Fuels, diesel - Trafigura

1 SAFETY DATA SHEET Page : 1 / 14 Revision nr : Issue date : 24/01/2018 Fuels, diesel Supersedes : 16/08/2016 SECTION 1: Identification of the substance/mixture and of the company/undertaking Product identifier Product form : Substance Trade name/designation : Fuels, diesel Chemical name : Fuels, diesel EC Index : 649-224-00-6 EC-No. : 269-822-7 CAS-No. : 68334-30-5 REACH registration No : 01-2119484664-27-0195 Product group : Trade product Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use of the substance/mixture : Fuels see attached exposure scenario. Title Use descriptors Use as an intermediateX (ES Ref.: 02) PROC1, PROC2, PROC3, PROC4, PROC8a, PROC8b, PROC15, ERC6a, ESVOC SPERC Distribution of substanceX (ES Ref.: 03) PROC1, PROC2, PROC3, PROC4, PROC8a, PROC8b, PROC9, PROC15, ERC4, ERC5, ERC6a, ERC6b, ERC6c, ERC6d, ERC7, ESVOC SPERC LubricantsX (ES Ref.)

2 : 05) PROC1, PROC2, PROC3, PROC4, PROC7, PROC8a, PROC8b, PROC9, PROC10, PROC13, PROC17, PROC18, ERC4, ERC7, ESVOC SPERC Use as a fuelX (ES Ref.: 06) PROC1, PROC2, PROC3, PROC8a, PROC8b, PROC16, ERC7, ESVOC SPERC Functional fluidsX (ES Ref.: 09) PROC1, PROC2, PROC3, PROC4, PROC8a, PROC8b, PROC9, ERC7, ESVOC SPERC Use as a fuelX (ES Ref.: 07) PROC1, PROC2, PROC3, PROC8a, PROC8b, PROC16, ERC9a, ERC9b, ESVOC SPERC Use as a fuelX (ES Ref.: 08) PC13, ERC9a, ERC9b, ESVOC SPERC Manufacture of substanceX (ES Ref.: 01) PROC1, PROC2, PROC3, PROC4, PROC8a, PROC8b, PROC15, ERC1, ESVOC SPERC Formulation & (re)packing of substances and mixturesX (ES Ref.: 04) PROC1, PROC2, PROC3, PROC4, PROC5, PROC8a, PROC8b, PROC9, PROC14, PROC15, ERC2, ESVOC SPERC Full text of use descriptors: see section 16 Uses advised against No data available Details of the supplier of the safety data sheet Trafigura Ventures Evert van de Beekstraat 1-82 The Base, Tower B - 5th Floor 1118 CL Schiphol - The Netherlands T +31 20 504 1800 Emergency telephone number Emergency number : +32 3 575 03 30 SAFETY DATA SHEET Page : 2 / 14 Revision nr : Issue date : 24/01/2018 Fuels, diesel Supersedes : 16/08/2016 This telephone number is available 24 hours per day, 7 days per week.

3 Country Official advisory body Address Emergency number Ireland National Poisons Information Centre Beaumont Hospital Beaumont Hospital Beaumont Road 9 Dublin +353 1 809 21 66 (public, 8am - 10pm, 7/7) +353 01 809 2566 (Professionals, 24/7) United Kingdom National Poisons Information Service (Newcastle Centre) Regional Drugs and Therapeutics Centre, Wolfson Unit Claremont Place Newcastle-upon-Tyne NE1 4LP Newcastle 0844 892 0111 (UK only, 24/7, healthcare professionals only) SECTION 2: Hazards identification Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixtures/Substances: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) Flam. Liq. 3 H226 Acute Tox. 4 (Inhalation) H332 Skin Irrit. 2 H315 Carc. 2 H351 STOT RE 2 H373 Asp. Tox. 1 H304 Aquatic Chronic 2 H411 Full text of H statements : see section 16 Label elements Labelling according to Regulation (EC) No.

4 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display Hazard pictograms (CLP) : GHS02 GHS07 GHS08 GHS09 Signal word : Danger Hazard statements (CLP) : H226 - Flammable liquid and vapour. H304 - May be fatal if swallowed and enters airways. H315 - Causes skin irritation. H332 - Harmful if inhaled. H351 - Suspected of causing cancer. H373 - May cause damage to organs through prolonged or repeated exposure. H411 - Toxic to aquatic life with long lasting effects. Precautionary statements (CLP) : P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260 - Do not breathe mist, vapours, spray, gas, fume. P273 - Avoid release to the environment. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P301+P310+P331 - IF SWALLOWED: Immediately call a POISON CENTER, a doctor.

5 Do NOT induce vomiting. P391 - Collect spillage. Listed in Annex VI : EC Index-No. : 649-224-00-6 SAFETY DATA SHEET Page : 3 / 14 Revision nr : Issue date : 24/01/2018 Fuels, diesel Supersedes : 16/08/2016 Other hazards Other hazards : PBT/vPvB data. This substance does not meet the PBT/vPvB criteria of REACH, annex XIII. SECTION 3: Composition/information on ingredients Substances Comments : UVCB Substance name : fuel diesel CAS-No. : 68334-30-5 EC-No. : 269-822-7 EC Index : 649-224-00-6 Substance name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Fuels, diesel ; Gasoil - unspecified (CAS-No.) 68334-30-5 (EC-No.) 269-822-7 (EC Index) 649-224-00-6 (REACH-no) 01-2119484664-27-0195 100 Flam. Liq. 3, H226 Asp. Tox. 1, H304 Skin Irrit. 2, H315 Acute Tox. 4 (Inhalation), H332 Carc.

6 2, H351 STOT RE 2, H373 Aquatic Chronic 2, H411 Full text of H-statements: see section 16 Mixtures Not applicable SECTION 4: First aid measures Description of first aid measures Additional advice : First aider: Pay attention to self-protection. See also section 8 . Treat symptomatically. Never give anything by mouth to an unconscious person. Show this safety data sheet to the doctor in attendance. In case of doubt or persistent symptoms, consult always a physician. Inhalation : Keep at rest. Provide fresh air. In case of doubt or persistent symptoms, consult always a physician. If unconscious place in recovery position and seek medical advice. Give oxygen or artificial respiration if necessary. Skin contact : Remove contaminated clothing and shoes. After contact with skin, wash immediately with plenty of water and soap.

7 In case of doubt or persistent symptoms, consult always a physician. In the event of a high pressure injection injury, worker should obtain immediate medical assistance. Eyes contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical advice/attention. Ingestion : Do NOT induce vomiting. Rinse mouth immediately and drink plenty of water. Get immediate medical advice/attention. Most important symptoms and effects, both acute and delayed Inhalation : Harmful if inhaled. May cause respiratory irritation. Skin contact : Causes skin irritation. Eyes contact : Contact with eyes may cause irritation. Ingestion : May be fatal if swallowed and enters airways. May cause gastrointestinal irritation, nausea, vomiting and diarrhoea. SAFETY DATA SHEET Page : 4 / 14 Revision nr : Issue date : 24/01/2018 Fuels, diesel Supersedes : 16/08/2016 Chronic symptoms : Suspected of causing cancer.

8 May cause damage to organs through prolonged or repeated exposure. Indication of any immediate medical attention and special treatment needed No data available SECTION 5: Firefighting measures Extinguishing media Suitable extinguishing media : Water spray, Alcohol resistant foam, Carbon dioxide, Dry extinguishing powder. Unsuitable extinguishing media : Strong water jet. Special hazards arising from the substance or mixture Specific hazards : Vapours are heavier than air and may spread along floors. On heating there is a risk of a build-up of pressure in hermetically sealed containers or tanks. Do not allow run-off from fire-fighting to enter drains or water courses. Explosion hazard : Vapours may form explosive mixture with air. Hazardous decomposition products in case of fire : Carbon oxides (CO, CO2). Hydrogen sulfide.

9 Sulphur oxides. Advice for firefighters Firefighting instructions : Special protective equipment for firefighters.. In case of fire: Wear self-contained breathing apparatus. Use water spray or fog for cooling exposed containers. Evacuate personnel to a safe area. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency personnel For non-emergency personnel : Provide adequate ventilation. Evacuate personnel to a safe area. Use personal protective equipment as required. Reference to other sections: 8. Avoid contact with skin, eyes and clothing. Do not breathe vapour/aerosol. Vapours may form explosive mixture with air. Vapours are heavier than air and may spread along floors.

10 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Ensure equipment is adequately earthed. Material can create slippery conditions. Product may release Hydrogen Sulphide: A specific assessment of inhalation risks from the presence of hydrogen sulphide in tank headspaces, confined spaces, product residue, tank waste and waste water, and unintentional releases should be made to help determine controls appropriate to local circumstances. For emergency responders For emergency responders : Ensure procedures and training for emergency decontamination and disposal are in place. Concerning personal protective equipment to use, see section 8. Environmental precautions Do not allow to enter into surface water or drains. Do not allow to enter into surface water or drains. Methods and material for containment and cleaning up Methods for cleaning up : Stop leak if safe to do so.