KCB Methylated Spirits - GSB Chemicals

1 KCB Methylated SpiritsHazard Alert Code: HIGHC hemwatch material safety data SheetIssue Date: 11-Mar-2014 CHEMWATCH 23-0387A317 LPVersion Page 1 of 18 Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONPRODUCT NAMEKCB Methylated SpiritsSYNONYMSE thanol, "Denatured Absolute Alcohol", "Industrial Methylated Spirits "PROPER SHIPPING NAMEETHANOL (ETHYL ALCOHOL) or ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION)PRODUCT USEThe use of a quantity of material in an unventilated or confined space may result in increased exposure and an irritating atmosphere developing. Before starting consider control of exposure by mechanical according to manufacturer's for adhesives, coatings, resins and :KCBS alesAddress:84 CampRoadBroadmeadowsVIC,3047 AustraliaTelephone:+613 94571125 EmergencyTel:+613 94571125(9am-5pm)Fax:+613 94597978 Section 2 - HAZARDS IDENTIFICATIONSTATEMENT OF HAZARDOUS NATUREHAZARDOUS SUBSTANCE.

2 DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG HAZARD RATINGSF lammability Toxicity Body Contact Reactivity Chronic SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme= Methylated SpiritsHazard Alert Code: HIGHC hemwatch material safety data SheetIssue Date: 11-Mar-2014 CHEMWATCH 23-0387A317 LPVersion Page 2 of 18 Section 2 - HAZARDS IDENTIFICATIONRISKSAFETY Highlyflammable. Keepawayfromsourcesof Harmfulbyinhalationandif Donotbreathegas/fumes/ Irritatingto eyesandskin. Avoidcontactwithskin. Repeatedexposuremaycauseskin Cumulativeeffectsmayresult *. Mayproducediscomfortof the *. Vapourspotentiallycause *.* (limitedevidence). Useonlyin wellventilatedareas. Keepcontainerin a wellventilatedplace. Donotemptyintodrains.

3 Tocleanthefloorandallobjectscontaminated bythismaterial,usewater. Keepcontainertightlyclosed. Keepawayfromfood,drinkandanimalfeedingst uffs. In caseof contactwitheyes,rinsewithplentyof waterandcontactDoctororPoisonsInformatio nCentre. If swallowed,IMMEDIATELY contactDoctororPoisonsInformationCentre. (showthiscontainerorlabel). Thismaterialanditscontainermustbedispose dof 3 - COMPOSITION / INFORMATION ON INGREDIENTSNAMECAS RN%ethanol64-17-570-100denaturant<1water 7732-18-50-35 Section 4 - FIRST AID MEASURESSWALLOWED If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; becoming unconscious.

4 Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Seek medical If this product comes in contact with the eyes: Wash out immediately with fresh running Methylated SpiritsHazard Alert Code: HIGHC hemwatch material safety data SheetIssue Date: 11-Mar-2014 CHEMWATCH 23-0387A317 LPVersion Page 3 of 18 Section 4 - FIRST AID MEASURES Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. Seek medical attention without delay; if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled If skin contact occurs: Immediately remove all contaminated clothing, including footwear.

5 Flush skin and hair with running water (and soap if available). Seek medical attention in event of If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary. Transport to hospital, or TO PHYSICIANAsin allcasesof suspectedpoisoning,followtheABCDEsof emergencymedicine(airway,breathing,circu lation,disability,exposure),thentheABCDE sof toxicology(antidotes,basics,changeabsorp tion,changedistribution,changeeliminatio n).

6 Forpoisons(wherespecifictreatmentregimei s absent):-------------------------------- ------------------------------BASICTREAT MENT------------------------------------ -------------------------- Establisha patentairwaywithsuctionwherenecessary. Watchforsignsof respiratoryinsufficiencyandassistventila tionasnecessary. Administeroxygenbynon-rebreathermaskat 10to 15L/min. Monitorandtreat,wherenecessary,forpulmon aryoedema. Monitorandtreat,wherenecessary,forshock. Anticipateseizures. suspectedrinsemouthandgiveupto 200mlwater(5ml/kgrecommended)fordilution wherepatientis ableto swallow,hasa Considerorotrachealornasotrachealintubat ionforairwaycontrolin unconsciouspatientorwhererespiratoryarre sthasoccurred. Positive-pressureventilationusinga bag-valvemaskmightbeof use.

7 Monitorandtreat,wherenecessary,forarrhyt hmias. StartanIV signsof Drugtherapyshouldbeconsideredforpulmonar yoedema. Hypotensionwithsignsof hypovolaemiarequiresthecautiousadministr ationof Treatseizureswithdiazepam. Proparacainehydrochlorideshouldbeusedto , , Methylated SpiritsHazard Alert Code: HIGHC hemwatch material safety data SheetIssue Date: 11-Mar-2014 CHEMWATCH 23-0387A317 LPVersion Page 4 of 18 Section 4 - FIRST AID MEASURES Acuteingestionin non-tolerantpatientsusuallyrespondsto supportivecarewithspecialattentiontoprev entionof aspiration,replacementof fluidandcorrectionof nutritionaldeficiencies(magnesium,thiami nepyridoxine,VitaminsC andK). Give50%dextrose(50-100ml)IV to obtundedpatientsfollowingblooddrawforglu cosedetermination.

8 Comatosepatientsshouldbetreatedwithiniti alattentionto airway,breathing,circulationanddrugsofim mediateimportance(glucose,thiamine). Decontaminationis probablyunnecessarymorethan1 houraftera singleingestions. Fructoseadministrationis contra-indicateddueto 5 - FIRE FIGHTING MEASURESEXTINGUISHING MEDIA Watersprayorfog. Alcoholstablefoam. Drychemicalpowder. waterjetto FIGHTING AlertFireBrigadeandtellthemlocationandna tureof hazard. Maybeviolentlyorexplosivelyreactive. Wearbreathingapparatusplusprotectiveglov esin theeventof a fire. Prevent,byanymeansavailable,spillagefrom enteringdrainsorwatercourse. Considerevacuation(orprotectin place). Fightfirefroma safedistance,withadequatecover. If safe,switchoffelectricalequipmentuntilva pourfirehazardremoved.

9 Usewaterdeliveredasa finesprayto controlthefireandcooladjacentarea. Avoidsprayingwaterontoliquidpools. Donotapproachcontainerssuspectedto behot. Coolfireexposedcontainerswithwatersprayf roma protectedlocation. If safeto doso,removecontainersfrompathof (includingroadandrailtankers)is involvedin a fire,considerevacuationby500metresin HAZARD Liquidandvapourarehighlyflammable. Severefirehazardwhenexposedto heat,flameand/oroxidisers. Vapourmaytravela considerabledistanceto sourceof ignition. Heatingmaycauseexpansionordecompositionl eadingto violentruptureof containers. Oncombustion,mayemittoxicfumesof carbonmonoxide(CO).Combustionproductsinc lude:carbondioxide(CO2),otherpyrolysispr oductstypicalof :Closedcontainersmayrupturedueto INCOMPATIBILITY ,oxidisingacids,chlorinebleaches, Methylated SpiritsHazard Alert Code: HIGHC hemwatch material safety data SheetIssue Date: 11-Mar-2014 CHEMWATCH 23-0387A317 LPVersion Page 5 of 18 Section 6 - ACCIDENTAL RELEASE MEASURESMINOR SPILLS Removeallignitionsources.

10 Cleanupallspillsimmediately. Avoidbreathingvapoursandcontactwithskina ndeyes. Controlpersonalcontactwiththesubstance,b yusingprotectiveequipment. Containandabsorbsmallquantitieswithvermi culiteorotherabsorbentmaterial. Wipeup. Collectresiduesin a SPILLS Clearareaof personnelandmoveupwind. AlertFireBrigadeandtellthemlocationandna tureof hazard. Maybeviolentlyorexplosivelyreactive. Wearbreathingapparatusplusprotectiveglov es. Prevent,byanymeansavailable,spillagefrom enteringdrainsorwatercourse. Considerevacuation(orprotectin place). Nosmoking,nakedlightsorignitionsources. Increaseventilation. Stopleakif safeto doso. Watersprayorfogmaybeusedto disperse/absorbvapour. Containspillwithsand,earthorvermiculite. Useonlyspark-freeshovelsandexplosionproo fequipment.