GESAMP/EHS Composite List 2014 - IMO

1 ANNEX 4 GHPs for NEW SUBSTANCES SUBMITTED FOR EVALUATION to GESAMP/EHS 51 ! ! "! #" " $ % & ' ' ( ) ! *$ + !! ( ' " ' # "! !#,- "" " " #'' " ! !! ' ! " . !#,!" ! " ' $ ! ' !#-- ' & " " ,) EHS NameTRN NameEHSTRNA1aA1bA1A2B1B2C1C2C3D1D2D3E1E2 E3 Alkanes (C10-C17), linear and branched2463(5)NI(5)R0100(0)00AF3 Renewable Aviation Fuel3815 RTECS NoCAS NoAlkanes (C5 - C7), linear and branched2464(5)NI(5)(R)(3)(0)00020 NAE2 Renewable Naphtha3799 RTECS NoCAS NoCyclohexane oxidation products, sodium salts solution24580NI0 Inorg100(0)(0)00D0 Sodium carboxylate solution3739 RTECS NoCAS NoDiethylenetriamine pentaacetic acid, pentapotassium salt solution (40%) (**)24661NI1NR2 NINININININIDNI3929 RTECS NoCAS NoDiethylenetriamine pentamethylene phosphonic acid, pentasodium salt solution (47 %) (**) 24670NI0R2 NINININININIDNI3930 RTECS NoCAS Non-Dodecyl mercaptan2462533NR5NI00(3)3(3)

2 SF3n-Dodecyl Mercaptan3743 RTECS NoCAS NoNaphthalene, crude (molten) (#)2459NI(3)(3)NR300(0)(2)22 CMTFp3 Raw Naphthalene, molten3858 RTECS NoCAS No85117-10-8n-Octyl mercaptan2461433NR5NI10(1)10SF3n-Octyl Mercaptan3742 RTECS NoCAS NoPoly N-alkylmethacrylamide ammonium acrylate copolymer (20 % in DEGME) (**)24680NI0NR2 NINININININIDNI3931 RTECS NoCAS NoPotassium carbonate solution2465 Inorg00 Inorg2NI00(0)22D23928 RTECS NoCAS NoANNEX 4 - NEW SUBSTANCES SUBMITTED FOR EVALUATION ( gesamp Hazard Profile)EHS 51/916 May 2014 Page 1 of 1 ANNEX 5 UPDATED gesamp Composite LIST Notes: - ! " / !" ! "! #" , " " 0 *! + - ! ( ' ' # " ) , " ) ) !" ( " ' # "! ! , ! - ! 1 2 ! "' # " " " ,) ! " ) !

3 " !!# ( " - ! " / !" ' ) " ' 2 3 "' ! 4 " - - '5 4 " ! ) !" ' !5 *6+ ' ' ! " ) " . - "! ( ' 4 )2 '" ) & ' ' ( ) . !! ! ' ( ) ! cannot be used ( ' - "#' ) #) " ! ' ) " " ,#)5 ! - "! "' ! 4 " - - '5 #,) !" ' !5 *66+ ' ' ! " - "#' - "! ( ' 4 )2 '" ) & ' ' ( ) ! , !! ! ' ( ) ! may be used ( ' - "#' ) #) " ! ' ) " " ,#)5 ! - "! "' ! 4 " - - '5 4 " ! - '5 *7+ ' () " " " ( ' " C3 rating " ' # " ! . #' ' " ' " ' ! ) ' - !" #) , ! ' " . ) 4 ' ) " & ' ( ' " #' ! ! ( ' !5 - - " EHS NameTRN NameEHSTRNA1aA1bA1A2B1B2C1C2C3D1D2D3E1E2 E3 Acetic acid13000R1NI1113C3D3 Acetic acid64 RTECS NoAF1225000 CAS No64-19-7 Acetic anhydride12000R1NI10233AD3 Acetic anhydride65 RTECS NoAK1925000 CAS No108-24-7 Acetochlor (ISO)2047322NR4NI10(1)00S2 Acetochlor66 RTECS NoAB5457000 CAS No34256-82-1 Acetone15000R0000012 NTDE2 Acetone67 RTECS NoAL3150000 CAS No67-64-1 Acetone cyanohydrin14000R4NI343(3)(3)D3 Acetone cyanohydrin68 RTECS NoOD9275000 CAS No75-86-5 Acetonitrile16000R1NI11212D2 Acetonitrile69 RTECS NoAL7700000 CAS No75-05-8 Acetonitrile (Low purity grade)23330NI0R3NI11212D2 Acetonitrile (Low purity grade)2876 RTECS NoCAS NoAcid mixtures (nitrating acid)289 InorgNI0 Inorg(2)

4 NI3343C3D3 Nitrating acid (mixture of sulphuric and nitric acids)497 RTECS NoCAS NoAcrylamide23000R2022(2)12 CMNSD3 Acrylamide solution (50% or less)70 RTECS NoAS3325000 CAS No79-06-1 Acrylic acid24000R4NI2223C3D3 Acrylic acid71 RTECS NoAS4375000 CAS No79-10-7 Acrylic acid / dimethyldiallylammonium chloride copolymer, partial sodium salt (MWt 1500-4000, aqueous solution)24060NI0R0000(0)00D0 Acrylic acid / dimethyldiallylammonium chloride copolymer, partial sodium salt (MWt 1500-4000, aqueous solution)3682 RTECS NoCAS NoAcrylic acid/ethenesulfonic acid copolymer with phosphonate groups, sodium salt (aqueous solution)24170NI0NR0NI0(0)(0)00D0 Acrylic acid / ethenesulfonic acid copolymer with phosphonate groups, sodium salt solution3693 RTECS NoCAS NoAcrylonitrile25022NR3023322 CSMNTDE3 Acrylonitrile72 RTECS NoAT5250000 CAS No107-13-1 Acrylonitrile-styrene copolymer dispersion in polyether polyol (LOA)1432NI00NI1NI0(0)(0)0(0)S0 Acrylonitrile-Styrene copolymer dispersion in polyether polyol73 RTECS NoCAS NoAdiponitrile26000R1NI3(3)33(3)FD3 ANNEX 5 - GESAMP/EHS Composite LISTGESAMP Hazard ProfilesEHS 51/916 May 2014 Page 1 of 64 EHS NameTRN NameEHSTRNA1aA1bA1A2B1B2C1C2C3D1D2D3E1E2 E3 Adiponitrile74 RTECS NoAV2625000 CAS No111-69-3 Alachlor (ISO)1488333NI4110(2)10 CSS3 Alachlor technical (90% or more)

5 75 RTECS NoAE1225000 CAS No15972-60-8 Alcoholic beverages293000R0000001D1 Alcoholic beverages, NoCAS NoAlcoholic silicasol2198000R0000012DE2 Tetraethyl silicate monomer/oligomer (20% in ethanol)2475 RTECS NoCAS NoAlcohol(C12-C16) poly(20 and above)ethoxylates14824(3)(3)R20(0)(0)(2) 21D2 Alcohol (C12-C16) poly(20+)ethoxylates78 RTECS NoCAS NoAlcohol(C6-C17)(secondary) poly(3-6)ethoxylate722433R420(0)(3)32D3 Alcohol (C6-C17) (secondary) poly(3-6)ethoxylates81 RTECS NoCAS NoAlcohol(C6-C17)(secondary) poly(7-12)ethoxylate295333R4110(3)33D3 Alcohol (C6-C17) (secondary) poly(7-12)ethoxylates80 RTECS NoCAS NoAlcohol(C8-C11) poly( )ethoxylates2094333R3NI10(2)(2)(2)D2 Alcohol (C9-C11) poly ( ) ethoxylate2209 RTECS NoCAS NoAlcohol(C12-C16) poly(1-6)ethoxylates294533R4100(2)22FD2 Alcohol (C12-C16) poly(1-6)ethoxylates77 RTECS NoCAS NoAlcohol(C12-C16) poly(7-19)ethoxylates1481433R4110(3)33D3 Alcohol (C12-C16) poly(7-19)ethoxylates79 RTECS NoCAS NoAlcohol(C12 C14)poly(2)ethoxylate sulfate, sodium salt (*)24192NI2R3 NINININININININI3695 RTECS NoCAS NoAlcohols (C8-C11)2279522(R)(3)(1)(0)(0)(2)(2)(2)F p2 Alcohols (C8-C11), primary, linear and essentially linear2887 RTECS NoCAS NoAlcohols, C13 and above as individuals and mixtures2039522R41000(1)(1)Fp2 Alcohols (C13+)86 RTECS NoCAS NoAlcohols, C10-C16 ethoxylated propoxylated (*)24500NI0R3 NINININININININI3868 RTECS NoCAS NoAlcohols (C12-C13), linear2294522R4(1)

6 00(1)11Fp2 Alcohols (C12-C13), primary, linear and essentially linear2950 RTECS NoCAS NoAlcohols (C14-C18), linear2293522R0100(1)11Fp2 ANNEX 5 - GESAMP/EHS Composite LISTGESAMP Hazard ProfilesEHS 51/916 May 2014 Page 2 of 64 EHS NameTRN NameEHSTRNA1aA1bA1A2B1B2C1C2C3D1D2D3E1E2 E3 Alcohols (C14-C18), primary, linear and essentially linear2951 RTECS NoCAS NoAlcohols, linear (C10-C14)2365(5)(2)(2)(R)(4)(1)00(2)(2)( 2)Fp2 Decyl/Dodecyl/Tetradecyl alcohol mixture3128 RTECS NoCAS NoAlkanes (C6-C9)2202(5)NI(5)(R)(4)NI(0)(0)(1)(2)( 2)NFE2 Alkanes (C6-C9)88 RTECS NoCAS NoIso- and cyclo-alkanes (C10-C11)2203(5)NI(5)NI(0)(0)(0)(0)(1)(1 )(0)F1 Iso- and cyclo-alkanes (C10-C11)393 RTECS NoCAS NoIso-and cyclo-alkanes (C12+)2204(5)NI(5)NI(0)NI00(1)(0)(0)ANI2 Iso- and cyclo-alkanes (C12+)394 RTECS NoCAS NoAlkanes (C10-C17), linear and branched2463(5)NI(5)R0100(0)00AF3 Renewable Aviation Fuel3815 RTECS NoCAS NoAlkanes(C10 -C26), linear and branched23920NI0R0NI00(1)11AF3 Alkanes(C10-C26), linear and branched, (flashpoint >60 C)3562 RTECS NoCAS No90622-53-0 Alkanes (C5 - C7), linear and branched2464(5)NI(5)(R)(3)(0)00020 NAE2 Renewable Naphtha3799 RTECS NoCAS Non-Alkanes (C9-C11) 2449(5)NI(5)R0(0)00(2)10AF33867 RTECS NoCAS Non-Alkanes (C10-C20)296(5)NI(5)(R)(0)(0)(0)(0)(1)(1 )(0)AF3n-Alkanes (C10+)471 RTECS NoCAS NoAlkane (C14-C17) sulphonic acid, sodium salt334222R3100(2)22D2 Sodium alkyl (C14-C17) sulphonates (60-65% solution)

7 1153 RTECS NoCAS NoAlkaryl polyether (C9-C20) (LOA)19744NI4NR3NI00(3)23S2 Alkaryl polyethers (C9-C20)90 RTECS NoCAS NoAlkenoic acid ester, borated23765(3)(3)R2NI00(2)20Fp23153 RTECS NoCAS NoAlkenylamide, long chain, more than C1018583NI3(NR)4NI0(0)(1)01Fp2 Alkenyl (C11+) amide838 RTECS NoCAS NoAlkenyl succinic anhydride298000NR1NI00(2)2(2)SFD2 Alkenyl (C16-C20) succinic anhydride2336 RTECS NoCAS NoAlkyl acrylate/Vinyl pyridine copolymer in toluene299222R2000(2)22 RNAF/Fp3 ANNEX 5 - GESAMP/EHS Composite LISTGESAMP Hazard ProfilesEHS 51/916 May 2014 Page 3 of 64 EHS NameTRN NameEHSTRNA1aA1bA1A2B1B2C1C2C3D1D2D3E1E2 E3 Alkyl acrylate-vinylpyridine copolymer in toluene94 RTECS NoCAS NoAlkyl/cyclo(C4-C5)alcohols2447(1)(1)(1 )(R)(2)(0)(1)(1)(2)(2)(3)FED33825 RTECS NoCAS NoAlkyl amine, alkenyl acid ester, mixture1433 NINININI1NI(0)(0)NININISFp3 Alkyl(C8+)amine, Alkenyl (C12+) acid ester mixture98 RTECS NoCAS NoAlkylaryl phosphate mixtures (more than 40% Diphenyl tolyl phosphate, less than ortho-isomers)2267444R4400(1)10S1 Alkylaryl phosphate mixtures (more than 40% Diphenyl tolyl phosphate, less than ortho-isomers)280 RTECS NoCAS NoAlkylated phenols (C4-C9)2273020NR1010(2)11Fp2 Alkylated (C4-C9) hindered phenols2575 RTECS NoCAS NoAlkyl benzene distillation bottoms300022NR0(3)00111Fp2 Alkyl benzene distillation bottoms3106 RTECS NoCAS NoAlkyl (C12-C15)

8 Benzene/indane/indene mixture1872044NR0NI00002FE2 Alkylbenzene, alkylindane, alkylindene mixture (each C12-C17)103 RTECS NoCAS NoAlkylbenzene mixtures (containing at least 50% of toulene)2303(2)(2)(2)(R)(3)(0)00(2)22 ACMNRFE3 Alkylbenzene mixtures (containing at least 50% of toluene)2909 RTECS NoCAS NoAlkyl (C3-C4) benzenes2206(3)NI(3)R4NI00(2)(2)(1)FE2 Alkyl (C3-C4) benzenes91 RTECS NoCAS NoAlkyl (C5-C8) benzenes2207544(NR)4NI00(2)(2)(1)F2 Alkyl (C5-C8) benzenes92 RTECS NoCAS NoAlkyl benzenes, C9-C17 (straight or branched)1783044NR1NI0(0)(1)(1)(1)F1 Alkyl(C9+)benzenes100 RTECS NoCAS NoAlkylbenzenes mixture (containing less than 1% naphthalene)2423333NR4NI00(2)21 ACF3 Alkylbenzenes mixture (containing less than 1% naphthalene)3600 RTECS NoCAS NoAlkylbenzenes mixtures (containing naphthalene)2424(3)(3)(3)(NR)(4)NI00(1)1 1 ACF3 Alkylbenzenes mixture (containing naphthalene)3698 RTECS NoCAS NoAlkyl(C11-C13)benzenesulphonates, straight chain301333R311(1)(3)23FD3 Alkylbenzene sulphonic acid, sodium salt solution102 RTECS NoDB4370000 CAS No42615-29-2 Alkyl dithiocarbamate (C19-C35)22360NI0NI1NI00(0)00S0 Alkyl dithiocarbamate (C19-C35)2538 RTECS NoCAS NoAlkyl dithio thiadiazole (C6-C24) (LOA)19815NI5NR1NI00(0)

9 00S2 ANNEX 5 - GESAMP/EHS Composite LISTGESAMP Hazard ProfilesEHS 51/916 May 2014 Page 4 of 64 EHS NameTRN NameEHSTRNA1aA1bA1A2B1B2C1C2C3D1D2D3E1E2 E3 Alkyldithiothiadiazole (C6-C24)104 RTECS NoCAS NoAlkyl(C4-C20) ester copolymer (LOA)1986NI00NR0NI00(0)00Fp2 Alkyl ester copolymer (C4-C20)2202 RTECS NoCAS NoAlkylnaphthalenes, crude (containing less than 1% naphthalene)2425444R4NI00(1)11 ACF3 Alkylnaphthalenes (containing less than 1% naphthalene), crude3601 RTECS NoCAS NoAlkylnaphthalenes, crude (containing naphthalene)2426(4)(4)(4)(R)(4)NI00(1)11 ACF3 Alkylnaphthalenes (containing naphthalenes), crude3699 RTECS NoCAS NoAlkyl (C7-C9) nitrates84NI4NR3NI00(3)2(3)SF3 Alkyl (C7-C9) nitrates93 RTECS NoCAS NoAlkyl(C8-C40)phenol sulphide (LOA)19850NI0NR0NI00(1)11FD1 Alkyl (C8-C40) phenol sulphide2253 RTECS NoCAS NoAlkyl(C8-C9)phenylamine, in aromatic solvent (LOA)20962NI2NR3NI(0)(0)(2)22S2 Alkyl (C8-C9) phenylamine in aromatic solvents2200 RTECS NoCAS NoAlkyl (C9-C15) phenyl propoxylate21880NI0NR0NI00(2)22FD2 Alkyl (C9-C15) phenyl propoxylate2430 RTECS NoCAS NoAlkyl[(C8-C10)/(C12-C14)]:(<40%/>60%)polyglucoside mixture solution (max 55% active material)