Conforms to ANSI Z400.1-2004 Standard (United …

1 TolyltriazoleMaterial Safety Data SheetProduct and company identification1 .Common nameTolyltriazole:MSDS authored by::Kemika XXI Inc. + 1-450-435-747503/31/2005 Conforms to ANSI Standard (United States, Canada).In case of emergency:Supplier/Manufacturer:CANUTEC (613) 996-6666 CHEMTREC, Domestic: (800) 424-9300 CHEMTREC, International: (703) 527-3887 Connect Chemical USA, LLC107 Colony Park DriveCumming, GA, 30040 Tel : (678) 947-4410 Fax : (678) 947-4110 Toll free : 888-58- Connect ( 82-6663)Dermal contact. Eye contact. Inhalation. identificationRoutes of entryPotential acute health effectsNo known significant effects or critical known significant effects or critical be harmful if known significant effects or critical stateSolid.

2 (Powder.)See toxicological information (section 11):::::: .Emergency overview:CAUTIONMAY BE HARMFUL IF not ingest. Wash thoroughly after effects: Not classified or listed by IARC, NTP, OSHA, EU and effects: Not effects: Not available.:Potential chronic healtheffectsColor:Yellow or material is classified hazardous under OSHA regulations in the United States and theWHMIS Controlled Product Regulation in status:Composition/information on ingredients3 .%NameCAS numberUnited StatesTolyltriazole29385-43-160 - 100 First aid measures4 .Eye contactIf inhaled, remove to fresh air. If not breathing, give artificial respiration. Get medicalattention if symptoms for and remove any contact lenses.

3 In case of contact with eyes, rinseimmediately with plenty of water. Get medical attention if symptoms contactInhalation:::Wash with soap and water. Get medical attention if symptoms of issue:03/31/2005 Page: 1/5 TolyltriazoleDo not induce vomiting. Never give anything by mouth to an unconscious person. Getmedical attention if symptoms to physician::No specific antidote. Medical staff must contact Poison Control be combustible at high products are carbon oxides, nitrogen an extinguishing agent suitable for the surrounding measuresFlammability of the productProducts of combustionExtinguishing mediaNo specific protectiveequipment for fire-fightersFire-fighters should wear appropriate protective equipment and self-contained breathingapparatus (SCBA) with a full face-piece operated in positive pressure mode.

4 :::5 .Special exposure hazards:None :Not suitable:Immediately contact emergency personnel. Keep unnecessary personnel away. Usesuitable protective emergency personnel are unavailable, vacuum or carefully scoop up spilled materialand place in an appropriate container for disposal by incineration. Avoid creating dustyconditions and prevent wind precautionsAccidental release measures:Avoid dispersal of spilled material, runoff and contact with soil, waterways, drains precautions:Methods for cleaning up:6 .Keep container tightly closed. Keep container in a cool, well-ventilated not ingest. Wash thoroughly after and storageHandlingStorage::7.

5 Exposure controls/personal protectionPersonal protectionConsult local authorities for acceptable exposure .Engineering measures:No special ventilation requirements. Good general ventilation should be sufficient tocontrol airborne levels. If this product contains ingredients with exposure limits, useprocess enclosures, local exhaust ventilation or other engineering controls to keep workerexposure below any recommended or statutory protection in caseof a large spill:Safety glasses, goggles or face shield. Impervious gloves. Full suit. Boots. Wear NIOSH-approved self-contained breathing apparatus or equivalent and full protective hands, forearms and face thoroughly after handling compounds and before eating,smoking and using the lavatory and at the end of the day.

6 Follow good industrial Code/Personalprotective equipment:BNatural rubber (latex).A respirator is not needed under normal and intended conditions of glasses. Eyes:SkinRespiratory:::HandsDate of issue:03/31/2005 Page: 2/5 Tolyltriazole160 C (320 F)Solid. (Powder.)76 to 87 C ( to F) (Water = 1) or pointMelting/freezing pointPhysical and chemical propertiesPhysical stateMolecular weightRelative densityOdorColorC7H7N3 Molecular formula::::::::Flash point:Closed cup: 182 C ( F). (Tagliabue.)9 .Insoluble in cold water, hot :The product is with oxidizing not and reactivityStability and reactivityIncompatibility with varioussubstancesHazardous polymerization:::10.

7 Not of reactivity:Toxicological informationToxicity dataProduct/ingredient nameTestResultRouteSpeciesTolyltriazoleL D50675 mg/kgOralRat11 .Eyes:No known significant effects or critical :No known significant effects or critical :No known significant effects or critical :May be harmful if EffectsPotential chronic healtheffects:Carcinogenic effects: Not classified or listed by IARC, NTP, OSHA, EU and effects: Not effects: Not products are carbon oxides and water, nitrogen products of degradation are less toxic than the product informationToxicity of the products ofbiodegradationProducts of degradation::Environmental precautions:No known significant effects or critical.

8 The generation of waste should be avoided or minimized wherever possible. Avoiddispersal of spilled material, runoff and contact with soil, waterways, drains and of this product, solutions and any by-products should at all times comply with therequirements of environmental protection and waste disposal legislation and any regionaland local authority disposalDisposal considerations:13 .Date of issue:03/31/2005 Page: 3/5 TolyltriazoleTransport information14 .IATA:DOT/ TDGIMDG/Not :Not informationUN/California prop. 65: No products were informationClean Water Act (CWA) 307: No products were Water Act (CWA) 311: No products were Air Act (CAA) 112 accidental release prevention: No products were Air Act (CAA) 112 regulated flammable substances: No products were Air Act (CAA) 112 regulated toxic substances: No products were regulationsInternational listsSARA 302/304/311/312 extremely hazardous substances: No products were 302/304 emergency planning and notification: No products were 302/304/311/312 hazardous chemicals: No products were 311/312 MSDS distribution - chemical inventory - hazard identification: No productswere found.

9 :CanadaUnited States15 .HCS ClassificationMay be harmful if Federal regulationsTSCA 8(b) inventory: Tolyltriazole::WHMIS (Canada)CEPA DSL: TolyltriazoleNot controlled under WHMIS (Canada).:State regulationsNo products were found.:This product, (and its ingredients) is (are) listed on national inventories, or is (are)exempted from being listed, Australia (AICS), in Europe (EINECS/ELINCS), in Korea(TCCL), in Japan (METI), in the Philippines (RA6969).This product has been classified in accordance with the hazard criteria of the Canadian CPR and the United StatesOSHA. This MSDS contains all the information required by the CPR and OSHA, the American National StandardInstitute (ANSI) informationHazardous MaterialInformation System ( )National Fire ProtectionAssociation ( )HealthSpecialReactivityFlammabilityMAY BE HARMFUL IF requirements ( ) :::16.

10 010 HMIS RATINGP hysical HazardHealth01 Fire hazardPersonal protectionB04- Extreme3- Serious2- Moderate1- Slight0- MinimalSee section 8 for more detailed information on personal RATINGSDate of issue:03/31/2005 Page: 4/5 TolyltriazoleReferencesReferencesDate of issueVersion:::03/31/20051:ANSI , MSDS Standard , 2004 . - Manufacturer's Material Safety Data Sheet. -29 CFR OSHA MSDS Requirements. - 49 CFR Table List of HazardousMaterials, UN#, Proper Shipping Names, PG. - Canada Gazette Part II, Vol. 122, No. SOR/88-64, 31 December 1987. Hazardous Products Act "IngredientDisclosure List" - Canadian Transport of Dangerous Goods, Regulations and Schedules,Clear Language version to readerTo the best of our knowledge, the information contained herein is accurate.