AZOLLA ZS 68 - Total

1 Quick-FDS [16640-39753-12926-012351] - 2013-07-22 - 11:02:33 MATERIAL SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006_____Page 1 / 12 SDS # : 31515 AZOLLA ZS 68+33 1 49 00 00 49 (24h/24, 7d/7)France - ORFILA T l : France : - PARIS : H pital Fernand Widal 200, rue du Faubourg Saint-Denis 75475 Paris C dex 10 , Tel : -MARSEILLE : Hopital Salvator, 249 bd Ste Marguerite 13274 Marseille cedex 5, Tel : - LYON : Hopital H douardHerriot, 5 place d'Arsonvil, 69437 Lyon cedex 3, Tel : - NANCY : Hopital central, 29 Av du Mal De Lattre deTassigny, 54000 Nancy, Tel : ou le SAMU : Tel ( 15 )SupplierTOTAL LUBRIFIANTS562 Avenue du Parc de L'ile92029 Nanterre CedexT l: +33 (0)1 41 35 40 00 Fax: +33 (0)1 41 35 84 71 Product nameAZOLLA ZS 682. HAZARDS Relevant identified uses of the substance or mixture and uses advised Product identifierFor further information, please Classification of the substance or mixtureNumberREGULATION (EC) No 1272/2008164 Contact PointFor the full text of the H-Statements mentioned in this Section, see Section usesHydraulic 67/548/EEC or 1999/45/ECFor the full text of the R-phrases mentioned in this Section, see Section Emergency telephone numberPure Details of the supplier of the safety data sheet1.

2 IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKINGV ersion EUVersion Date: 2011-11-25 Date of the previous version: 2011-11-16 Quick-FDS [16640-39753-12926-012351] - 2013-07-22 - 11:02:33 _____Revision Date: 2011-11-25 AZOLLA ZS 68 Version 2 / 12 SDS # : MixtureThe substance/mixture is non-dangerous in accordance with Directive(s) 67/548/EEC with amendments and/or 1999/45/EC withamendmentsR-phrase(s) noneHazardous ingredientsDo not contain hazardous substance nor substance with european workplace exposurelimits in concentration above regulatory Label elementsS-phrase(s) noneAdditional informationProduct containing mineral oil with less than 3% DMSO extract as measured by IP 346 Symbol(s) Not ClassifiedFor the full text of the R-phrases mentioned in this Section, see Section Other hazardsFor the full text of the H-Statements mentioned in this Section, see Section FIRST AID MEASURESP hysical-Chemical PropertiesContaminated surfaces will be extremely Description of first-aid measuresEnvironmental propertiesShould not be released into the according to:Not classified/No labelling required3.

3 COMPOSITION/INFORMATION ON INGREDIENTSV ersion EUQuick-FDS [16640-39753-12926-012351] - 2013-07-22 - 11:02:33 _____Page 3 / 12 SDS # : 31515 Revision Date: 2011-11-25 AZOLLA ZS 68 Version contactNot NOT induce vomiting. Never give anything by mouth to an unconscious person. Call aphysician or Poison Control Center Extinguishing mediaRinse thoroughly with plenty of water, also under the Extinguishing MediaCarbon dioxide (CO2). ABC powder. Foam. Water spray or classified. Inhalation of vapors in high concentration may cause irritation of Extinguishing MediaDo not use a solid water stream as it may scatter and spread fireGeneral Most important symptoms and effects, both acute and delayedIngestionNot classified. Ingestion may cause gastrointestinal irritation, nausea, vomiting Special hazards arising from the substance or mixtureInhalationSpecial HazardIncomplete combustion and thermolysis may produce gases of varying toxicity such ascarbon monoxide, carbon dioxide, various hydrocarbons, aldehydes and soot.

4 These maybe highly dangerous if inhaled in confined spaces or at high to fresh Indication of immediate medical attention and special treatment needed, if necessaryIN CASE OF SERIOUS OR PERSISTENT CONDITIONS, CALL A DOCTOR OREMERGENCY MEDICAL Advice for fire-fightersNot contactNotes to physicianTreat symptomaticallyVersion EUSkin contactRemove contaminated clothing and shoes. Wash skin with soap and water. Washcontaminated clothing before reuse. High pressure jets may cause skin damage. In this case, the casualty should be sentimmediately to FIRE-FIGHTING MEASURESQ uick-FDS [16640-39753-12926-012351] - 2013-07-22 - 11:02:33 _____Page 4 / 12 SDS # : 31515 Revision Date: 2011-11-25 AZOLLA ZS 68 Version ACCIDENTAL RELEASE MEASURESW aste treatmentSee section 13 Cool containers / tanks with water spray.

5 Fire residues and contaminated fire extinguishingwater must be disposed of in accordance with local Methods and materials for containment and cleaning up7. HANDLING AND STORAGEDo not touch or walk through spilled material. Contaminated surfaces will be extremelyslippery. Use personal protective equipment. Ensure adequate ventilation. Remove allsources of Precautions for safe handlingMethods for cleaning upDam up. Contain spillage, and then collect with non-combustible absorbent material, ( , earth, diatomaceous earth, vermiculite) and place in container for disposal accordingto local / national regulations (see section 13). Keep in suitable, closed containers on safe handlingWhen using, do not eat, drink or smoke. For personal protection see section 8.

6 Use only inwell-ventilated areas. Do not breathe vapors or spray mist. Avoid contact with skin, eyesand protective equipment Environmental precautionsPrevention of fire and explosionTake precautionary measures against static discharges. Ground/bond containers, tanksand transfer/receiving Reference to other Personal precautions, protective equipment and emergency proceduresWear self-contained breathing apparatus and protective suitOther informationPersonal Protective EquipmentVersion EUSee Section 8 for more detailGeneral InformationDo not allow material to contaminate ground water system. Try to prevent the material fromentering drains or water courses. Local authorities should be advised if significant spillagescannot be [16640-39753-12926-012351] - 2013-07-22 - 11:02:33 _____Page 5 / 12 SDS # : 31515 Revision Date: 2011-11-25 AZOLLA ZS 68 Version to AvoidStrong oxidizing Control Exposure controlsExposure limitsoil mist : 10mg/m3, for 15 minutes; oil mist : 5mg/m3, for 8 hoursTechnical Specific end usesOccupational Exposure ControlsEngineering MeasuresApply technical measures to comply with the occupational exposure limits.

7 When workingin confined spaces (tanks, containers, etc.), ensure that there is a supply of air suitable forbreathing and wear the recommended away from food, drink and animal feedingstuffs. Keep in a bunded area. Keepcontainer tightly closed. Keep preferably in the original container. Otherwise reproduce allindication of the regulation label on the new container. Do not remove the hazard labels ofthe containers (even if they are empty). Design the installations in order to avoid accidentalemissions of product (due to seal breakage, for example) onto hot casings or electricalcontacts. Protect from frost, heat and sunlight. Protect from measuresPersonal Protective Conditions for safe storage, including any incompatibilitiesLegendGeneral InformationIf the product is used in mixtures, it is recommended that you contact the appropriateprotective equipment suppliers.

8 These recommendations apply to the product as section 168. EXPOSURE CONTROLS/PERSONAL PROTECTIONE nsure the application of strict rules of hygiene by the personnel exposed to the risk ofcontact with the product. Regular cleaning of equipment, work area and clothing isrecommended. Wash hands before breaks and immediately after handling the product. Donot use abrasives, solvents or fuels. Do not dry hands with rags that have beencontaminated with product. Do not put product contaminated rags into workwear EUQuick-FDS [16640-39753-12926-012351] - 2013-07-22 - 11:02:33 _____Page 6 / 12 SDS # : 31515 Revision Date: 2011-11-25 AZOLLA ZS 68 Version protection9. PHYSICAL AND CHEMICAL PROPERTIESHand ProtectionHydrocarbon-proof gloves. Please observe the instructions regarding permeability andbreakthrough time which are provided by the supplier of the gloves.

9 Also take intoconsideration the specific local conditions under which the product is used, such as thedanger of cuts, abrasion. If used in solution, or mixed with other substances, and underconditions which differ from EN 374, contact the supplier of the EC approved Information on basic physical and chemical propertiesWhen workers are facing concentrations above the exposure limit they must useappropriate certified respirators. Respirator with combination filter for vapour/particulate(EN 141). The use of breathing apparatus must comply strictly with the manufacturer'sinstructions and the regulations governing their choices and State @20 CliquidOdorCharacteristicSkin and body protectionEnvironmental exposure controlsWear suitable protective clothing. Protective shoes or boots.

10 Long sleeved InformationThe product should not be allowed to enter drains, water courses or the soilEye ProtectionIf splashes are likely to occur, wear:. Safety glasses with Open Cup (COC)Flammability Limits in AirlogPowDensityNo information available885 kg/m3No information availableVapor Pressure@ 15 CNo information availablepHAutoignition temperatureFlash pointValuesWater solubility>= 410 FNo information availableNot applicablePropertyNot applicableNo information availableViscosity, kinematic>= 210 CNot applicable68 mm2/sVapor densityBoiling point/boiling range@ 40 CCleveland Open Cup (COC).Solubility in other solventsRemarksISO 3104No information availableVersion EUNo information availableEvaporation rateQuick-FDS [16640-39753-12926-012351] - 2013-07-22 - 11:02:33 _____Revision Date: 2011-11-25 AZOLLA ZS 68 Version 7 / 12 SDS # : ReactivityHazardous ReactionsHazardous Decomposition ProductsNone under normal useNone under normal processing11.