AZOLLA ZS 46 - Total

1 Quick-FDS [16640-39746-21185-010718] - 2013-07-22 - 11:02:26 MATERIAL SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006_____Page 1 / 12 SDS # : 31372 AZOLLA ZS 46+33 1 49 00 00 49 (24h/24, 7d/7)France - ORFILA T l : France : - PARIS : H pital Fernand Widal 200, rue du Faubourg Saint-Denis 75475 Paris C dex 10 , Tel : -MARSEILLE : Hopital Salvator, 249 bd Ste Marguerite 13274 Marseille cedex 5, Tel : - LYON : Hopital H douardHerriot, 5 place d'Arsonvil, 69437 Lyon cedex 3, Tel : - NANCY : Hopital central, 29 Av du Mal De Lattre deTassigny, 54000 Nancy, Tel : ou le SAMU : Tel ( 15 )SupplierTOTAL LUBRIFIANTS562 Avenue du Parc de L'ile92029 Nanterre CedexT l: +33 (0)1 41 35 40 00 Fax: +33 (0)1 41 35 84 71 Product nameAZOLLA ZS 462. HAZARDS Relevant identified uses of the substance or mixture and uses advised Product identifierFor further information, please Classification of the substance or mixtureNumberREGULATION (EC) No 1272/2008161 Contact PointFor the full text of the H-Statements mentioned in this Section, see Section usesHydraulic Emergency telephone numberPure Details of the supplier of the safety data sheet1.

2 IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKINGV ersion EUVersion Date: 2011-11-25 Date of the previous version: 2011-07-05 Quick-FDS [16640-39746-21185-010718] - 2013-07-22 - 11:02:26 _____Revision Date: 2011-11-25 AZOLLA ZS 46 Version 2 / 12 SDS # : 31372 The substance/mixture is non-dangerous in accordance with Directive(s) 67/548/EEC with amendments and/or 1999/45/EC withamendments3. COMPOSITION/INFORMATION ON MixtureLabelled according to:Hazardous ingredientsDo not contain hazardous substance nor substance with european workplace exposurelimits in concentration above regulatory thresholdsR-phrase(s) noneNot classified/No labelling requiredDIRECTIVE 67/548/EEC or 1999/45/ECAdditional informationProduct containing mineral oil with less than 3% DMSO extract as measured by IP 346S-phrase(s) noneFor the full text of the R-phrases mentioned in this Section, see Section 16 Symbol(s) Not ClassifiedFor the full text of the H-Statements mentioned in this Section, see Section Other hazards4.

3 FIRST AID MEASURESFor the full text of the R-phrases mentioned in this Section, see Section 16 Physical-Chemical PropertiesContaminated surfaces will be extremely Label elementsEnvironmental propertiesShould not be released into the EUQuick-FDS [16640-39746-21185-010718] - 2013-07-22 - 11:02:26 _____Page 3 / 12 SDS # : 31372 Revision Date: 2011-11-25 AZOLLA ZS 46 Version to physicianTreat symptomaticallyNot to fresh air5. FIRE-FIGHTING MEASURESSkin contactNot classified. High pressure injection of the products under the skin may have veryserious consequences even though no symptom or injury may be Extinguishing mediaGeneral adviceIngestionSuitable Extinguishing MediaCarbon dioxide (CO2). ABC powder. Foam. Water spray or NOT induce vomiting. Never give anything by mouth to an unconscious person. Call aphysician or Poison Control Center classified. Inhalation of vapors in high concentration may cause irritation of contactUnsuitable Extinguishing MediaDo not use a solid water stream as it may scatter and spread fireRemove contaminated clothing and shoes.

4 Wash skin with soap and water. Washcontaminated clothing before reuse. High pressure jets may cause skin damage. In this case, the casualty should be sentimmediately to CASE OF SERIOUS OR PERSISTENT CONDITIONS, CALL A DOCTOR OREMERGENCY MEDICAL Special hazards arising from the substance or mixtureIngestionNot classified. Ingestion may cause gastrointestinal irritation, nausea, vomiting Most important symptoms and effects, both acute and delayedSpecial HazardIncomplete combustion and thermolysis may produce gases of varying toxicity such ascarbon monoxide, carbon dioxide, various hydrocarbons, aldehydes and soot. These maybe highly dangerous if inhaled in confined spaces or at high thoroughly with plenty of water, also under the Indication of immediate medical attention and special treatment needed, if necessaryVersion Description of first-aid measuresInhalationEye contactQuick-FDS [16640-39746-21185-010718] - 2013-07-22 - 11:02:26 _____Page 4 / 12 SDS # : 31372 Revision Date: 2011-11-25 AZOLLA ZS 46 Version Protective EquipmentSee Section 8 for more detailOther informationCool containers / tanks with water spray.

5 Fire residues and contaminated fire extinguishingwater must be disposed of in accordance with local InformationWaste treatmentSee section 13Do not allow material to contaminate ground water system. Try to prevent the material fromentering drains or water courses. Local authorities should be advised if significant spillagescannot be Personal precautions, protective equipment and emergency proceduresWear self-contained breathing apparatus and protective suit7. HANDLING AND Methods and materials for containment and cleaning Precautions for safe handlingGeneral InformationDo not touch or walk through spilled material. Contaminated surfaces will be extremelyslippery. Use personal protective equipment. Ensure adequate ventilation. Remove allsources of on safe handlingWhen using, do not eat, drink or smoke. For personal protection see section 8. Use only inwell-ventilated areas. Do not breathe vapors or spray mist. Avoid contact with skin, eyesand for cleaning upDam up.

6 Contain spillage, and then collect with non-combustible absorbent material, ( , earth, diatomaceous earth, vermiculite) and place in container for disposal accordingto local / national regulations (see section 13). Keep in suitable, closed containers ACCIDENTAL RELEASE MEASURESP revention of fire and explosionTake precautionary measures against static discharges. Ground/bond containers, tanksand transfer/receiving Advice for Reference to other sectionsSpecial protective equipment forfire-fightersVersion Environmental precautionsQuick-FDS [16640-39746-21185-010718] - 2013-07-22 - 11:02:26 _____Page 5 / 12 SDS # : 31372 Revision Date: 2011-11-25 AZOLLA ZS 46 Version Conditions for safe storage, including any incompatibilitiesEnsure the application of strict rules of hygiene by the personnel exposed to the risk ofcontact with the product. Regular cleaning of equipment, work area and clothing isrecommended. Wash hands before breaks and immediately after handling the product.

7 Donot use abrasives, solvents or fuels. Do not dry hands with rags that have beencontaminated with product. Do not put product contaminated rags into workwear to Control parametersStrong oxidizing Exposure controlsExposure limitsoil mist : 10mg/m3, for 15 minutes; oil mist : 5mg/m3, for 8 hoursOccupational Exposure ControlsEngineering MeasuresApply technical measures to comply with the occupational exposure limits. When workingin confined spaces (tanks, containers, etc.), ensure that there is a supply of air suitable forbreathing and wear the recommended Specific end usesTechnical measures/StorageconditionsPersonal Protective EquipmentKeep away from food, drink and animal feedingstuffs. Keep in a bunded area. Keepcontainer tightly closed. Keep preferably in the original container. Otherwise reproduce allindication of the regulation label on the new container. Do not remove the hazard labels ofthe containers (even if they are empty).

8 Design the installations in order to avoid accidentalemissions of product (due to seal breakage, for example) onto hot casings or electricalcontacts. Protect from frost, heat and sunlight. Protect from InformationIf the product is used in mixtures, it is recommended that you contact the appropriateprotective equipment suppliers. These recommendations apply to the product as section 16 Hygiene measuresVersion EU8. EXPOSURE CONTROLS/PERSONAL PROTECTIONQ uick-FDS [16640-39746-21185-010718] - 2013-07-22 - 11:02:26 _____Revision Date: 2011-11-25 AZOLLA ZS 46 Version 6 / 12 SDS # : 31372 Wear suitable protective clothing. Protective shoes or boots. Long sleeved InformationThe product should not be allowed to enter drains, water courses or the soilWhen workers are facing concentrations above the exposure limit they must useappropriate certified respirators. Respirator with combination filter for vapour/particulate(EN 141). The use of breathing apparatus must comply strictly with the manufacturer'sinstructions and the regulations governing their choices and Protection9.

9 PHYSICAL AND CHEMICAL PROPERTIESIf splashes are likely to occur, wear:. Safety glasses with ProtectionHydrocarbon-proof gloves. Please observe the instructions regarding permeability andbreakthrough time which are provided by the supplier of the gloves. Also take intoconsideration the specific local conditions under which the product is used, such as thedanger of cuts, abrasion. If used in solution, or mixed with other substances, and underconditions which differ from EN 374, contact the supplier of the EC approved Information on basic physical and chemical propertiesColoryellowPhysical State @20 CliquidOdorCharacteristicRespiratory protectionEnvironmental exposure controlsSkin and body protectionCleveland Open Cup (COC).Solubility in other solventsRemarksNo information availableNo information availableEvaporation rateMethodCleveland Open Cup (COC)Flammability Limits in AirlogPowDensityNo information available880 kg/m3No information availableVapor Pressure@ 15 CNo information availablepHASTM 1298 Autoignition temperatureFlash pointValuesWater solubility> 392 FNo information availableNo information availablePropertyNot applicableNot applicable> 200 CNot applicableVersion EUVapor densityBoiling point/boiling rangeQuick-FDS [16640-39746-21185-010718] - 2013-07-22 - 11:02:26 _____Page 7 / 12 SDS # : 31372 Revision Date: 2011-11-25 AZOLLA ZS 46 Version Hazardous Decomposition Products10.

10 STABILITY AND Possibility of hazardous reactionsHazardous Decomposition ProductsNone under normal useHazardous Reactions11. TOXICOLOGICAL INFORMATIONNone under normal Information on toxicological Conditions to AvoidAcute toxicity Local effects Product Other informationConditions to AvoidHeat (temperatures above flash point), sparks, ignition points, flames, static contactNot classified. High pressure injection of the products under the skin may have veryserious consequences even though no symptom or injury may be Chemical stabilityEye contactNot Incompatible MaterialsStabilityStable under recommended storage conditionsMaterials to AvoidStrong oxidizing PropertiesNot applicable46 mm2/sViscosity, kinematicExplosive propertiesNot explosivePossibility of hazardous reactionsNot applicable@ 40 CVersion EUQuick-FDS [16640-39746-21185-010718] - 2013-07-22 - 11:02:26 _____Page 8 / 12 SDS # : 31372 Revision Date: 2011-11-25 AZOLLA ZS 46 Version classified.