-COOH Introduction to RilsanHT H N-(CH grinding …

1 Rilsan HT - The First Flexible PPA Confidential Arkema Property Duplication prohibitedIntroduction to Rilsan HT1 ARKEMAR ilsan HT - The First Flexible PPA Confidential Arkema Property Duplication prohibitedCastor seedCastor plantharvestinggrindingLong chain PAPA11monomerCastor oilLong chain PAPA12 Mid-chain PAPA612 Petroleum basePA elastomerPEBAP rocess flow of high performance PARigid PAHigh heat resistance PAAminoundecanoic acidSebacic acidDecanediamineH2N-(CH2)10-COOHHOOC-(C H2)8-COOHH2N-(CH2)10-NH2 Mid&long chain PAPA610, 1010, 1012PA elastomerPEBA polymerization45~100%Up to 95%Amorphous PA100%Up to 53%56%Up to 70%Rilsan XDRilsan HT - The First Flexible PPA Confidential Arkema Property Duplication prohibited150 C110-120 C250 C110-120 C150 C220-200 CMetal Metal & RubberComplex solutions ( reinforced Rubber / FKM)Cooling: PA11 HPPA MLT solutionPA12 Special GradeAir IntakeTEEE, PA6, PA6-Alloy, RubberMetalMetal/ / RubberRubberSolutionSolutionFlexible Flexible ThermoplasticThermoplasticSolutionSoluti on-no solutionno solution220-200 CA Breakthrough in Metal Replacement Rilsan HT creates opportunities to replace metal in tubing that were previously unthinkable !

2 Rilsan HT New class of flexible PPAR ilsan HT - The First Flexible PPA Confidential Arkema Property Duplication prohibitedWhat makes Rilsan HT so different ? is the first flexible PPAto replace metal in tubing for high temperature applications surpasses other high-temperature thermoplastics with superior long-term resistance to thermo-oxidative and chemical agingat high temperatures is the only PPA being spin- weldableon aliphatic PA naturally fits into eco-design concepts can be easily manufactured on standard processing equipment offers cost-efficient manufacturingand system cost reduction features high design flexibility is a light- weight PPAresin offers exceptional dimensional stability Flexibility Processability: processing similar to aliphatic polyamides no need for special heating & cooling system excellent thermoforming and fitting insertion Long term heat resistance (thermooxidation) and chemical resistance at high temperature Integrity of mechanical properties at high temperature Spin-welding Low density Low moisture uptake BiobasedHigh Temperature PLUS:Rilsan HT - The First Flexible PPA Confidential Arkema Property Duplication prohibitedRilsan HT.

3 The optimum synergy of bothRilsan HT The First Flexible PPAL imitationsTemperature resistance up to 150 CLimitationsOnly available as injection grades due to intrinsic brittleness / stiffness of materialPoorer Long-Term Aging ResistanceDifficult overall processingRilsan PA11 Classical PPA resinsKey Points:High melting pointHigh temperature resistanceKey Points: Flexibility Excellent Long-Term Aging Resistance Ease of processing BioBasedRilsan HT - The First Flexible PPA Confidential Arkema Property Duplication prohibitedFlexural modulus of Rilsan HT compared to classic HT polymers a breakthrough amongst HT materials Rilsan HT Unprecedented Flexibility Rilsan HT: <<<<is the only PPA to combine the high-temperature resistance of conventional PPA grades with flexibilityRilsan HTPA 119T6/6T66/6T6I/6T4610001500200025003000 3500150170190210230250270290310330 Melting point ( C)Flexural modulus (MPa)Classic PPANew class of flexible PPAPA 6(neat resins)RigidFlexible500 Rilsan HT extrusion gradesRilsan HT - The First Flexible PPA Confidential Arkema Property Duplication prohibitedWeight reduction by Rilsan HTWeight savings, throughMetal replacementand substitution of rubber & other polymeric materials Low densityRilsan HT: <<<<lowers total system weight by min.

4 50% (factor 2 to 3 vs Al, 6 to 8 vs steel)<<<<is a light- weight PPA resin<<<<helps to reduce emissions and fuel consumption 6 TPA46PA66 Rilsan HTPA11 MetalFluorinated PolymersOther HT/HPPolymersClassicHT MaterialsDensity [g/cm3]Rilsan HTRubber 1,15 1, of Rilsan HT compared to metal, rubber and other polymeric materialsRilsan HTis more than 10% lighter than classic PPAE nvironmentalEnvironmentalMetal assembly / 1000g Rilsan HT / 350gWeight gain: Rilsan HT 3 times lighterBlow-by @ VWAlu tube w/ Brass QC (280g) resp. w/ Alu QC (110g) --> Rilsan HT tubing / 50gWeight gain: Rilsan HT 2 to 6 times lighterEGR vacuum tubing @ PSAAlu assembly / 270g Rilsan HT / 110gWeight gain: Rilsan HT times lighterTOC @ HyundaiRilsan HT - The First Flexible PPA Confidential Arkema Property Duplication prohibitedSystem Cost reduction by Rilsan HTRilsan HT vs.

5 Metal based tubing assembly:Rilsan HT: <<<<generates up to 50% cost savings vs. metal tubing assemblies0102030405060708090100 System costs[ Base 100 of Metal Assembly System Cost] AssemblyProcessing(Extrusion,Thermoformi ng)MaterialComponent / system cost Metal Tubing AssemblyRilsan HT Tubing AssemblyEconomicalEconomicalRilsan HT - The First Flexible PPA Confidential Arkema Property Duplication prohibitedRilsan HT product line upExtrusion gradeRilsan HT CESV P010 TLRilsan HT CESV Bk P010TL HPRilsan HT CESV Bk P223 TLRilsan HT CESV P123 TLRilsan HT CZM30 Bk TLDR ilsan HT CSR13 Injection gradefeature (flexural modulus)Standard (820 MPa)High pressure (1530 MPa)Flexible (520 MPa)Improved hydrolysis (820 MPa)feature (flexural modulus)GF30% (7300 MPa)Conductive (7600 MPa)

6 Rilsan HT CMFOHigh flowability, non-filled (1800 MPa)Rilsan HT CMNO TLStandard, non-filled (1370 MPa)Rilsan HT CMNOS tandard, non-filled (1800 MPa)Rilsan HT - The First Flexible PPA Confidential Arkema Property Duplication already been selected by many OEM Rilsan HT ..Rilsan HT - The First Flexible PPA Confidential Arkema Property Duplication prohibitedRilsan HT with best fit ..IntercoolerEGR coolerEGR valveInjectorBlow-byTurboAirFuelSCRDPFDO CAdBlueTankExhaust GasDPF (Diesel Particulate Filter)SCR (catalyst)AdBlue Tankand InjectionDOC(Diesel OxydationCatalyst)EGREGR ValveTubingMixerSCR / AdBlue Air ManagementAggressive Media Media EGR (exhaust gas recirculation)Air IntakeAir IntakeTOC TOC (Transmission Oil Cooling)BlowBlow--bybyAdBlueAdBlue / SCR / SCR (selective catalytic reduction)CoolingCoolingFuel High TemperatureTemperatureFuel LinesFuel to Euro 6 & key powertrain technologiesRilsan HT - The First Flexible PPA Confidential Arkema Property Duplication prohibited GradeGradeGradeGrade: Rilsan HT CESV P010TL Case studyCase studyCase studyCase study.

7 Powertrain Powertrain Powertrain Powertrain ---- Aggressive Media ManagementAggressive Media ManagementAggressive Media ManagementAggressive Media ManagementBlow By LineBlow By LineBlow By LineBlow By Line Replaced:Replaced:Replaced:Replaced:Alum inium tubing / HPPA with heat shield Status:Status:Status:Status:Approved and in series prod. since Q3 2010at VW (PV 3936) / AUDI / SEAT / Porsche / Bentley; Daimler, Mahindra, Ferrari / Maserati / Alfa Romeo, Chrysler Models:Models:Models:Models:VW VW VW VW groupegroupegroupegroupe: : : : <<<<all diesel engines (having a diesel particle filter, due to new Euro 5/6 regulation), models/platforms starting with 2,0l & 1,6l engines, eg. Golf, Passat, Tiguan, A3, Skoda, ..) <<<<all new 12 cyl. gasoline engines ( , Phaeton, Bentley)Fiat Fiat Fiat Fiat groupegroupegroupegroupe: <<<< for new V6 engines of Ferrari & Chrysler for Maserati, Alfa Romeo, Chrysler Example: Example: Example: Example: Rilsan HT TubingAirBlow By GasExhaust GasCombustion Chamber PistonConnecting rodCrankshaftOil panBlow-by tubing Air IntakeExhaust gazRilsan HT CESV P010 TLCrankcase2 temp.

8 Classes: 160 C 180 CCase: Aggressive M. / Blow ByRilsan HT - The First Flexible PPA Confidential Arkema Property Duplication prohibitedIntercoolerIntercoolerFilterFi lterClean air tubeOutside Intercooler TubeOUTSIDE TURBO TUBEE xhaustgas pipeAIRAIRGAST urbo -CompressorOutside Turbo TubeOutside Turbo Tube4 cylinders engine4 cylinders engineRilsan HT 180 C < T < 200 CP~2-4bar, T ~ 180-200 CP~2-4bar, T ~ 110 CT ~125 to 150 CT ~125 to 150 CP~ bar, T ~ 20-40 COrgalloy LTOrgalloy LT GradesGradesGradesGrades: Rilsan HT CESV P010 TLRilsan HT CESVO P223TL ( ultra-flexible ) Case studyCase studyCase studyCase study: Powertrain Powertrain Powertrain Powertrain Air / Pressure ManagementAir / Pressure ManagementAir / Pressure ManagementAir / Pressure ManagementAir IntakeAir IntakeAir IntakeAir Intake Replaced:Replaced:Replaced:Replaced:Meta l, Rubber Status:Status:Status:Status:Under development ExampleExampleExampleExample:Rilsan HT TubingCase: Air Mngt.

9 / Air IntakeRilsan HT - The First Flexible PPA Confidential Arkema Property Duplication prohibited GradesGradesGradesGrades: Rilsan HT CESV P010-HP TL (tubing)Rilsan HT GF reinforced (QC)Connection by spin-welding Case studyCase studyCase studyCase study: Powertrain Powertrain Powertrain Powertrain ---- Oil Oil Oil Oil MngtMngtMngtMngt. / Transport. / Transport. / Transport. / TransportTOC TOC TOC TOC (Transmission Oil Cooling) Replaced:Replaced:Replaced:Replaced:Meta l, Rubber Tubing Status:Status:Status:Status:Approved at BMW, Greatwall Models:Models:Models:Models:will be in series for new platforms ExampleExampleExampleExample:Metal, Rubber Tubingreplaced by:Rilsan HT CESV P010-HP TLRilsan HT GF reinforced (QC)GearboxTransmission Fluid CoolerRadiatorTransmission Oil Cooler HoseRilsan HT CESV P010-HP TLSpecification: 3000h oil 150 C / peak 175 C Burst resistance: hot oil at 220 CRilsan HT TubingCase: Oil Mngt.

10 / TOCR ilsan HT - The First Flexible PPA Confidential Arkema Property Duplication prohibitedCase: Cooling GradesGradesGradesGrades: Rilsan HT CESV P010 TL (medium temp.)Rilsan HT CESV black P123 TL (high temp.) Case studyCase studyCase studyCase study: Powertrain Powertrain Powertrain Powertrain ---- Aqueous Media Aqueous Media Aqueous Media Aqueous Media linesCooling linesCooling linesCooling lines Replaced:Replaced:Replaced:Replaced:Alum inium tubing / Rubber Status:Status:Status:Status:Current grade: Current grade: Current grade: Current grade: RilsanRilsanRilsanRilsan HT CESV P010 TLHT CESV P010 TLHT CESV P010 TLHT CESV P010 TL BMWBMWBMWBMW Mini, series 3, 5, 7 / new Hybride SOP end 2013 DAIMLERDAIMLERDAIMLERDAIMLER Mercedes Class C SOP end 2013 VOLVO Truck (US)VOLVO Truck (US)VOLVO Truck (US)VOLVO Truck (US)New grade: CESV black P123 TL New grade: CESV black P123 TL New grade: CESV black P123 TL New grade.