HACH LANGE GmbH Safety Data Sheet - Camlab

1 LCK 014 CSB/COD/DCOS afety data Sheetaccording to 2001/58/ECProduct code : LCK014 Print date : 1 of 7 hach LANGE GmbH1. Identification of the substance/preparation and of the Identification of the substance or preparationLCK 014 CSB/COD/DCOUse of the substance/preparationWater Company/undertaking identificationHACH LANGE GmbHCompany nameStreetWillst tterstr. 11 PlaceD-40549 D sseldorfTelephone+49(0)2115288 officeHACH LANGE Ltd. Pacific WaySalford Manchester M50 1DL - EnglandTel. +44 (0) 161 872 1487 e-Mail: Composition/information on ingredientsChemical characterization( preparation )Hazardous name7664-93-965 %C R35231-639-5sulphuric acid .. %7732-18-533 %213-791-2 Water7778-50-9<1 %O, Carc.

2 Cat. 2, Muta. Cat. 2, Repr. Cat. 2, T+, T, Xn, C, N R8-45-46-60-61-26-25-48/23-21-34-42/43-5 0-53231-906-6potassium dichromate7783-35-9<1 %T+, N R33-26/27/28-50-53233-653-7 Mercury(II) sulfate10294-26-5<0,5 %Xi R41233-653-7 Silver sulfateFull text of each relevant R phrase can be found in heading Hazards identificationClassificationSymbols : Toxic, CorrosiveR-phrases :May cause cause heritable genetic impair cause harm to the unborn of cumulative severe by inhalation, in contact with skin and if cause sensitization by inhalation and skin to aquatic organisms, may cause long-term adverse effects in the aquatic First aid measuresRevision no. : 1,00 Revision date : GB - ENLCK 014 CSB/COD/DCOS afety data Sheetaccording to 2001/58/ECProduct code : LCK014 Print date : 2 of 7 hach LANGE GmbHTake off all contaminated clothing immediately.

3 Consult a physician. Show this Safety data Sheet to the doctor in informationMove to fresh air. Consult a physician. Show this Safety data Sheet to the doctor in inhalationWash off immediately with plenty of water for at least 15 minutes. Immediate medical treatment is necessary as untreated wounds from corrosion of the skin heal slowly and with difficulty. Show this Safety data Sheet to the doctor in contact with skinRinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Show this Safety data Sheet to the doctor in contact with eyesClean mouth with water and drink afterwards plenty of water. Do NOT induce a physician. Show this Safety data Sheet to the doctor in ingestionTreat to doctor5.

4 Fire-fighting measuresUse extinguishing measures that are appropriate to local circumstances and the surrounding environment. The product itself does not extinguishing mediaSpecial exposure hazards arriving from substance or preparation itself, combustion products, resulting gasesFire may liberate hazardous vapours. The following may develop in event of fire: sulfur oxides, mercury the event of fire, wear self-contained breathing apparatus. In order to avoid contact with skin, keep a Safety distance and wear suitable protective protective equipment for fire-fightersFire residues and contaminated fire extinguishing water must be disposed of in accordance with local information6.

5 Accidental release measuresUse personal protective precautionsDo not flush into surface water or sanitary sewer precautionsSoak up with inert absorbent material and dispose of as hazardous for cleaning up/taking upFire residues and contaminated fire extinguishing water must be disposed of in accordance with local information7. Handling and HandlingRevision no. : 1,00 Revision date : GB - ENLCK 014 CSB/COD/DCOS afety data Sheetaccording to 2001/58/ECProduct code : LCK014 Print date : 3 of 7 hach LANGE GmbHUse only in well-ventilated areas. Do not breathe on safe StorageKeep tightly closed in a dry, cool and well-ventilated place. Protect against light.

6 Accessible only for authorized for storage rooms and vessels8. Exposure controls/personal Exposure limit valuesExposure limits (EH40)CategoryF/mlmg/m ml/m SubstanceCAS (8 h)Mercury(II) sulfate7783-35-90,1 MAKSTEL (15 min)MAKBAT values (TRGS 903)CAS materialValueParameterSampling time7439-97-6 Quecksilber, Exposure controlsThe type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific and hygiene measuresBreathing apparatus only if aerosol or dust is protectionUse barrier skin cream. Wash hands before breaks and after work. Chemical resistant protective gloves The protective gloves to be used must comply with the specifications of EC directive 89/686/EEC and the resultant standard protectionsafety glasses with side-shieldsEye protectionRemove and wash contaminated clothing before protection9.

7 Physical and chemical propertiesColourPhysical General Important health, Safety and environmental informationTest methodpH-Value (at 20 C) :< 1 Changes in the physical stateBoiling point300 Cnot applicableFlash pointFlammabilityRevision no. : 1,00 Revision date : GB - ENLCK 014 CSB/COD/DCOS afety data Sheetaccording to 2001/58/ECProduct code : LCK014 Print date : 4 of 7 hach LANGE GmbHnot applicableSolidnot applicableGasnot applicableLower explosion limitsnot applicableUpper explosion limits1,55 g/cm Density (at 20 C) :completely solubleWater solubility : at (20 C) Other informationnot applicableIgnition temperatureno data available10. Stability and reactivityTo avoid thermal decomposition, do not overheat.

8 Above 300 C, hazardous fumes may be to avoidorganic materials, bases, alkali metals, metals, ammonia, reducing agents, nitric acid. Reacts violently with to avoidSulphur trioxide chromium oxidesHazardous decomposition productsvery reactiveAdditional information11. Toxicological informationNo data is available on the product itself. Information given is based on data on the components and the toxicology of similar toxicityThe product causes burns of eyes, skin and mucous and irritant effectsMay cause sensitization by inhalation and skin effectsCarcinogenic/mutagenic/toxic effects for reproductionCarcinogen. Mutagen. toxic effects for reproduction12. Ecological informationMay cause long-term adverse effects in the aquatic not flush into surface water or sanitary sewer Disposal considerationsAdvice on disposalOur local agencies will accept used cuvettes to ensure their proper disposal.

9 In accordance with local and national no. : 1,00 Revision date : GB - ENLCK 014 CSB/COD/DCOS afety data Sheetaccording to 2001/58/ECProduct code : LCK014 Print date : 5 of 7 hach LANGE GmbHWaste disposal number of waste from residues/unused products160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures of laboratory chemicalsClassified as hazardous disposal number of used productWASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures of laboratory chemicalsClassified as hazardous Transport informationLand transport (ADR/RID)8 ADR/RID classWarning plateUN number29228+ labelIADR/RID packing groupCorrosive liquid, toxic, of the goodsInland waterways transportnot testedRemarks (inland waterways transport)Marine transport8+ code3316UN number--Marine pollutantF-A, S-PEmSIIMDG packing groupDescription of the goodsCorrosive liquid, toxic, (Chromosulphuric acid, mercury sulphate)Air transport8+ numberIICAO packing groupCorrosive liquid, toxic, (Chromosulphuric acid, mercury sulphate)

10 Description of the goods15. Regulatory LabellingT - Toxic; C - CorrosiveIndication of dangerT - ToxicC - CorrosiveClassification according to European directive on classification of hazardous preparations 1999/45 according to EC-guidelinesRevision no. : 1,00 Revision date : GB - ENLCK 014 CSB/COD/DCOS afety data Sheetaccording to 2001/58/ECProduct code : LCK014 Print date : 6 of 7 hach LANGE GmbHpotassium dichromatesulphuric acid .. %Mercury(II) sulfateHazardous component(s) to be indicated on labelR phrases33 Danger of cumulative severe cause cause heritable genetic impair cause harm to the unborn by inhalation, in contact with skin and if cause sensitization by inhalation and skin to aquatic organisms, may cause long-term adverse effects in the aquatic phrases53 Avoid exposure - obtain special instructions before case of contact with eyes, rinse immediately with plenty of water and seek medical case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).