MATERIAL SAFETY DATA SHEET - …

1 Issued by: Rentokil Initial Pty LimitedProduct: Rentokil IGR Grain ProtectantPhone: (02)9370 9300 Page 1 of 3 Revised: September, 2000 MATERIAL SAFETY data SHEETC ompany DetailsRentokil Initial Pty Ltd150 Mowbray RdWilloughby NSW 2068 ACN 000 034 597 Emergency Telephone(02)9370 9300 Not classified as hazardous according to the criteria of NOHSC IDENTIFICATIONP roduct Name: Rentokil IGR Grain ProtectantOther Names: Code: No: None allocatedHazchem Code: None allocatedDangerous Goods Class: None allocatedSub Risk Class: None allocatedPackaging Group: None allocatedPoison Schedule: S5 Chemical Family: Blend of ingredients (see below). Active ingredient is methoprene, an Insect Growth : For mixing with uninfested cereal grain for protection against immature stages of Lesser Grain Borer, Rust-RedFlour Beetle and Sawtoothed Grain Beetle, including organophosphate-resistant Appearance & PropertiesAppearance & Odour: Clear, straw coloured liquid.

2 Mild hydrocarbon point: No specific data . Liquid at normal point and vapour pressure: No materials: No specific data . Expected to be low at 100 : Not gravity: No in water: : Not Exposure LimitsChemical EntityCAS NoProportion, %TWA, mg/m3 STEL, mg/m3methoprene40596-69-83not setnot setLiquid hydrocarbonsecret72not setnot setOther non hazardous ingredientssecretto 100not setnot setThis is a commercial product whose exact ratio of components may vary. Trace quantities of impurities are also HEALTH HAZARD DATAH ealth Effects:No specific data is available for the product for chronic exposure symptoms. The ingredients are not listed ascarcinogenic in Worksafe s document Exposure Standards for Atmospheric Contaminants in the OccupationalEnvironment (May 1995), nor in NOHSC s List of Designated Hazardous Substances (April 1999).

3 No Methoprene-related effects were observed in two-year feeding trials with rats given up to and including a 5,000ppm diet, nor in miceon a 250ppm diet, daily for 18 Effects:Swallowed: data suggests that this product should present no significant : This product may be mildly irritating to eyes. However, it is unlikely to cause any more than mild transientdiscomfort. It is also unlikely to cause any lasting : This product may be mildly irritating to skin. However, it is unlikely to cause any more than mild transientdiscomfort. It is also unlikely to cause any lasting : data suggests that this product should present no significant Methoprene LD50 Oral (Rat) 34,600mg/kg. LD50 Oral (dog) 5,000 to 10,000 mg/kgMATERIAL SAFETY data SHEETI ssued by: Rentokil Initial Pty LimitedProduct: Rentokil IGR Grain ProtectantPhone: (02)9370 9300 Page 2 of 3 Revised: September, 2000LD50 Dermal (Rabbit) 3,038 - 10,250 mg/kg.

4 LC50 (rat) >210 Aid:If poisoning occurs, contact a Doctor or Poisons Information Centre. Phone 13 1126 from anywhere in : If product gets in eyes, wash MATERIAL from them with running water. If they begin watering or reddening, takespecial care in washing : If product gets on skin, thoroughly wash contacted areas. No further measures should normally be required unlessirritation is noticed. If irritation persists, seek medical : No first aid measures normally required. However, if vapours or mists have been inhaled, and irritation hasdeveloped, remove to fresh air and observe until recovered. If irritation becomes painful or persists more than about 30minutes, seek medical to Doctor: Treat symptomatically. Note the nature of this PRECAUTIONS FOR USEE xposure Standards:A time weighted average (TWA) concentration for an 8 hour day, and 5 day week has not been established by NOHSCA ustralia for any of the major ingredients in this product.

5 There is a blanket limit of 10mg/m3 for dusts or mists whenlimits have not otherwise been established. The ADI (Acceptable Daily Intake) for methoprene is set at corresponding NOEL (No-observable-effect-level) is set at Values taken from Australian ADI List,May Controls:In industrial situations, concentration values below the TWA value should be maintained. Values may be reduced byprocess modification, use of local exhaust ventilation, capturing substances at the source, or other methods. If youbelieve air borne concentrations of mists, dusts or vapours are high, you are advised to modify the process orenvironment to reduce the Protection:Respiratory Protection: It is usually safe to not use a dust mask or respirator protection on account of this , if the product is being used in dusty or confined conditions, use of a mask or respirator may be preferred.

6 Forhelp in selecting suitable equipment, consult AS/NZS Gloves: Impermeable protective gloves should be worn when you are using this product, to prevent help in selecting suitable equipment, consult AS Protection: Protective eyewear is not normally necessary when using this product. However, it is always prudent touse protective eyewear. Consult AS1336 and AS/NZS 1337 for advice on Industrial Eye : This product is essentially safe to use without special protective clothing. However, its use is recommended asa good industrial practice. Consult AS2919 for advice on Industrial Boots: Wearing SAFETY boots in industrial situations is advisory. Consult AS/NZS2210 for advice on OccupationalProtective wash hands before smoking, eating or using the toilet. Wash contaminated clothing and other protectiveequipment before storing or SAFE HANDLING INFORMATIONS torage & TransportNo special storage and transport requirements.

7 This product has no UN classification. This product is a S5 all relevant regulations regarding sale, transport and storage of this class of product. Containers should bekept closed in order to minimise contamination. Keep from extreme heat and open flames, and make sure that theproduct does not come into contact with substances listed under "Materials to avoid" & DisposalsIn the event of a major spill, prevent spillage from entering drains or water courses. As a minimum, wear overalls,goggles and gloves. Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitableabsorbent MATERIAL . Sweep up and shovel or collect recoverable product into labelled containers for recycling orsalvage. After spills, wash area preventing runoff from entering drains. If a significant quantity of MATERIAL enters drains,advise emergency services.

8 Full details regarding disposal of used containers, spillage and unused MATERIAL may befound on the label. If there is any conflict between this MSDS and the label, instructions on the label prevail. Dispose ofonly in accord with all SAFETY data SHEETI ssued by: Rentokil Initial Pty LimitedProduct: Rentokil IGR Grain ProtectantPhone: (02)9370 9300 Page 3 of 3 Revised: September, 2000 Fire & Explosion HazardThere is a slight risk of an explosion from this product if it is involved in a : Not limits: Not applicable. This product is not Media: carbon dioxide, dry chemical, foam, water Fire Fighting procedures: Immediately evacuate the area of unnecessary personnel. When fighting firesinvolving significant quantities of this product, wear SAFETY boots, non-flammable overalls, gloves, hat and preferably, Fire & Explosion Hazards: Fire decomposition products from this product may form toxic mixtures in confinedspaces.

9 Vapours from this product are heavier than air and may accumulate in sumps, pits and other low-lying spaces,forming potentially explosive mixtures. They may also flash back considerable distances. Violent steam generation oreruption may occur upon application of direct water stream on hot : This product is unlikely to spontaneously : This product is unlikely to spontaneously Products: Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. to avoid: oxidising OTHER INFORMATIONThis MSDS is prepared in accord with the Worksafe Australia document National Code of Practice for the Preparationof MATERIAL SAFETY data Sheets , Points:Police and Fire Brigade:Dial 000If ineffective:Dial 1100 (Exchange)For emergency response:Dial (02)9370 9300 National Poisons Information Centre:Dial 13 1126 (from anywhere in Australia)THE data USED TO PREPARE THIS DOCUMENT HAS BEEN COLLATED FROM PUBLISHED IS THE RESPONSIBILITY OF THE USER TO SATISFY HIMSELF OF THE COMPLETENESS OR SUITABILITY OF THEINFORMATION FOR HIS OWN read all labels carefully before using MSDS copyright Kilford & Kilford Pty Ltd, June, Phone (02)9516 2079