 25778 ListofTlspecies .. 26079 ListofTmspecies .. 26280 ListofUspecies .. 26581 ListofVspecies .. 26982 ListofWspecies .. 27283 ListofYspecies .. 27484 27685 27986 ListofZrspecies .. 2833 List of Figures1 LegendofEh-pHdiagram.

4 103 Eh-pHdiagramsofthesystemAc-O-H(1).. 144 Eh-pHdiagramsofthesystemAc-O-H(2).. 155 Eh-pHdiagramsofthesystemAg-O-H(1).. 186 Eh-pHdiagramsofthesystemAg-O-H(2).. 197 Eh-pHdiagramsofthesystemAl-O-H(1).. 228 Eh-pHdiagramsofthesystemAl-O-H(2).. 239 Eh-pHdiagramsofthesystemAm-O-H(1) .. 2610 Eh-pHdiagramsofthesystemAm-O-H(2) .. 2711 Eh-pHdiagramsofthesystemAs-O-H(1).. 3012 Eh-pHdiagramsofthesystemAs-O-H(2).. 3113 3314 Eh-pHdiagramsofthesystemB-O-H(1) .. 3615 Eh-pHdiagramsofthesystemB-O-H(2) .. 3716 Eh-pHdiagramsofthesystemBa-O-H(1).. 4017 Eh-pHdiagramsofthesystemBa-O-H(2).. 4118 Eh-pHdiagramsofthesystemBe-O-H(1).

5 4419 Eh-pHdiagramsofthesystemBe-O-H(2).. 4520 4721 4922 Eh-pHdiagramsofthesystemC-O-H(1) .. 5223 Eh-pHdiagramsofthesystemC-O-H(2) .. 5324 Eh-pHdiagramsofthesystemCa-O-H(1).. 5625 Eh-pHdiagramsofthesystemCa-O-H(2).. 5726 Eh-pHdiagramsofthesystemCd-O-H(1) .. 6027 Eh-pHdiagramsofthesystemCd-O-H(2) .. 6128 Eh-pHdiagramsofthesystemCe-O-H(1).. 6429 Eh-pHdiagramsofthesystemCe-O-H(2).. 6530 6731 Eh-pHdiagramsofthesystemCm-O-H(1) .. 7032 Eh-pHdiagramsofthesystemCm-O-H(2) .. 7133 Eh-pHdiagramsofthesystemCo-O-H(1).. 7434 Eh-pHdiagramsofthesystemCo-O-H(2).. 7535 Eh-pHdiagramsofthesystemCr-O-H(1).

6 7836 Eh-pHdiagramsofthesystemCr-O-H(2).. 7937 Eh-pHdiagramsofthesystemCs-O-H(1).. 8238 Eh-pHdiagramsofthesystemCs-O-H(2).. 8339 Eh-pHdiagramsofthesystemCu-O-H(1) .. 8640 Eh-pHdiagramsofthesystemCu-O-H(2) .. 8741 8942 9143 Eh-pHdiagramsofthesystemEu-O-H(1).. 9444 Eh-pHdiagramsofthesystemEu-O-H(2).. 9545 Eh-pHdiagramsofthesystemF-O-H(1) .. 9846 Eh-pHdiagramsofthesystemF-O-H(2) .. 9947 Eh-pHdiagramsofthesystemFe-O-H(1).. 10248 Eh-pHdiagramsofthesystemFe-O-H(2).. 10349 Eh-pHdiagramsofthesystemFr-O-H .. 10550 10751 Eh-pHdiagramsofthesystemGd-O-H .. 109452 11153 11354 Eh-pHdiagramsofthesystemHg-O-H(1).

7 11655 Eh-pHdiagramsofthesystemHg-O-H(2).. 11756 11957 Eh-pHdiagramsofthesystemI-O-H(1).. 12258 Eh-pHdiagramsofthesystemI-O-H(2).. 12359 Eh-pHdiagramsofthesystemIn-O-H .. 12560 Eh-pHdiagramsofthesystemK-O-H(1) .. 12861 Eh-pHdiagramsofthesystemK-O-H(2) .. 12962 Eh-pHdiagramsofthesystemLa-O-H(1).. 13263 Eh-pHdiagramsofthesystemLa-O-H(2).. 13364 Eh-pHdiagramsofthesystemLi-O-H(1) .. 13665 Eh-pHdiagramsofthesystemLi-O-H(2) .. 13766 13967 Eh-pHdiagramsofthesystemMg-O-H(1) .. 14268 Eh-pHdiagramsofthesystemMg-O-H(2) .. 14369 Eh-pHdiagramsofthesystemMn-O-H(1) .. 14670 Eh-pHdiagramsofthesystemMn-O-H(2) .. 14771 Eh-pHdiagramsofthesystemMo-O-H(1).

8 15072 Eh-pHdiagramsofthesystemMo-O-H(2) .. 15173 Eh-pHdiagramsofthesystemN-O-H(1) .. 15474 Eh-pHdiagramsofthesystemN-O-H(2) .. 15575 Eh-pHdiagramsofthesystemNa-O-H(1).. 15876 Eh-pHdiagramsofthesystemNa-O-H(2).. 15977 Eh-pHdiagramsofthesystemNb-O-H(1) .. 16278 Eh-pHdiagramsofthesystemNb-O-H(2) .. 16379 Eh-pHdiagramsofthesystemNd-O-H(1) .. 16680 Eh-pHdiagramsofthesystemNd-O-H(2) .. 16781 Eh-pHdiagramsofthesystemNi-O-H(1).. 17082 Eh-pHdiagramsofthesystemNi-O-H(2).. 17183 Eh-pHdiagramsofthesystemNp-O-H(1) .. 17484 Eh-pHdiagramsofthesystemNp-O-H(2) .. 17585 17786 Eh-pHdiagramsofthesystemP-O-H(1) .. 18087 Eh-pHdiagramsofthesystemP-O-H(2).

9 18188 Eh-pHdiagramsofthesystemPa-O-H(1).. 18489 Eh-pHdiagramsofthesystemPa-O-H(2).. 18590 Eh-pHdiagramsofthesystemPb-O-H(1).. 18891 Eh-pHdiagramsofthesystemPb-O-H(2).. 18992 19193 Eh-pHdiagramsofthesystemPm-O-H .. 19394 19595 19796 19997 Eh-pHdiagramsofthesystemPu-O-H(1).. 20298 Eh-pHdiagramsofthesystemPu-O-H(2).. 20399 Eh-pHdiagramsofthesystemRa-O-H(1).. 206100 Eh-pHdiagramsofthesystemRa-O-H(2).. 207101 209102 211103 2135104 Eh-pHdiagramsofthesystemRu-O-H(1) .. 216105 Eh-pHdiagramsofthesystemRu-O-H(2) .. 217106 Eh-pHdiagramsofthesystemS-O-H(1) .. 220107 Eh-pHdiagramsofthesystemS-O-H(2) .. 221108 Eh-pHdiagramsofthesystemSb-O-H(1).

10 224109 Eh-pHdiagramsofthesystemSb-O-H(2).. 225110 227111 Eh-pHdiagramsofthesystemSe-O-H(1).. 230112 Eh-pHdiagramsofthesystemSe-O-H(2).. 231113 Eh-pHdiagramsofthesystemSi-O-H(1) .. 234114 Eh-pHdiagramsofthesystemSi-O-H(2) .. 235115 Eh-pHdiagramsofthesystemSm-O-H(1) .. 238116 Eh-pHdiagramsofthesystemSm-O-H(2) .. 239117 Eh-pHdiagramsofthesystemSn-O-H(1).. 242118 Eh-pHdiagramsofthesystemSn-O-H(2).. 243119 Eh-pHdiagramsofthesystemSr-O-H(1).. 246120 Eh-pHdiagramsofthesystemSr-O-H(2).. 247121 249122 Eh-pHdiagramsofthesystemTc-O-H(1).. 252123 Eh-pHdiagramsofthesystemTc-O-H(2).. 253124 255125 Eh-pHdiagramsofthesystemTh-O-H(1) .. 258126 Eh-pHdiagramsofthesystemTh-O-H(2).