Material Safety Data Sheet

1 SDSEU / EN / TSDSEU02 Version: Revision Date: Initiator: 0001 150000093409 COPYRIGHT 2015 BY EASTMAN CHEMICAL COMPANY 1/20 Safety data Sheet SECTION 1: Identification of the substance/mixture and of the company/undertaking Product identifier Product name: Skydrol LD4 Fire Resistant Hydraulic Fluid Product No.: 34102-00, P3410207, P3410200, P3410206, P3410204, P3410202, P3410205, P3410203, E3410201 Relevant identified uses of the substance or mixture and uses advised against Identified uses: Hydraulic fluid Uses advised against: None known. Details of the supplier of the Safety data Sheet Manufacturer / Supplier Eastman Chemical Company 200 South Wilcox Drive Kingsport, TN 37660-5280 US +14232292000 Visit our website at or email National Supplier Eastman Chemical Fascinatio Boulevard 602-614 2909 Capelle aan den IJssel The Netherlands Telephone: (31) 10 2402 111 Fax: (31) 10 2402 100 Emergency telephone number: For emergency health, Safety , and environmental information: telephone 800-EASTMAN or 423 229-4511 in the United States; or +44 (0)1235 239 670 in Europe.

2 For emergency transportation information, call +44(0)1235 239 670; or 800 964214 in England; 01800559700 in Eire; or 423-229-4511 in the United States. Identify the call as a transportation emergency. SECTION 2: Hazards identification SDSEU / EN / TSDSEU02 Version: Revision Date: Initiator: 0001 150000093409 COPYRIGHT 2015 BY EASTMAN CHEMICAL COMPANY 2/20 Classification of the substance or mixture The product has been classified according to the legislation in force. Regulation No. 1272/2008. Health HazardsSkin Corrosion/Irritation Category 2 H315: Causes skin irritation. Carcinogenicity Category 2 H351: Suspected of causing cancer. Environmental HazardsChronic hazards to the aquatic environment Category 3 H412: Harmful to aquatic life with long lasting effects. Hazard summary Physical Hazards: None known. Health Hazards Inhalation: None known. Eye contact: Eye may become red, tear, and become painful.

3 Skin contact: Irritating to skin. The product contains a small amount of sensitizing substance which may provoke an allergic reaction among sensitive individuals in contact with skin. Ingestion: None known. Other Health Effects: Contains a substance which may be potentially carcinogenic. Environmental hazards: Harmful to aquatic life with long lasting effects. Classification according to Directive 67/548/EEC or 1999/45/EC as amended. Carc. 3: Carcinogen category 3. R40: Limited evidence of a carcinogenic effect. Xi: Irritant R38: Irritating to skin. R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Label Elements SDSEU / EN / TSDSEU02 Version: Revision Date: Initiator: 0001 150000093409 COPYRIGHT 2015 BY EASTMAN CHEMICAL COMPANY 3/20 Signal Words: Warning Hazard Statement(s): H315: Causes skin irritation. H351: Suspected of causing cancer.

4 H412: Harmful to aquatic life with long lasting effects. Precautionary Statement Prevention: P201: Obtain special instructions before use. P273: Avoid release to the environment. P280: Wear protective gloves/protective clothing/eye protection/face protection. Response: P302+P352: IF ON SKIN: Wash with plenty of soap and water. P308+P313: IF exposed or concerned: Get medical advice/attention. Disposal: P501: Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Supplemental label information Contains: 2-Ethylhexyl 7-oxabicyclo[ ]heptane-3-carboxylate. May produce an allergic reaction. Other hazards: None known. SECTION 3: Composition/information on ingredients Mixture General information: Chemical name Concentration Additional identification Notes Tributyl phosphate 55 - 65% CAS-No.

5 : 126-73-8 EC No.: 204-800-2 REACH Registration No.: 01-2119492859-14-0002 01-2119967407-27-0000 Reaction mass of butyl diphenyl phosphate and dibutyl phenyl phosphate and tributyl phosphate 20 - 40% EC No.: 907-672-2 REACH Registration No.: 01-2119967407-27-0000 2-Ethylhexyl 7-oxabicyclo[ ]heptane-3-carboxylate <10% CAS-No.: 62256-00-2 EC No.: 263-471-3 SDSEU / EN / TSDSEU02 Version: Revision Date: Initiator: 0001 150000093409 COPYRIGHT 2015 BY EASTMAN CHEMICAL COMPANY 4/20 butylated hydroxytoluene 1 - 5% CAS-No.: 128-37-0 EC No.: 204-881-4 Explanation f or Notes (if applicable): * All concentrations are percent by w eight unless ingredient is a gas. Gas concentrations are in percent by volume. # This substance has w orkplace exposure limit(s). PBT: persistent, bioaccumulative and toxic substance. vPvB: very persistent and very bioaccumulative substance. Classification Chemical name Classification Notes Tributyl phosphate DSD: Carc.

6 3 R40 Xn, R22 Xi, R38 CLP: Carc. 2, H351; Acute , H302; Skin , H315; Aquatic Chronic3, H412 Reaction mass of butyl diphenyl phosphate and dibutyl phenyl phosphate and tributyl phosphate DSD: Carc. 3 Xn, R40 R52/53 CLP: Carc. 2, H351; Aquatic Chronic3, H412 2-Ethylhexyl 7-oxabicyclo[ ]heptane-3-carboxylate DSD: Xi, R43 CLP: Skin Sens. 1, H317 butylated hydroxytoluene DSD: N, R50/53 CLP: Aquatic Acute 1, H400; Aquatic Chronic1, H410 DSD: Directive 67/548/EEC. CLP: Regulation No. 1272/2008.: The full text for all R-phrases and H-statements is displayed in section 16. SECTION 4: First aid measures General: Get medical attention if symptoms occur. Show this Safety data Sheet to the doctor in attendance. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Place unconscious person on the side in the recovery position and ensure breathing can take place.

7 Ensure that medical personnel are aware of the Material (s) involved and take precautions to protect themselves. Description of first aid measures Inhalation: In case of inhalation of spray mist: Move person into fresh air and keep at rest. For breathing difficulties, oxygen may be necessary. Consult a physician for specific advice. Persons who have inhaled vapours or smoke fumes have to be put under medical observation for at least 48 hours, due to the delayed appearance of poisoning. Eye contact: Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses. Get medical attention if symptoms occur. SDSEU / EN / TSDSEU02 Version: Revision Date: Initiator: 0001 150000093409 COPYRIGHT 2015 BY EASTMAN CHEMICAL COMPANY 5/20 Skin contact: Immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.

8 If skin irritation or an allergic skin reaction develops, get medical attention. Wash contaminated clothing before reuse. Destroy or thoroughly clean contaminated shoes. Ingestion: If swallowed, rinse mouth with water (only if the person is conscious). Call a physician or poison control center immediately. Do not induce vomiting without advice from poison control center. Never give liquid to an unconscious person. Provide fresh air, warmth and rest, preferably in comfortable upright sitting position. Loosen tight clothing such as a collar, tie, belt or waistband. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Most important symptoms and effects, both acute and delayed: Eye may become red, tear, and become painful. The product contains a small amount of sensitizing substance which may provoke an allergic reaction among sensitive individuals.

9 Limited evidence of a carcinogenic effect. Indication of any immediate medical attention and special treatment needed Hazards: No data available. Treatment: Treat symptomatically. SECTION 5: Firefighting measures General Fire Hazards: Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. Keep upwind. In case of fire and/or explosion do not breathe fumes. Extinguishing media Suitable extinguishing media: Water spray, foam, dry powder or carbon dioxide. Unsuitable extinguishing media: Avoid water in straight hose stream; will scatter and spread fire. Special hazards arising from the substance or mixture: May ignite at high temperature. During fire, gases hazardous to health may be formed. Risk of chemical pneumonia after aspiration. Hazardous Combustion Products : carbon dioxide, carbon monoxide , oxides of phosphorus . Advice for firefighters Special fire fighting procedures: In case of fire: Evacuate area.

10 Move container from fire area if it can be done without risk. Use water spray to keep fire-exposed containers cool. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. SDSEU / EN / TSDSEU02 Version: Revision Date: Initiator: 0001 150000093409 COPYRIGHT 2015 BY EASTMAN CHEMICAL COMPANY 6/20 Special protective equipment for fire-fighters: Self-contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures: No action shall be taken involving any personal risk or without suitable training. Keep unauthorized personnel away. Ventilate closed spaces before entering them. Avoid inhalation of vapors and spray mists.