BRENNTAG SAFETY DATA SHEET - Hill Brothers …

1 Product#: 872691 From: BRENNTAG PACIFIC INC. To: HILL Brothers CHEMICAL CO Monday June 08, 2015 BRENNTAGSAFETY data SHEETAMMONIUM BIFLUOR1DE 98% CRY PROPER AND LEGAL PURPOSESNone IdentificationProduct identifierOther means of identificationRecommended useRecommended restrictionsManufacturer/lmporter/Suppli er/Distributor informationManufacturerCompany name BRENNTAG Pacific 10747 Patterson PlaceSanta Fe Springs, CA 90670 Telephone 562-903-9626E-mail Not phone number 800-424-9300 CHEMTREC2. Hazard(s) identificationPhysical hazardsHealth hazardsEnvironmental hazardsOSHA defined hazardsLabel elementsSignal wordHazard statementPrecautionary statementPreventionResponseStorageDispos alHazard(s) not otherwiseclassified (HNOC)Supplemental informationNot toxicity, oralAcute toxicity, inhalationSkin corrosion/irritationSerious eye damage/eye irritationNot 3 Category 4 Category 1 Category 1 DangerToxic if swallowed.

2 Causes severe skin burns and eye damage. Causes serious eye if not breathe mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke whenusing this product. Use only outdoors or in a well-ventilated area. Wear eye protection/faceprotection. Wear protective gloves/protective clothing/eye protection/face swallowed: Immediately call a poison center/doctor. If swallowed: Rinse mouth. Do NOT inducevomiting. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin withwater/shower. If inhaled: Remove person to fresh air and keep comfortable for breathing. If ineyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easyto do. Continue rinsing. Immediately call a poison center/doctor. Wash contaminated clothingbefore locked of contents/container in accordance with local/regional/national/international of the mixture consists of component(s) of unknown acute oral toxicity.

3 2% of the mixtureconsists of component(s) of unknown acute inhalation Composition/information on ingredientsMixturesMaterial name: ammonium BIFLUORIDE 98% CRY GSO672691 Version*: 01 Issue date: 05-21-2015 SDSUS1 IIProduct #: 872691 From: BRENNTAG PACIFIC INC. To: HILL Brothers CHEMICAL CO Monday, June 08, 2015 Chemical nameCommon name and synonymsCAS numberAMMONIUM FLUORIDE((NH4)(HF2))1341 -49-798 Other components below reportable levels^Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade , First-aid measuresInhalationSkin contactEye contactIngestionMost importantsymptoms/effects, acute anddelayedIndication of immediatemedical attention and specialtreatment neededGeneral informationRemove victim to fresh air and keep at rest in a position comfortable for breathing, Oxygen orartificial respiration if needed. Call a POISON CENTER or doctor/physician if you feel off immediately all contaminated clothing.

4 Rinse skin with water/shower. Call a physician orpoison control center immediately. Chemical burns must be treated by a physician. Washcontaminated clothing before reuse,Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. Call a physician or poison control center a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. Ifvomiting occurs, keep head low so that stomach content doesn't get into the lungs. Do not usemouth-to-mouth method if victim ingested the substance. Induce artificial respiration with the aid ofa pocket mask equipped with a one-way valve or other proper respiratory medical pain and severe corrosive skin damage. Causes serious eye damage. Symptoms mayinclude stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage includingblindness could general supportive measures and treat symptomatically.

5 Chemical burns: Flush with waterimmediately, While flushing, remove clothes which do not adhere to affected area, Call anambulance. Continue flushing during transport to hospital. Keep victim warm. Keep victim underobservation. Symptoms may be delayed,Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Show this SAFETY data SHEET to the doctor in attendance,5. Fire-fighting measuresSuitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire,mediaSpecific hazards arising from During fire, gases hazardous to health may be chemicalSpecial protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of precautions for firefightersFire fighting Move containers from fire area if you can do so without methods Use standard firefighting procedures and consider the hazards of other involved fire hazards No unusual fire or explosion hazards Accidental release measuresPersonal precautions,protective equipment andemergency proceduresMethods and materials forcontainment and cleaningupEnvironmental precautions7.

6 Handling and storagePrecautions for safe handlingKeep unnecessary personnel away, Keep people away from and upwind of spill/leak, Wearappropriate protective equipment and clothing during clean-up. Do not breathe mist or vapor. Donot touch damaged containers or spilled material unless wearing appropriate protective adequate ventilation. Local authorities should be advised if significant spillages cannot becontained, For personal protection, see section 8 of the Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this ispossible. Cover with plastic SHEET to prevent spreading. Absorb in vermiculite, dry sand or earthand place into containers. Following product recovery, flush area with Spills: Wipe up with absorbent material ( cloth, fleece), Clean surface thoroughly toremove residual return spills to original containers for re-use. For waste disposal, see section 13 of the discharge into drains, water courses or onto the not breathe mist or vapor.

7 Do not get in eyes, on skin, or on clothing. Do not taste or using, do not eat, drink or smoke. Use only outdoors or in a well-ventilated area. Wearappropriate personal protective equipment. Wash hands thoroughly after handling. Observe goodindustrial hygiene practices,Material name: ammonium BIFLUORIDE 98% CRY GSO SDS us872691 Version #: 01 Issue date: 05-21-2015 2/7 Product#: 872691 From: BREMNTAG PACIFIC INC. To: HILL Brothers CHEMICAL CO Monday June 08, 2015 Conditions for safe storage,including any incompatibilitiesStore locked up, Store in original tightly closed container. Store in a well-ventilated place.

8 Storeaway from incompatible materials (see Section 10 of the SDS).8. Exposure controls/personal protectionOccupational exposure limits No exposure limits noted for ingredient(s).Biological limit values No biological exposure limits noted for the ingredient(s).Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation ratescontrols should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,or other engineering controls to maintain airborne levels below recommended exposure limits. Ifexposure limits have not been established, maintain airborne levels to an acceptable level. Eyewash facilities and emergency shower must be available when handling this protection measures, such as personal protective equipmentEye/face protection Wear SAFETY glasses with side shields (or goggles) and a face protectionHand protectionOtherRespiratory protectionThermal hazardsGeneral hygieneconsiderationsWear appropriate chemical resistant gloves.

9 Suitable gloves can be recommended by the appropriate chemical resistant case of insufficient ventilation, wear suitable respiratory appropriate thermal protective clothing, when necessary,Keep away from food and drink. Always observe good personal hygiene measures, such aswashing after handling the material and before eating, drinking, and/or smoking. Routinely washwork clothing and protective equipment to remove Physical and chemical propertiesAppearancePhysical stateFormColorOdorOdor thresholdpHMelting point/freezing pointInitial boiling point and boilingrangeFlash pointEvaporation rateFlammability (solid, gas)Upper/lower flammability or explosive limitsFlammability limit - lower Not "F ( C) estimated464 F (240 C) estimatedNot limit - upper Not limit - lower (%)Explosive limit - upper (%)Vapor pressureVapor densityRelative densitySolubility(ies)Solubility (water)Partition coefficient(n-octanol/water)Auto-ignitio n temperatureDecomposition temperatureViscosityNot hPa estimatedNot name: ammonium BIFLUORIDE 98% CRY GSO872691 Version*: 01 Issue date: 05-21-2015 SDS US3/7 Pro duct #:872691>From: BRENNTAG PACIFIC INC.

10 To: HILL Brothers CHEMICAL CO Monday June 08, 2015 Other informationDensityExplosive propertiesOxidizing propertiesSpecific gravity10. Stability and reactivityReactivityChemical stabilityPossibility of hazardousreactionsConditions to avoidIncompatible materialsHazardous decompositionproducts12,52 Ibs/gal estimatedNot estimatedThe product is stable and non-reactive under normal conditions of use, storage and is stable under normal polymerization does not with incompatible oxidizing hazardous decomposition products are , Toxicological informationInformation on likely routes of exposureInhalationSkin contactEye contactIngestionSymptoms related to thephysical, chemical andtoxicoiogical characteristicsHarmful if severe skin serious eye if swallowed. Causes digestive tract burns,Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms mayinclude stinging, tearing, redness, swelling, and blurred vision.