Copper Alloys 101, 102, 103, 104, 110, 122, 151, XP5

1 MATERIAL SAFETY DATA SHEETCOPPER Alloys 101, 102, 103, 104, 110, 122, 151, XP5 Page 1 of 6 December 15, PRODUCT AND COMPANY IDENTIFICATIONPMX Industries, Willow Creek Drive SWCedar Rapids, Iowa 52404-4303 Emergency: 319-368-7700 TELEPHONE:319-368-7700 FAX:319-368-7701 PRODUCT NAMES:PMXALLOY #COMMON NAMEUNS #/CDA #101 Oxygen Free Electronic OFHCC10100102 Oxygen Free Copper OFHCC10200103C10300104C10400110 ETP Copper Electrolytic Tough PitchC11000122 Deoxidized Copper (DHP) Phos Deoxidized CopperC12200151 PMX High Precision AlloyC15100XP5 PMX High Precision AlloyCHEMICAL FAMILY: Copper AlloyISSUE DATE:December 15, 2004 SUPERSEDES DATE:March 8, HAZARDS IDENTIFICATIONEMERGENCY OVERVIEW: Copper alloy products in the natural state do not present a hazard for emergency response HEALTH EFFECTS.

2 Copper alloy products in the natural state do not present an inhalation, ingestion, or contact , operations such as burning, welding, sawing, brazing, or grinding may release fumes and/ordusts which may present health hazards if occupational exposure limits are SAFETY DATA SHEETCOPPER Alloys 101, 102, 103, 104, 110, 122, 151, XP5 Page 2 of 6 December 15, 2004 LIKELY ROUTES OF EXPOSURE:Inhalation, Eye Contact, Skin ContactINHALATION:Short-term exposure to fumes/dust may produce irritation of the respiratory system. Highconcentrations of Copper oxide fumes may cause metal fume :Short-term exposure to fumes/dust may produce :Repeated or prolonged exposure to Copper dusts or mists may cause irritant or allergiccontact :Abdominal pain, nausea, CONDITIONS AGGRAVATED BY EXPOSURE:Exposure to fumes or dust may aggravate existing respiratory disease or ORGANS:Upper respiratory tract, eyes, skinSIGNS AND SYMPTOMS:Metal fume fever metallic taste in mouth, dryness, and irritation of the throat, and influenza-likesymptoms.

3 The effects may be :COMPONENTACGIHIARCNTPC opper (fume, dusts & mists)NoNoNoSee Toxicological Information (Section #11)POTENTIAL ENVIRONMENTAL EFFECTS:None known. Product has not been tested for environmental CHEMICAL COMPONENTSNOTE: This MSDS applies to a range of Alloys . For actual compositions refer to material test report orspecific alloy specification. All percentages are by #% FIRST AID MEASURESINHALATION:If exposed to excessive levels of metal fumes, remove to fresh air. Seek medical :Flush with water for at least 15 :Wash with soap and SAFETY DATA SHEETCOPPER Alloys 101, 102, 103, 104, 110, 122, 151, XP5 Page 3 of 6 December 15, FIRE FIGHTING MEASURESSUITABLE EXTINGUISHINGMEDIA:Use extinguishing media appropriate to the surrounding FIREFIGHTINGINSTRUCTIONS: Copper alloy products in the solid state present no fire or explosionhazard, but may react with strong acids, bases, or oxidizing ACCIDENTAL RELEASE MEASURESSTEPS TO BE TAKEN IN THE EVENT OF SPILLS, LEAKS, OR RELEASES:Not HANDLING AND STORAGEHANDLING.

4 In welding, precautions should be taken for airborne contaminants that may originate fromcomponents of the welding EXPOSURE CONTROLS/PERSONAL PROTECTIONEXPOSURE GUIDELINESCOMPONENTOSHA PELTWAACGIH TLV TWAC opper dust, mg/m3 Copper mg/m3 ENGINEERINGCONTROLS:Local exhaust ventilation should be utilized when welding, burning, sawing,brazing, grinding, or machining when exposure exceeds occupational PROTECTION:Safety glasses or goggles should be utilized as required by exposure. Otherprotective equipment should be utilized as required by welding PROTECTION:Wear appropriate personal protective clothing to prevent skin contact withcopper dusts and :NIOSH-approved dust or fume respirator should be used to avoid excessiveinhalation of particulates when exposure exceeds occupational exposure PREVENTIVEMEASURES:Do not eat, drink, or smoke during work.

5 Wash hands before eating or SAFETY DATA SHEETCOPPER Alloys 101, 102, 103, 104, 110, 122, 151, XP5 Page 4 of 6 December 15, PHYSICAL AND CHEMICAL PROPERTIESAPPEARANCE:Salmon-colored, lustrous metalODOR:NonePHYSICAL STATE:SolidPH:Not applicableVAPOR PRESSURE:Not applicableVAPOR DENSITY (AIR = 1)Not applicablePERCENT VOLATILE:Not applicableEVAPORATION RATE:Not applicableSPECIFIC IN WATER:Not applicableDENSITY, LB/IN3 POINT:1,981 FFLASH POINT:Not applicableLOWER EXPLOSIVE LIMIT (%):NoneAUTOIGNITION TEMPERATURE:Not applicableUPPER EXPLOSIVE LIMIT (%) STABILITY AND REACTIVITYCHEMICAL STABILITY:StableCONDITIONS TO AVOID:NoneINCOMPATIBLE MATERIALS:Mercury, ammonia, acetylene acids.

6 Contact withstrong acids, bases, or oxidizing agentsHAZARDOUS DECOMPOSITION PRODUCTS:Metallic dust or fumes may be produced duringwelding, burning, grinding, and OF HAZARDOUS REACTIONS:Will not TOXICOLOGY INFORMATIONACUTE TOXICITY DATA FOR COMPONENTSC opper TDLo:120 g/kg (human, oral gastrointestinal effects)LD50 mg/kg (mouse, intraperitoneal)CHRONIC EFFECTS:Repeated or prolonged overexposure to Copper fume may cause the skin and hair to change ECOLOGICAL INFORMATIONNot applicableMATERIAL SAFETY DATA SHEETCOPPER Alloys 101, 102, 103, 104, 110, 122, 151, XP5 Page 5 of 6 December 15, DISPOSAL CONSIDERATIONSWASTE DISPOSAL METHODS:According to local, state, and federal TRANSPORT INFORMATIONNot REGULATORY INFORMATIONGLOBAL INVENTORIESCOPPERTSCA: United StatesIncludedDSL: CanadaIncludedEINECS: European Union:IncludedSARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355).

7 These Alloys are not regulated under Section 302 of SARA and 40 CFR TITLE III SECTION 311/312 HAZARDOUS CATEGORIZATION (40 CFR 370):OSHA defines these Alloys as hazardous 29 CFR (d).SARA TITLE III SECTION 313 TOXIC CHEMICALS (40 CFR 372):These Alloys may contain the following toxic chemical(s) subject to reporting requirements under thissection of SARA and of 40 CFR 372:COMPONENTCAS #% BY WEIGHTC opper7440-50-8 LISTSC hemical NameCA Prop 65 ChemicalMA ToxicSubstanceListMI CriticalMaterialsRegisterNJ HazardousSubstancesListPA Right-to-Know OTHER INFORMATIONREFERENCESACGIH Threshold Limit Values (TLV ) (2004)Agency for Toxic Substances and Disease Registry (ATSDR).

8 Toxicological Profile for Copper , September 2002 MATERIAL SAFETY DATA SHEETCOPPER Alloys 101, 102, 103, 104, 110, 122, 151, XP5 Page 6 of 6 December 15, 2004 International Agency for Research on Cancer (IARC) MonographsNational Library of Medicine (NLM) Databases:ChemIDIntegrated Risk Information (IRIS)International Toxicity Estimates for Risk (ITER)Chemical Carcinogenesis Risk Information System (CCRIS)Hazardous Substances Data Bank (HSDB)National Toxicology Program (NTP) ReportsNIOSH Pocket Guide to Chemical Hazards (2003)NIOSH/OSHA Occupational Health Guideline for Copper FumeNIOSH/OSHA Occupational Health Guideline for Copper Dusts and MistsOSHA General Industry Standards (29 CFR 1910)Registry of Toxic Effects of Chemical Substances (RTECS )

9 DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIESA lthough reasonable care has been taken in the preparation of this document, we extend no warrantiesand make no representations as to the accuracy or completeness of the information contained therein,and assume no responsibility regarding the suitability of this information for the user s intended purposesor for the consequences of its use. Each individual should make a determination as to the suitability ofthe information for their particular purpose(s).PREPARATION INFORMATIONP repared by:Cindy Baldwin, CIH5855 Willow Creek Drive SWCedar Rapids, Iowa 52404