ENVIRONMENTAL IMPACTS OF PRESERVATIVE-TREATED …

1 ENVIRONMENTAL IMPACTS OF PRESERVATIVE-TREATED WOOD February 8 11, 2004 Orlando, Florida, USA Florida Center for ENVIRONMENTAL Solutions Gainesville, Florida (pre-conference proceedings) ii This page intentionally left blank. iiiTABLE OF CONTENTS vii TECHNICAL PAPERS Variability in Evaluating ENVIRONMENTAL IMPACTS of treated Wood .. 3 Stan Lebow, Paul Cooper and Patricia Lebow Integrated Studies of the Dynamics of Arsenic Release and Exposure from CCA- treated Richard Maas, Steven Patch and Jacob Berkowitz Effects of CCA Wood on Non-Target Aquatic Biota .. 32 Judith Weis and Peddrick Weis Retention of As, Cu, and Cr leached from CCA- treated wood products in select Florida soils .. 45 Tait Chirenje, Lena Ma, M Szulczewski, K.

2 Hendry and C. Clark ENVIRONMENTAL IMPACTS of CCA- treated Wood Within Florida, USA .. 57 Helena Solo-Gabriele, Timothy Townsend and Yong Cai Scaled-Up Remediation of CCA- treated 71 Carol Clausen and William Kenealy Modeling of wood preservative leaching in service .. 81 Levi Waldron, Paul Cooper and Tony Ung Leachate Quality from Simulated Landfills Containing CCA- treated Wood .. 98 Jenna Jambeck, Timothy Townsend and Helena Solo-Gabriele Effect of Coatings on CCA Leaching From Wood in a Soil 113 David Stilwell and Craig Musante Depletion of Copper-Based Preservatives from Pine Decking and IMPACTS on Soil-Dwelling Invertebrates .. 124 Michael Kennedy ENVIRONMENTAL impact of CCA- treated Wood in Japan .. 146 Toshimitsu Hata, Paul Bronsveld; Tomo Kakitani, Dietrich Meier; and Yuji Imamura Alternatives to Chromated Copper Arsenate (CCA) for Residential Construction 156 Stan Lebow Assessing Potential Waste Disposal impact from preservative treated Wood 169 Timothy Townsend, Brajesh Dubey and Helena Solo-Gabriele ivHealth Effects of Preserved Wood: Relationship Between CCA- treated Wood and Incidence of Cancer in the United States.

3 189 Daniel West Disposal of treated 196 Jeffrey Morrell EU Directives and National Regulations for the Recycling and Disposal of Waste Wood .. 210 Rolf-Dieter Peek Electrodialytic Remediation of CCA- treated Wood In Larger 227 Iben Christensen, Anne Pedersen, Lisbeth Ottosen and Alexandra Ribeiro Recovery and Reuse of The Wood and Chromated Copper Arsenate (CCA) from CCA treated Wood A Technical Paper .. 238 Kazem Oskoui Bioremediation of waste copper/chromium treated wood using wood decay 245 Miha Humar, Pohleven Franc and Amartey O. Sam Bioremediation and Degradation of CCA- treated Wood 259 Barbara Illman and Vina Yang Compression Tests on Wood-Cement Particle Composites Made of CCA- treated Wood Removed From Service .. 270 An Gong, Donatien Kamdem and Ronald Harichandran Review of Thermochemical Conversion Processes as Disposal Technologies for Chromated Copper Arsenate (CCA) treated Wood Waste.

4 277 Lieve Helsen and Eric Bulck Characterization of Residues from Thermal Treatment of CCA Impregnated Wood. Chemical and Electrochemical Extraction .. 295 Lisbeth Ottosen, Anne Pedersen and Iben Christensen TEHCNICAL PAPERS SUPPLEMENTING POSTER PRESENTATION A Complete Industrial Process To Recycle CCA- treated 313 Jean-Sebastian Hery IMPACTS of Wood Preservatives (CCA, CCB, CDDC, ACZA, ACQ and ACC) on the Settlement and Growth of Fouling 323 B. Tarakanadha, Jeffrey Morrell and K. Satyanarayana Rao Leachable and Dislodgeable Arsenic and Chromium from In-Service CCA- treated Wood .. 335 Tomoyuki Shibata, Helena M. Solo-Gabriele, Lora Fleming, Stuart Shalat, Yong Cai, and Timothy Townsend vPOSTER ABSTRACT Arsenic speciation in soils and CCA- treated wood leachate .. 352 Myron Georgiadis, Yong Cai and Helena Solo-Gabriele Managing Wood Pallets and Industrial Wood Wastes : Sumter County Wood Reuse & Exchange 353 Miriam Zimms and Shane Barrett Characterizing Properties and Products of Spent CCA from Residential Decks.

5 357 Robert Smith, Dave Bailey, and Phil Araman COST Action E31: Management of Recovered 358 Gerfried Jungmeier, Bengt Hillring Copper Fixation Using A Pyrolytic Resin .. 360 Daniel Mourant, X Lu, Yang, B. Riedl and C Roy Deportment and Management of Metals Produced During Combustion of CCA- treated Timbers .. 361 Mary Stewart, Joe Rogers, Ashley Breed, Brian Haynes and Jim Petrie Energy Recovery from Shredded Waste Railroad Ties .. 362 Karl Lorber Extent of CCA- treated Wood in Consumer 363 Gary Jacobi, Helena Solo-Gabriele , Timothy Townsend, Brajesh Dubey and Laura Lugo Forecast of future uses for CCA outside USA .. 364 Ian Stalker Human and Ecological Risk Assessment of Borate-based Wood Preservatives. 365 Christian E. Schlekat, Susan A. Hubbard, Mark E. Stelljes impact of restrictions on the use of CCA- treated wood in 366 J ran Jermer Influence of weathering conditions on leaching of CCA, ACQ and Cu-azole components and their reaction with soil.

6 368 Silvija Stefanovic, and Paul Cooper Leaching of copper containing preservatives according to OECD guideline XXX and 369 Ali Temiz, Fred G. Evans Leaching of Copper, Chromium and Arsenic from CCA treated Wood in Sanitary Landfill Leachate .. 370 Brajesh Dubey, Tim Townsend and Helena Solo-Gabriele Life Cycle Management of treated Wood - The Canadian Approach .. 371 Curtis Englot Quantification and Speciation of Arsenic Leaching From an In-Service CCA- treated Wood Deck and Disposed CCA- treated Wood to Lysimeters Simulating Different Landfill 372 viBernine Khan, Helena Solo-Gabriele, Timothy Townsend, and Yong Cai Recycling of CCA treated 374 Leo Lindroos Unregulated Use of Toxic Wood Preserving Chemicals in Kenya: Health and ENVIRONMENTAL Issues .. 375 Ramakrishna Venkatasamy Water-Borne Copper Naphthenate: An Arsenic and Chromium Free preservative for 376 Mike Freeman, Pascal Kamdem and Jim Brient Wood preservative 101: Frequently Asked Question (FAQ).

7 377 Yuki Sotome, Alysia Muniz, Tomoyuki Shibata and Helena M. Solo-Gabriele viiForward The Florida Center for ENVIRONMENTAL Solutions is pleased to present the proceedings of the ENVIRONMENTAL IMPACTS of PRESERVATIVE-TREATED Wood Conference. The proceedings consist of manuscripts submitted by the speakers and abstracts from the poster presenters. We are very appreciative of the participation of our esteemed speakers and presenters. The Center would like to recognize the following for their assistance in planning this conference: Conference Organizing Committee Helena Solo-Gabriele, PhD, PE - Conference Chair Timothy Townsend, PhD, PE, Conference Co-Chair Marcia Marwede Larry Robinson, PhD Rhonda Rogers John Schert, Director Conference Technical Committee Kevin Archer, PhD.

8 , Chemical Specialities William Baldwin, Arch Wood Protection, Inc. Van den Bulck, Katholieke Universiteit Paul Cooper, PhD, University of Toronto, Session Moderator Carol Clausen, Forest Products Laboratory, Session Moderator Lieve Helsen, PhD, Katholieke Universiteit, Session Moderator William Hinkley, Florida Department of ENVIRONMENTAL Protection, Session Moderator John Horton, Osmose, Inc. Barbara Illman, PhD, Forest Products Laboratory, Session Moderator Pascal Kamdem, PhD, Michigan State University, Session Moderator Jeffrey Morrell, PhD, Oregon State University, Session Moderator Lisbeth Ottosen, PhD, University of Denmark, Session Moderator Helena Solo-Gabriele, PhD, PE, University of Miami, Conference Chair, Session Moderator David Stilwell, PhD, The Connecticut Agricultural Experiment Station, Session Moderator Timothy Townsend, PhD, PE, University of Florida, Conference Co-Chair, Session Moderator Judith Weis, PhD, Rutgers University, Session Moderator The Center takes great pride in recognizing the National Science Foundation - Partnerships for Innovation and the Directorate for Engineering for their funding support.

9 Without this viiisupport, the conference would not have happened. The entities listed below provided additional sponsorship for the conference. We are indeed grateful for their support as well. GOLD PATRONS Janssen Pharmaceutical Southern Waste Systems SILVER PATRONS GeoSyntec Consultants Solid Waste Authority of Palm Beach County Southern Waste Information Exchange (SWIX) Center for ENVIRONMENTAL and Human Toxicology, University of Florida BRONZE PATRONS Akzo Nobel Jones, Edmunds and Associates, Inc. Powell Center for Construction and Environment, University of Florida Waste Pro, Inc. Last but by no means least, we wish to thank the conference attendees. We exceeded our expectations to bring together the experts in treated wood from across the world.

10 Thank you for taking the time to attend this conference and participate in the discussions. Your participation is appreciated. Tehcnical Papers 2 This page intentionally left blank. 3 Variability in Evaluating ENVIRONMENTAL IMPACTS of treated Wood Stan Lebow, Paul Cooper, Patricia Lebow Prepared for Proceedings of the ENVIRONMENTAL IMPACTS of PRESERVATIVE-TREATED Wood Conference Orlando, Florida February 8 10, 2004 The Forest Products Laboratory is maintained in cooperation with the University of Wisconsin. This article was written and prepared by Government employees on official time, and it is therefore in the public domain and not subject to copyright. ABSTRACT preservative treated wood contains components that may be toxic to non-target organisms if released into the environment in sufficient quantities.