GRAMOXONE® SL 2 - CDMS Home

1 safety data Sheet3/10/20157/8/2015 Replaces:Date: gramoxone SL 1. PRODUCT IDENTIFICATIONA7813 QUse:HerbicideProduct identifier on label: gramoxone SL :Syngenta Crop Protection, LLCPost Office Box 18300 Greensboro NC 27419 Manufacturer Phone:1-800-334-9481 Emergency Phone:1-800-888-8372 Product No.: 2. HAZARDS IDENTIFICATIOND angerClassifications:Signal Word (OSHA):May be corrosive to metalsHazard Statements:Harmful if swallowedCauses skin irritationFatal if inhaledCauses damage to organs Causes damage to organs through prolonged or repeated exposure Skin Corrosion/Irritation: Category 2 Specific Target Organ Toxicity: Single Category 1 Corrosive to Metals: Category 1 Oral: Category 4 Specific Target Organ Toxicity: Repeated Category 1 Inhalation: Category 1 Precautionary Statements.

2 Keep only in original not breathe mist, vapors, hands and face thoroughly after not eat, drink or smoke when using this only outdoors or in a well-ventilated protective gloves, protective clothing, eye case of inadequate ventilation wear respiratory protection. See Section 8 Exposure Control/Personal Protection. Hazard Symbols:Page 1 of 8 safety data Sheet3/10/20157/8/2015 Replaces:Date: gramoxone SL not precisely identified are proprietary or non-hazardous. Values are not product specifications.

3 3. COMPOSITION/INFORMATION ON INGREDIENTSC hemical NameConcentrationCommon NameCAS NumberOther ingredientsOther ingredientsTrade (1,1'-dimethyl-4,4'-bipyridinium dichloride)Paraquat 4. FIRST AID MEASURESHave the product container, label or safety data sheet with you when calling Syngenta (800-888-8372), a poison contol center or doctor, or going for IS ESSENTIAL. Immediate medical attention is required. If available, give an adsorbent such as activated charcoal, bentonite or Fuller's a poison control center or doctor immediately for treatment not give anything by mouth to an unconscious in eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes.

4 Remove contact lenses, if present, after 5 minutes, then continue rinsing eye. Call Syngenta (800-888-8372), a poison control center or doctor for treatment on skin or clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call Syngenta (800-888-8372), a poison control center or doctor for treatment person to fresh odor of this product is from the stenching agent, which has been added, not from the person is not breathing, call 911 or an a poison control center or doctor for further treatment :Eye Contact:Skin Contact:Inhalation:Most important symptoms/effects:Skin irritationFlammable hydrogen gas may be formed on contact with incompatible metals.

5 See "Conditions to Avoid", Section Hazard Statements:If swallowed: Call a poison center, doctor or Syngenta if you feel unwell. Rinse on skin: Wash with plenty of soap and skin irritation occurs: Get medical inhaled: Remove person to fresh air and keep comfortable for exposed or concerned: Call a poison center, doctor or call a poison center, doctor or medical advice if you feel treatment is urgent (see Section 4 First Aid Measures).Take off contaminated clothing and wash it before spillage to prevent material locked in corrosive resistant plastic, plastic-lined steel, stainless steel or fiberglass of contents and container in accordance with local 2 of 8 safety data Sheet3/10/20157/8/2015 Replaces:Date: gramoxone SL of immediate medical attention and special treatment needed:Refer to the booklet 'Paraquat Poisoning.

6 A Practical guide to Diagnosis, First Aid and Hospital Treatment'. ( ) Administer either activated charcoal (100 g for adults or 2 g/kgbody weight in children) or Fuller's Earth (15% solution; 1 liter for adults or 15 ml/kg body weight in children). NOTE: The use of gastric lavage without administration of an adsorbent has not shown any clinical benefit. Do not use supplemental oxygen. Eye splashes from concentrated material should be treated by an eye specialist after initial treatment. With the possibility of late onset corneal ulceration, it is advised that patients with paraquat eye injuries are reviewed by an eye specialist the day after first presentation.

7 Use treatment that is appropriate for chemical burns. Intact skin is an effective barrier to paraquat, however, contact with irritated or cut skin or repeated contact with intact skin may result in poisoning. 5. FIRE FIGHTING MEASURESS uitable (and unsuitable) extinguishing media:Specific Hazards:Special protective equipment and precautions for firefighters:Use dry chemical, foam or CO2 extinguishing media. If water is used to fight fire, dike and collect in alkaline media. This product reacts with aluminum to produce hydrogen gas.

8 Do not mix or store in containers or systems made of aluminum or having aluminum a fire, irritating and possibly toxic gases may be generated by thermal decomposition or full protective clothing and self-contained breathing apparatus. Evacuate nonessential personnel from the area to prevent human exposure to fire, smoke, fumes or products of combustion. 6. ACCIDENTAL RELEASE MEASURESP ersonal precautions, protective equipment, and emergency procedures:Methods and materials for containment and cleaning up:Follow exposure controls/personal protection outlined in Section spilled material can dry to a highly irritating the spill at its source.

9 Contain the spill to prevent from spreading or contaminating soil or from entering sewage and drainage systems or any body of water. Clean up spills immediately, observing precautions outlined in Section 8. Cover entire spill with absorbing material and place into compatible disposal container. Scrub area with hard water detergent ( commercial products such as Tide, Joy, Spic and Span). Pick up wash liquid with additional absorbent and place into compatible disposal container. Once all material is cleaned up and placed in a disposal container, seal container and arrange for disposition.

10 7. HANDLING AND STORAGEP recautions for safe handling:Conditions for safe storage, including any incompatibilities:Store above 32 F (0 C).Avoid contact with skin and eyes. Avoid inhalation of high concentrations of dusts. Avoid inhalation of liquid aerosols. Empty container retains product residue. Triple rinse, or equivalent, empty container, return rinse water to dilution mixture, and dispose of dilution mixture as a hazardous waste if it cannot be disposed of by use according to label instructions. Do not reuse container.