Illinois Industrial Carbon Capture & Storage Project

1 Illinois Industrial Carbon Capture & Storage ProjectEliminating CO2 Emissions from the Production of Bio Fuels -A Green Carbon ProcessBioeconomy 2017 July 11, 2017 Scott McDonaldBiofuels Development DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANY The Industrial Carbon Capture and Storage (ICCS) Project is administered by the Department of Energy's Office of Fossil Energy and managed by the National Energy Technology Laboratory (award number DE-FE-0001547) and by a cost share agreement with the ADM, U of I (ISGS), SLB, & RCC. The Intelligent Monitoring System (IMS) Project is administered by the Department of Energy's Office of Fossil Energy and managed by the National Energy Technology Laboratory (award number DE-FE-0026517) and by a cost share agreement with the ADM, LBNL, Silixa, SLB, U of I (ISGS), & RCC.

2 The Midwest Geological Sequestration Consortium (MGSC) is funded by the Department of Energy through the National Energy Technology Laboratory via the Regional Carbon Sequestration Partnership Program (contract number DE-FC26-05NT42588) and by a cost share agreement with the Illinois DCEO. The MGSC is a collaboration led by the geological surveys of Illinois , Indiana, and KentuckyAcknowledgementsARCHER DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANYP rogram ObjectiveLarge scale geologic test to inject million tons of CO2 over a three year period (1,000 MT/day). Project Team Members Knowledge Base-Site Geological Characterization-Risk Assessment & Reservoir Modeling-Engineering Design & MVANov 2014-Completed goal of injecting and storing 1,000,000 tons of Basin Decatur Project (IBDP)ARCHER DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANYP rogram Objectives-Target & Demonstrate Advanced CCS Technologies at Industrial Scale Facilities-Inject and Store One Million Tons of CO2 Annually (3,000 tons/day)

3 Project Team MembersKnowledge Base-Site Geological Characterization-Risk Assessment & Reservoir Modeling-Engineering Design & MVA-Education and Public OutreachStudy the interaction between the CO2plumes from two injection wells within the same Industrial CCS Project (IL-ICCS)ARCHER DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANYP rogram Objectives-Develop and validate software tools that advance CCS-specific IMS by enabling access, integration and analysis of real-time surface and subsurface data for decision-making and automation of process-Demonstrate integration of system components to validate feasibility of real-world application to Team MembersIntelligent Monitoring System (IMS)ARCHER DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANYWet CO2from Corn-to-EthanolFermentationCO2 Inlet SeparatorCentrifugal Blower (3000 HP)CO2 CO2P=35 Dehydrated CO2to 4thStageCO2 Contactor3rdStage Discharge CO2P=590 CO2 Sequestration ~7,000 ft.

4 Depth in Mt. Simon SandstoneNew Albany Shale (D=2000, T=120): Tertiary SealPrimary Source of Drinking Water (D=140)Pre-Cambrian Granite (D=7200)Eau Claire Shale (D=5000, T=500): Primary SealMt. Simon Sandstone (D=5500, T=1600): Saline ReservoirMaquoketa Shale (D=2600, T=200): Secondary SealCentrifugal Booster Pump(400 HP)Reciprocating Compressors (3250 HP) 4 Stages with Intercoolers4thStage Discharge CO2 P=1425 Tri-ethylene Glycol Dehydration Unit Return Dry Glycol WaterGlycol RegeneratorSupercritical CO28- in, 1-mile Pipeline2500-3000 MTPD M< line1500-ftInjection WellP set by permit (estimate <2300)St. Peter Sandstone Lower Most USDW (D=4000)

5 Project Process Flow DiagramARCHER DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANY Cratonicbasin 60,000 square mile area Structurally complex to the south with faulting and seismicity ADM Decatur facility is located near the center of this geologic formation Estimated CO2storage capacity between 27 to 109 billion metric tonsSite SelectionRegional Geologic CharacterizationADMARCHER DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANYSite CharacterizationSeismic Acquisition ARCHER DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANYTest Well ConstructionARCHER DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANYC oring and Well LoggingARCHER DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANYG eophysical Model DevelopmentARCHER DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANYS eismic LogCoreInitial

6 Conditions1 DMEMS eismicStatic Model3 DMEMP ressure Saturation Fluid Props RelPermInitial ConditionsPressure Stress Feature StrengthsInitializeInitializeRates Pressure SaturationHistorical DataObsDeformMicroseisHistory MatchHistory MatchRate Schedules CompletionForecast ScenariosForecastForecastRegulationOpera tionEconomicsTarget/ObjectivesCaprockWel lboreInducedSeis-RiskEvaluateStructureSt ructurePorosityPermStructureElasticModul usFeaturesPredictedDeformationFailurePre dicted SaturationPressureReservoir Flow ModelGeomechanical ModelIterationPressurePressureInitial ConditionsInitial ConditionsCalibrate ModelCalibrate ModelGeophysical Model FrameworkARCHER DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANYG eophysical ModelingCO2 Plume Position - 2012S- SWN-NEEau ClaireLower Mt SimonUpperMt SimonCross Section OrientationARCHER DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANYG eophysical ModelingCO2 Plume Position - 2013S- SWN-NEEau ClaireLower Mt SimonUpperMt SimonCross Section OrientationARCHER DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANYG eophysical ModelingCO2 Plume Position - 2014S- SWN-NEEau ClaireLower Mt SimonUpperMt SimonCross Section OrientationARCHER DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANYG eophysical ModelingCO2 Plume Position - 2015S- SWN-NEEau ClaireLower Mt SimonUpperMt SimonCross Section OrientationARCHER DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANYG eophysical ModelingCO2

7 Plume Position - 2016S- SWN-NEEau ClaireLower Mt SimonUpperMt SimonCross Section OrientationARCHER DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANYG eophysical ModelingCO2 Plume Position - 2017S- SWN-NEEau ClaireLower Mt SimonUpperMt SimonCross Section OrientationARCHER DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANYG eophysical ModelingCO2 Plume Position - 2018S- SWN-NEEau ClaireLower Mt SimonUpperMt SimonCross Section OrientationARCHER DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANYG eophysical ModelingCO2 Plume Position - 2019S- SWN-NEEau ClaireLower Mt SimonUpperMt SimonCross Section OrientationARCHER DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANYG eophysical ModelingCO2 Plume Position - 2020S- SWN-NEEau ClaireLower Mt SimonUpperMt SimonCross Section OrientationARCHER DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANYE nvironmental Monitoring (MVA)

8 Conceptual FrameworkNear SurfaceSoil and Vadose ZoneAerial ImagerySoil CO2 FluxGround WaterGeochemical SamplingP/T MonitoringDeep SubsurfaceAbove SealGeophysical SurveysSeismic MonitoringP MonitoringInjection ZoneGeophysical SurveysGeochemical samplingP/T MonitoringARCHER DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANYE nvironmental MonitoringNear Surface Monitoring Near infrared aerial imagery will be used to evaluate plant stress Soil resistivity characterized shallow depths for identification of optimum GWM locations GWM for baseline conditions and operational surveillance Surface soil CO2flux monitoringARCHER DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANYE nvironmental MonitoringDeep Subsurface Monitoring Deep P/T monitoring Distributed Temp Sensor Distributed Vibration Sensor Multi-levelfluid sampling ports P/T monitoring above the seal formation Deep geophones arrays allowing vertical seismic profiling (VSP) Pulseneutron well logging ARCHER DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANYS eismic MonitoringUSGS Site Monitoring ARCHER DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANYDeep Seismic Monitoring 3 Geophone Arrays in CCS1 24 Active Geophones in GM1 5 Level Geophone Array in GM2 7 Borehole Stations (500 ft) 14 Surface StationsDistributed Acoustic Sensing (DAS)

9 Example from PTRC AquistoreDAS Baseline 3D-VSP29 Flow unitsSealsStorageCasing DeploymentOf Fiber Optic LinesDAS VSP is becoming accepted Equipment Layout30VW#22,600 CCS#2SS#1350 SS#22,150 SS#34,250 GM#2SS#41,800 SS#53,850 ROTARY SEISMIC SOURCE GENERATOR (NOTE 1)INJECTION AND MONITORING WELLS (EXISTING)DAS FIBER OPTIC LINE (BORED TO 25 FT)NOTE 1: DISTANCES ARE MEASURED FROM CCS#2 Plume OverlayTechnologies Developed under DOE Core R&D are incorporated into the IMS31 Rotary Orbital SourceBroadside Sensitive Cable32 IMS Data Acquisition ArchitectureARCHER DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANYS eismic Monitoring DataFrequency of DetectedEvents/Day8007006005004003002001 0002/1/125/11 /128/19/12 Time11 /27/123/7/13 ARCHER DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANYCO2 Based Chemicals Carbonates Glycerol Carbonate Propylene Carbonate Dimethyl Carbonate Fertilizers Alcohols Fuels Acids OthersTransformation of Carbon Dioxide, Sakakura, Choi, & Yasuda.

10 2007 ARCHER DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANYE nhanced Oil DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANY(1)BASIN ORIENTED STRATEGIES FOR CO2 ENHANCED OIL RECOVERY: Illinois AND MICHIGAN BASIN OF Illinois , INDIANA, KENTUCKY AND MICHIGAN; Advanced Resources International, February 2006 Illinois Basin - Oil Producing Region Est. Recoverable Oil = 700 million bbls(1) Est. CO2 Requirements = 150 million tonsADM Plants10,000 TPDI llinois Basin PotentialARCHER DANIELS MIDLAND COMPANYARCHER DANIELS MIDLAND COMPANYT hank You! Industrial Carbon Capture and Storage Project : Department of Energy Award No. DE-FE-0001547 Administered by the DOE s Office of Fossil Energy Managed by the National Energy Technology LaboratoryCost Share Agreements: Archer Daniels Midland Company University of Illinois through the Illinois State Geological Survey Schlumberger Carbon Services Richland Community CollegeProject Team Members Contacts: Dr.