DEAN #37261 (McGHP) RIGHT INTERACTIVE - UC Santa …

1 PROPERTIES OF ATOMS, RADICALS, AND dissociation EnergiesThe bond dissociation energy (enthalpy change) for a bond A9B which is broken through the reactionAB:A Bis defined as the standard-state enthalpy change for the reaction at a specified temperature, here at 298 is, Hf Hf(A) Hf(B) Hf(AB)298298298298 All values refer to the gaseous state and are given at 298 K. Values of 0 K are obtained by subtractingRT3 2from the value at 298 convert the tabulated values to kcal/mol, divide by Hf298,kJ/mo lBond Hf298,kJ/molAluminumAl9A l186(9)Al9As180Al9Au326(6)Al9Br439(8)Al9 C255Al9C l494(13)AlCl9C l402(8)AlCl29C l372(8)AlO9C l515(84)Al9Cu216(10)Al9D291Al9F664(6)AlF 9F546(42)AlF29F544(46)AlO9F761(42)Al9H28 5(6)Al9I368(4)Al9Li176(15)Al9N297(96)Al9 O512(4)

2 AlCl9O540(41)AlF9O582Al9P213(13)Al9Pd259 (12)Al9S374(8)Al9Se334(10)Al9Si251(3)Al9 Te268(10)Al9U326(29)AntimonySb9Sb299(6)S b9Br314(59)Sb9C l360(50)Sb9F439(96)Sb9N301(50)Antimony (continued)Sb9O372(84) (38)ArsenicAs9As382(11)As9C (12)As9H272(12)As9N582(126)As9O481(8)As9 P534(13)As9S(478)As9Se96As9T l198(15)AstatineAt9At( )BariumBa9Br370(8)Ba9C l444(13)Ba9F487(7)Ba9I 431(4)Ba9O563(42)Ba9OH477(42)Ba9S400(19) BerylliumBe9Be59Be9Br381(84)Be9C l388(9)DEAN #37261 (McGHP)RIGHTINTERACTIVEtop of rhbase of rhcap heightbase of 4 TABLE dissociation Energies (Continued) bond Hf298,kJ/mo lBond Hf298,kJ/molBeryllium (continued)BeCl9C l540(63)Be9F577(42)Be9H226(21)Be9O448(21 )Be9S372(59)BismuthBi9Bi197(4)Bi9Br267(4 )Bi9C l305(8)Bi9D284Bi9F259(29)Bi9Ga159(17)Bi9 H279Bi9O343(6)Bi9P280(13)Bi9Pb142(15)Bi9 S316(5)Bi9Sb251(4)Bi9Se280(6)Bi9Te232(11 )Bi9T l121(13)

3 BoronB9B297(21)H3B9BH3146OB9BO506(84)B9B r435(21)B9C448(29)B9C l536(29)BO9C l460(42)B9D341(6)B9F766(13)BF9F523(63)BF 29F557(84)B9H330(4)B9I384(21)B9N389(21)B 9O806(5)BCl9O715(41)B9P347(17)B9S581(9)B 9Se462(15)B9Si289(29)B9Te354(20) (4)Br9C280(21)Br9CH3284(8)Br9CH2Br255(13 )Br9 CHBr2259(17)Br9 CBr3209(13)Br9 CCl3218(13)Br9CF3285(13) (63) (63)Br9 CHF2289Br9C (4) (2)Br9N276(21) (63) (4) (8)Cd9Br159(96)Cd9C (34)Cd9F305(21) (4)Cd9I138(21)Cd9In138Cd9O142(42) (46)Ca9Br321(23)Ca9C l398(13)Ca9F527(21) (63)Ca9O464(84)Ca9S314(19)CarbonC9C607(2 1)H3C9CH3368 DEAN #37261 (McGHP)LEFTINTERACTIVEtop of rhbase of rhcap heightbase of textshortstandardlongPROPERTIES OF ATOMS, RADICALS, AND dissociation Energies (Continued) bond Hf298,kJ/mo lBond Hf298,kJ/molCarbon (continued)(CH3)2C9CH3335(CH3)2C9C(CH3) (CH3)3C9C(C6H5)363CH39allyl301CH39viny l121CH39C#CH490CH2"CH9CH"CH2418HC#C9C#CH 628H2C"CH2682HC#CH962CH39CN506(21)CH39CH 2CN305(8)CH39CH(CH3)CN331(8)CH39C(C6H5)C N(CH3)

4 (71)NC9CN603(21) (46)CH2F9CH2F368(8)CF39CF3406(13)CF2"CF2 318(13) (8) (C6H5CH2) l397(29)C9F536(21) (8)C9I209(21)C9N770(4)CF39NF2272(13)CH39 NH2331(13)C6H5CH29NH2301(4)CH39 NHC6H5285CH39N(CH3)C6H5272C6H5CH29 NHCH3289(4)C6H5CH29N(CH3)2255(4)CH39(N"N CH3) (N"NC2H5) (CH3)3C9N"NC(CH3) "NCH29ary l157 Carbon (continued)CF39(N"NCF3) "NH644(21)HC# (38) (54) (75)(CH3) (54) (42) (42) (42)NC9NO121(13)CH39NO2247(13) (4)CH39 OCH3335CH39OC6H5381CH39 OCH2C6H5280C2H59OC6H5213C6H5CH29 OCOCH3285C6H5CH29 OCOC6H5289CH3CO9 OCH3406CH39 OSOCH3280CH2"CHCH29 OSOCH3209C6H5CH29 OSOCH3222C"O749H2C"O732OC" (4)SC"O628C#O1075C9P513(8)C9S699(8)CH39S H305(13)CH39SC6H5285(8)CH39 SCH2C6H5247(8) (96)CeriumCe9Ce243(21)Ce9F582(42)Ce9N519 (21)Ce9O795(13)Ce9S573(13)Ce9Se495(15)Ce 9Te389(42)DEAN #37261 (McGHP)RIGHTINTERACTIVEtop of rhbase of rhcap heightbase of 4 TABLE dissociation Energies (Continued) bond Hf298,kJ/mo lBond Hf298, (93) (42)Cs9C l439(21)Cs9F514(8) (38)Cs9I339(4)

5 Cs9O297(25)Cs9OH385(13)ChlorineCl9C (16)Cl9C338(42)Cl9CH3339(21)Cl9 CH3213Cl9C(CH3) l310(13)Cl9 CCl3293(21)Cl9CF3360(33)Cl9 CCl2F305(8)Cl9 CClF2318(8) (71)Cl9CH"CH2351Cl9CN439Cl9 COC (13)Cl9Cl (42) (8)O3Cl9F255Cl9N389(50)Cl9NC (25)Cl9NO159(6)Cl9NO2142(4)Cl9O272(4)OCl 9O243(13)O2Cl9O201(4)Cl9P289(42)Cl9 SiCl3464 ChromiumCr9Cr155(21)Cr9Br328(24)Cr9C l366(24)Chromium (continued)Cr9Cu155(21)Cr9F437(20)Cr9Ge1 70(29)Cr9H280(50)Cr9I287(24)Cr9N378(19)C r9O427(29)OCr9O531(63)O2Cr9O477(84)Cr9S3 39(21)CobaltCo9Co167(25)Co9Br331(42)Co9C l398(8)Co9Cu162(17)Co9F435(63)Co9Ge239(2 5)Co9I235(81)Co9O368(21)Co9S343(21)Coppe rCu9Cu202(4)Cu9Br331(25)Cu9C l383(21)Cu9F431(13)Cu9Ga216(15)Cu9Ge209( 21)Cu9H280(8)Cu9I197(21)Cu9Ni206(17)Cu9O 343(63)Cu9S285(17)Cu9Se293(38)Cu9Sn177(1 7)Cu9Te176(38)CuriumCm9O736 DysprosiumDy9F527(21)Dy9O611(42)Dy9Se322 (42)Dy9Te234(42)DEAN #37261 (McGHP)

6 LEFTINTERACTIVEtop of rhbase of rhcap heightbase of textshortstandardlongPROPERTIES OF ATOMS, RADICALS, AND dissociation Energies (Continued) bond Hf298,kJ/mo lBond Hf298,kJ/molErbiumEr9F565(17)Er9O611(13) Er9S418(42)Er9Se326(42)Er9Te239(42) (165) (18)Eu9O557(13)Eu9S364(15)Eu9Se301(15)Eu 9Te243(15) (96)F9F 251F9CH3452(21)F9C(CH3)3439F9C6H5485F9 CCl3444(21)F9 CCl2F460(25)F9 CClF2490(25)F9CF3523(17)F9 COCH3498F9FO272(13) (42)F9NF318(25)F9NF2243(8) (42)F9NO2197(25)GadoliniumGd9F590(27)Gd9 O716(17)Gd9S525(15)Gd9Se431(15)GalliumGa 9Ga138(21)Ga9Br444(17)(CH3)3Ga9CH3253Ga9 C l481(13)Ga9F577(15)Ga9H 274Ga9I339(10)Gallium (continued)Ga9O285(63)Ga9P230(13)Ga9Sb20 9(13)Ga9Te251(25)GermaniumGe9Ge274(21)Ge 9Br255(29)Ge9C (4)Ge9F485(21) (8)Ge9O662(13) (25)Ge9Se490(21)Ge9Si301(21)Ge9Te402(8) (21)Au9B368(11)Au9Be285(8)Au9Bi293(84)Au 9C l343(10)Au9Co215(13)Au9Cr215(6)Au9Cu232( 9)Au9Fe187(17)Au9Ga294(15)Au9Ge277(15)Au 9H314(10)Au9La80(5) (16)Au9Mg243(42)Au9Mn185(13)Au9Ni274(21) Au9Pb130(42)Au9Pd143(21)Au9Rh231(29)Au9S 418(25)Au9Si312(12)Au9Sn244(17)Au9Te247( 67)

7 Au9U318(29)HafniumHf9C548(63)Hf9N534(29) Hf9O791(8)DEAN #37261 (McGHP)RIGHTINTERACTIVEtop of rhbase of rhcap heightbase of 4 TABLE dissociation Energies (Continued) bond Hf298,kJ/mo lBond Hf298, (4) (4) (4) (21) (8)H9CH452(33)H9CH2473(4)H9CH3431(8)2H9C 2H3or (25)H9C#CH523(4)H9CH"CH2427H9CH2CH3410(4 )H9CH2C# (50)H9CH2CH"CH2356H9cyclopropyl423(13)H9 CH2CH2CH3410(8)H9CH(CH3) (13)H9CH2CH(CH3)2360H9CH(CH3)CH2CH3397(4 )H9C(CH3)3381H9H9H9 CHH9CH2CH"CH2CH"CH2 CCH3CH3CH3339(4)335(4)343(4)414(4)H9C(CH 3)2CH"CH2331H9cyclopentyl395(42)H9CH2C(C H3)3418(4)H9C6H5431H9CH2C6H5356(4)H9C(C6 H5) (42) (42)H9norborny l406(13)H9CH2Br410(25)H9 CHBr2435H9CH2C l423 Hydrogen (continued) (8)H9 CBr3377(8)H9 CCl2 CHCl2393(8)H9CH2F423(8)H9 CHF2423(8)H9CF3444(13)H9CF2C l435(4)H9CH2CF3446(45)H9CF2CH3416(4)H9CF 2CF3431(63)H9CH2I431(8)H9 CHI2431(8)H9CN540(25) (CH3)CN377(8)H9C(CH3)2CN364(8)H9CH2NH239 7(8)H9CH2Si(CH3)3414(4)H9CH2 COCH3393(75)H9C (4)H9CO126(8)H9 CHO364(4)H9 COOH377H9 COCH3364(4)H9 COCH2CH3364(4)H9O385H9 COC6H5364(4)H9 COCF3381(8) (13) (8)H9N314(17)H9NH377(8)H9NH2435(8)

8 H9 NHCH3431(8)H9N(CH3)2397(8)H9 NHC6H5335(13)H9N(CH3)C6H5310(13)HNF2318( 13)H9N3356H9NO (21) (8) (42) (CH3)3439(4)H9OC6H5368(25) (25)DEAN #37261 (McGHP)LEFTINTERACTIVEtop of rhbase of rhcap heightbase of textshortstandardlongPROPERTIES OF ATOMS, RADICALS, AND dissociation Energies (Continued) bond Hf298,kJ/mo lBond Hf298,kJ/molHydrogen (continued) (25)H9 OOH374(8)H9 OOCCH3469(17)H9 OOCCH2CH3460(17)H9 OOCC3H7431(17)H9P343(29)H9S344(12)H9SH38 1(4) (2) (46)H9 SiH3393(13)H9Si(CH3)3377(13)H9Te268(2)In diumIn9In100(8)In9Br418(21)In9C l439(8)In9F506(15)In9O360(21) (85)In9S289(17)In9Sb152(11)In9Se247(17)I n9Te218(17) (8) (4)I9CH3232(13) (CH3)2222I9C(CH3) (4)I9CF2CH3216(4)I9C3F7209(4)I9CH"CHCH31 72I9C6H5268(4)I9C6F5276I9C (4) (4)I9F280(4)I9N159(17)I9NO71(4)I9NO275(4 )I9O184(21)IridiumIr9O352(21)Ir9Si463(21 )IronFe9Fe100(21)Fe9Br247(96) (13)Fe9S339(21)Fe9Si297(25) (8)Kr9F54 LanthanumLa9La247(21)La9C506(63)La9F598( 42)La9N519(42)La9O799(13)La9S577(25)Lead Pb9Pb339(25)Pb9Br247(38)Pb(CH3)39CH3207( 42)Pb9C l301(29)Pb9F356(8)Pb9H176(21)Pb9