Green Chromium Oxide Safety Data Sheet - …

1 Revision date: 6/9/2015 Revision: 14 Supersedes date: 5/28/2015 Safety data SHEETC hromium Oxide Green1. IdentificationProduct identifierProduct nameProduct numberChromium Oxide GreenG4099,G5099,G6099,G7099,G8599,G6099 HP,GA4090,GA5090,GA6090,Accrox R,M100C,GO3955,GO4099R,GO6099R, G112 CAS number1308-38-9 Recommended use of the chemical and restrictions on useApplicationIndustrial colorDetails of the supplier of the Safety data sheetSupplierHuntsman Pigments Americas Box 4980 The Woodlands, TX 77387+1 301 210 3400 / +1 323 269 telephone numberEmergency telephoneCHEMTREC: (800) 424-9300 (Contract No: 191118)2.

2 Hazard(s) identificationClassification of the substance or mixtureOSHA Regulatory StatusThis Product is Hazardous under the OSHA Hazard Communication hazardsNot ClassifiedHealth hazardsNot ClassifiedEnvironmental hazardsNot ClassifiedLabel elementsHazard statementsNC Not ClassifiedOther hazardsThis product does not contain any substances classified as PBT or Composition/information on ingredientsMixturesCHROMIUM (III) Oxide > 98%CAS number: 1308-38-9 REACH registration number: ProprietaryClassificationNot ClassifiedThe Full Text for all Hazard Statements are Displayed in Section Clay Company # MCHRGRR evision date: 6/9/2015 Revision: 14 Supersedes date: 5/28/2015 Chromium Oxide GreenComposition commentsPigment Green 17, 772884.

3 First-aid measuresDescription of first aid measuresInhalationIf exposed to excessive levels of dust or fumes, remove to fresh air. Get medical attention ifcough or other symptoms physician if larger quantity has been ContactWash skin thoroughly with soap and water. Get medical attention if irritation persists contactRinse immediately with plenty of water. Remove any contact lenses and open eyelids wideapart. Continue to rinse for at least 15 minutes. Continue to rinse for at least 15 minutes. Getmedical attention if irritation persists after important symptoms and effects, both acute and delayedInhalationFrequent inhalation of dust over a long period of time increases the risk of developing to the physical nature of this material it is unlikely that swallowing will contactProlonged contact may cause redness.

4 Irritation and dry contactMay cause temporary eye of immediate medical attention and special treatment neededNotes for the doctorNo specific measuresExtinguishing mediaSuitable extinguishing mediaUse fire-extinguishing media suitable for the surrounding hazards arising from the substance or mixtureFlammability ClassNo Uniform Fire Code hazardsFire conditions may produce small amounts of hexavalent for firefightersProtective actions duringfirefightingN/ASpecial protective equipmentfor firefightersUse protective equipment appropriate for surrounding Accidental release measuresPersonal precautions, protective equipment and emergency proceduresPersonal precautionsFor personal protection, see Section precautionsEnvironmental precautionsAvoid spreading dust or contaminated materials.

5 Avoid discharge into drains or watercoursesor onto the ground. Avoid the spillage or runoff entering drains, sewers or and material for containment and cleaning date: 6/9/2015 Revision: 14 Supersedes date: 5/28/2015 Chromium Oxide GreenMethods for cleaning upRemove spillage with vacuum cleaner. If not possible, collect spillage with shovel, broom orthe like. Avoid generation and spreading of dust. Avoid the spillage or runoff entering drains,sewers or to other sectionsFor personal protection, see Section Handling and storagePrecautions for safe handlingUsage precautionsDo not eat, drink or smoke when using the product.

6 Good personal hygiene proceduresshould be implemented. Wash hands and any other contaminated areas of the body with soapand water before leaving the work site. For pallets wrapped in polyethylene plastic, removalmay cause an electrostatic spark; removal of the wrap should not be done in the presence offlammable for safe storage, including any incompatibilitiesStorage precautionsKeep container end uses(s)Specific end use(s)The identified uses for this product are detailed in Section Exposure Controls/personal protectionControl parametersOccupational exposure limitsCHROMIUM (III) OXIDELong-term exposure limit (8-hour TWA): ACGIH mg/m Short-term exposure limit (15-minute).

7 ACGIHACGIH = American Conference of Governmental Industrial commentsThreshold Limit Values (2005), ACGIH, by the American Conference on GovernmentalIndustrial controlsProtective equipment Appropriate engineeringcontrolsProvide adequate ventilation. Avoid inhalation of dust. Observe any occupational exposurelimits for the product or protectionThe following protection should be worn: Chemical splash protectionChemical-resistant, impervious gloves complying with an approved standard should be worn ifa risk assessment indicates skin contact is skin and bodyprotectionProvide eyewash station and Safety measuresNo specific hygiene procedures recommended but good personal hygiene practices shouldalways be observed when working with chemical products.

8 Wash hands at the end of eachwork shift and before eating, smoking and using the protectionA respiratory protection program that meets OSHA's 29 CFR and ANSI must be followed whenever workplace conditions warrant a respirator's date: 6/9/2015 Revision: 14 Supersedes date: 5/28/2015 Chromium Oxide Green9. Physical and Chemical PropertiesInformation on basic physical and chemical propertiesAppearanceDusty (concentrated solution): pH (diluted solution): 5 - 9 @ 10%Melting point2266 CInitial boiling point and rangeNot @ kg/m3 CBulk density600-1500 kg/m Solubility(ies)Insoluble @ C Insoluble in informationNo information organic compoundThis product contains a maximum VOC content of None.

9 10. Stability and reactivityReactivityThe following materials may react with the product: molten alkali at high temperature chlorinetrifluoride producing flame glycerol - may produce an explosionStabilityStable at normal ambient temperatures and when used as of hazardousreactionsWill not to avoidWater, to avoidChomic Oxide may react with molten alkali at high temperatures under oxidizing react with lithium, nitroalkanes, dirubidium acetylide, oxygen difluoride and other strongoxidizers. Reaction with chlorine trifluoride produces flame. Contact with glycerol andchromic Oxide my produce an decompositionproductsA small amount (< as Cr) of reversion to hexavalent Chromium may occur if the drychromium (III) Oxide powder is exposed to elevated Toxicological informationInformation on toxicological effectsToxicological effectsFrom literature surveys undertaken for Chromium (III) Oxide in powder form: LD50: >5000mg/kg (oral rat).

10 Chromic Oxide fed to rats in dosages up to 5% for 2 years produced notreatment related effects.[Ivankovic S. & Preussman R., Food Cosmet. Toxicol. 13, 347-351(1975).] Dermal: non-irritant Rabbit skin (24 h)Other health effectsIARC Not Listed. NTP Not Listed. OSHA Not Regulated. This product is a trivalent chromiumcompound that contains less than 100 ppm hexavalent Chromium . Trivalent Chromium is notspecifically listed as a carcinogen by NTP, IARC or toxicity - oralAcute toxicity oral (LD date: 6/9/2015 Revision: 14 Supersedes date: 5/28/2015 Chromium Oxide GreenAcute toxicity - inhalationAcute toxicity inhalation (LC dust/mist mg/l) informationNo specific health hazards may irritate the respiratory system.)