BARIUM SULFATE PRECIPITATED - BLANC FIXE Brilliant

1 SAFETY DATA SHEETBARIUM SULFATE PRECIPITATED - BLANC fixe BrilliantRevision Date 06/01/2018P01000021799 Version : / CA ( Z8 ) 1 / 15 SECTION 1: Identification of the substance/mixture and of the Product identifier-Trade nameBARIUM SULFATE PRECIPITATED - BLANC fixe Brilliant -Chemical nameBarium SULFATE -Molecular Relevant identified uses of the substance or mixture and uses advised againstUses of the Substance / Mixture-Manufacture of pigments-Manufacture of plastics products-Manufacture of paper-Manufacture of batteries and accumulators-Industrial manufacture of coatings and inks-Manufacture of paints and coatings-Industrial and professional use of paints and coatings-Cosmetics-FillersUses advised Details of the supplier of the safety data sheetCompanySOLVAY FLUORIDES, LLC3737 Buffalo Speedway,Suite 800,Houston, TX 77098 USATel.

2 Emergency telephoneFOR EMERGENCIES INVOLVING A SPILL, LEAK, FIRE, EXPOSURE OR ACCIDENT, CONTACT CHEMTREC (24-Hour Number): 800-424-9300 within the United States and Canada, or 703-527-3887 for international collect 2: Hazards identificationAlthough WHMIS has not adopted the environmental portion of the GHS regulations, this document may include information on environmental Classification of the substance or mixture-Not classified as hazardous product under the regulation Label elementsHazardous Products Regulations (WHMIS 2015)-Not labelled as hazardous product under the regulation DATA SHEETBARIUM SULFATE PRECIPITATED - BLANC fixe BrilliantRevision Date 06/01/2018P01000021799 Version : / CA ( Z8 ) 2 / Other hazards which do not result in classification-Product dust may be irritating to eyes, skin and respiratory risk of irreversible effects through of pulmonary overload (respirable particulates)SECTION 3: Composition/information on SubstanceWHMIS Hazardous Ingredients and ImpuritiesChemical nameIdentification [% wt/wt or V/V] BARIUM sulfate7727-43-7 >= 95 - < MixtureNot applicable, this product is a 4.

3 First aid Description of first-aid measuresIn case of inhalation -Move to fresh symptoms persist, call a case of skin contact -Wash off with soap and case of eye contact -Rinse thoroughly with plenty of water, also under the eye irritation persists, consult a case of ingestion -Rinse mouth with NOT induce symptoms persist, call a physician or Poison Control Center Most important symptoms and effects, both acute and delayedIn case of inhalationEffects-May cause nose, throat, and lung or prolonged exposure-Risk of pulmonary overload (respirable particulates)In case of skin contactEffects-No known Toxicological Information Section DATA SHEETBARIUM SULFATE PRECIPITATED - BLANC fixe BrilliantRevision Date 06/01/2018P01000021799 Version : / CA ( Z8 ) 3 / 15In case of eye contactEffects-Contact with eyes may cause case of ingestionEffects-Ingestion may cause gastrointestinal irritation, nausea, vomiting and Indication of any immediate medical attention and special treatment neededNotes to physician -If accidentally swallowed obtain immediate medical attention.

4 -When symptoms persist or in all cases of doubt seek medical advice. SECTION 5: Firefighting Extinguishing mediaSuitable extinguishing media -Use extinguishing measures that are appropriate to local circumstances and the surrounding extinguishing media -None Special hazards arising from the substance or mixtureSpecific hazards during fire fighting-Not combustion products:- BARIUM oxide-Sulfur Advice for firefightersSpecial protective equipment for fire-fighters-In the event of fire, wear self-contained breathing 6: Accidental release Personal precautions, protective equipment and emergency proceduresAdvice for non-emergency personnel-Evacuate personnel to safe dust for emergency responders-Use personal protective up to prevent slipping further leakage or Environmental precautionsSAFETY DATA SHEETBARIUM SULFATE PRECIPITATED - BLANC fixe BrilliantRevision Date 06/01/2018P01000021799 Version : / CA ( Z8 ) 4 / 15-Should not be released into the authorities should be advised if significant spillages cannot be Methods and materials for containment and cleaning up-Sweep up and shovel into suitable containers for Reference to other sections-Refer to protective measures listed in sections 7 and 7.

5 Handling and Precautions for safe handling-Ensure adequate measures-When using do not eat, drink or hands before breaks and at the end of in accordance with good industrial hygiene and safety Conditions for safe storage, including any incompatibilitiesTechnical measures/Storage conditions-Store in original in a well-ventilated in a dry container materialSuitable Specific end use(s)-Contact your supplier for additional informationSECTION 8: Exposure controls/personal protectionIntroductory Remarks: These recommendations provide general guidance for handling this product. Because specific work environments and material handling practices vary, safety procedures should be developed for each intended application. Assistance with selection, use and maintenance of worker protection equipment is generally available from equipment Control parametersComponents with workplace occupational exposure limitsConsult local authorities for acceptable exposure typeValueBasisParticles not otherwise specified (PNOS)TWA10 mg/m3 American Conference of Governmental Industrial HygienistsSAFETY DATA SHEETBARIUM SULFATE PRECIPITATED - BLANC fixe BrilliantRevision Date 06/01/2018P01000021799 Version : / CA ( Z8 ) 5 / 15 Form of exposure : Inhalable fractionThe goal of the TLV -CS Committee is to recommend TLVs for all substances for which there is evidence of health effects at airborne concentrations encountered in the workplace.

6 When a sufficient body of evidence exists for a particular substance, a TLV is established. Thus, by definition the substances covered by this recommendation are those for which little data exist. The recommendation at the end of this Appendix is supplied as a guideline rather than a TLV because it is not possible to meet the standard level of evidence used to assign a TLV . In addition, the PNOS TLV and its predecessors have been misused in the past and applied to any unlisted particles rather than those meeting the criteria listed below. The recommendations in this Appendix apply to particles that: - Do not have an applicable TLV ; - Are insoluble or poorly soluble in water (or, preferably, in aqueous lung fluid if data are available); and - Have low toxicity ( are not cytotoxic, genotoxic or otherwise chemically reactive with lung tissue, and do not emit ionizing radiation, cause immune sensitization, or cause toxic effects other than by inflammation or the mechanism of 'lung overload').

7 ACGIH believes that even biologically inert, insoluble, or poorly soluble particles may have adverse effects and recommends that airborne concentrations should be kept below 3 mg/m , respirable particles, and 10 mg/m , inhalable particles, until such time as a TLV is set for a particular not otherwise specified (PNOS)TWA3 mg/m3 American Conference of Governmental Industrial HygienistsForm of exposure : Respirable fractionThe goal of the TLV -CS Committee is to recommend TLVs for all substances for which there is evidence of health effects at airborne concentrations encountered in the workplace. When a sufficient body of evidence exists for a particular substance, a TLV is established. Thus, by definition the substances covered by this recommendation are those for which little data exist.

8 The recommendation at the end of this Appendix is supplied as a guideline rather than a TLV because it is not possible to meet the standard level of evidence used to assign a TLV . In addition, the PNOS TLV and its predecessors have been misused in the past and applied to any unlisted particles rather than those meeting the criteria listed below. The recommendations in this Appendix apply to particles that: - Do not have an applicable TLV ; - Are insoluble or poorly soluble in water (or, preferably, in aqueous lung fluid if data are available); and - Have low toxicity ( are not cytotoxic, genotoxic or otherwise chemically reactive with lung tissue, and do not emit ionizing radiation, cause immune sensitization, or cause toxic effects other than by inflammation or the mechanism of 'lung overload').

9 ACGIH believes that even biologically inert, insoluble, or poorly soluble particles may have adverse effects and recommends that airborne concentrations should be kept below 3 mg/m , respirable particles, and 10 mg/m , inhalable particles, until such time as a TLV is set for a particular with workplace occupational exposure limitsIngredientsValue typeValueBasisBarium sulfateTWA5 mg/m3 American Conference of Governmental Industrial HygienistsForm of exposure : Inhalable fractionPneumoconiosis, The value is for particulate matter containing no asbestos and < 1% crystalline silicaSAFETY DATA SHEETBARIUM SULFATE PRECIPITATED - BLANC fixe BrilliantRevision Date 06/01/2018P01000021799 Version : / CA ( Z8 ) 6 / Exposure controlsControl measuresEngineering measures-Provide appropriate exhaust ventilation at places where dust is technical measures to comply with the occupational exposure protection measuresRespiratory protection-Use only respiratory protection that conforms to international/ national NIOSH approved respiratory with a particle filter (EN 143)Hand protection-Wear suitable material-PVC-Natural RubberEye protection-Dust proof goggles, if and body protection-Dust impervious protective suitHygiene measures-When using do not eat, drink or hands before breaks and at the end of in accordance with good industrial hygiene and safety 9.

10 Physical and chemical propertiesPhysical and Chemical properties here represent typical properties of this product. Contact the business area using the Product information phone number in Section 1 for its exact specifications. Information on basic physical and chemical propertiesAppearanceForm: Crystalline powder Physical state:solid Color: white Particle size: ca. - 6 mMean diameterOdorodorless Odor ThresholdNo data availableMolecular weight g/molpHca. : Not applicableSAFETY DATA SHEETBARIUM SULFATE PRECIPITATED - BLANC fixe BrilliantRevision Date 06/01/2018P01000021799 Version : / CA ( Z8 ) 7 / 15 Melting point/freezing pointDecomposition: yesNot applicableInitial boiling point and boiling rangeBoiling point/boiling range: Thermal decomposition: yesNot applicableFlash pointNot applicable Evaporation rate (Butylacetate = 1)Not applicableFlammability (solid, gas)No data availableFlammability (liquids)No data availableFlammability / Explosive limitExplosiveness:Not explosiveAutoignition temperatureNot applicableVapor pressureNot applicableVapor densityNot applicableDensityRelative SolubilityWater solubility: mg/l ( 77 F (25 C))insolublePartition coefficient.