Material Safety Data Sheet ANTIFREEZE Code

1 ReactivityHealth HazardFire Hazard0 Personal ProtectionH12*Section I. Chemical Product and Company IdentificationMaterial Safety data SheetNFPAP rotective ClothingProduct NameSynonymCodeANTIFREEZEU niversal ANTIFREEZE , Radiator ANTIFREEZE , Diesel ANTIFREEZE , Petro-CanadaAntifreeze-Coolant, Petro-Canada Heavy Duty ANTIFREEZE -Coolant, Pre-MixAntifreeze, Petro-Canada Premium Radiator as an engine ANTIFREEZE case ofEmergencyPetro-Canada: 403-296-3000 Canutec Transportation:613-996-6666 Poison Control Centre: Consultlocal telephone directory foremergency number(s). Box 2844 Calgary, AlbertaT2P 3E3 DOT (pictograms)DSLOn the TSCA Uses120 HealthFire HazardReactivitySpecific hazardHMIS ( )Rating0 Insignificant1234 SlightModerateHighExtremeSection II. Composition and Information on IngredientsNameCAS #Exposure Limits (ACGIH)CEILING% (V/V)TLV-TWA(8 h)STEL1) Ethylene glycol107-21-1>55 Not establishedNot established100 mg/m (aerosol)2) Sodium tetraborate pentahydrate1330-43-4<51 mg/m Not establishedNot establishedManufacturerRecommendationNot applicableConsult local, state, provincial or territory authorities for acceptable exposure Exposure LimitsSection III.

2 Hazards can cause slight irritation of skin, eyes and respiratory tract. Extremely dangerous in case of ingestion. For moreinformation, refer to Section HealthEffectsDO NOT induce vomiting because of danger of aspirating liquid into lungs. Seek medical ContactSkin ContactInhalationIngestionIMMEDIATELY flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek medical contaminated clothing - launder before reuse. Wash gently and thoroughly the contaminated skin with running waterand non-abrasive soap. Seek medical the victim to a safe area as soon as possible. If the victim is not breathing, perform artificial respiration. Allow thevictim to rest in a well ventilated area. Seek medical IV. First Aid MeasuresNote to PhysicianNot availableAuto-IgnitionTemperatureProduct s ofCombustionFlash PointsFire FightingMedia andInstructionsFlammable LimitsFire Hazards inPresence ofVarious Substances413 CCarbon oxides (CO, CO2), smoke and irritating vapours as products of incomplete Cup: 116 C (Tagliabue)Open Cup: 116 C (Cleveland)Lower: , Upper: FIRE: Use DRY chemicals, CO2, water spray or FIRE: Use water spray, fog or foam.

3 DO NOT use water in presence of open flames Hazardsin Presence ofVarious SubstancesNot a product presenting risks of be combustible at high V. Fire-fighting MeasuresContinued on Next PageAvailable in FrenchANTIFREEZEPage Number: 2 Section VI. Accidental Release MeasuresMaterial Releaseor SpillSmall spill or leak: Dilute with water and mop up or absorb with an inert DRY Material and place in an appropriate wastedisposal spill or leak: Absorb with an inert Material and put the spilled Material in an appropriate waste disposal. Dispose of inaccordance with regional container dry. Keep container tightly closed. Keep in a cool, well-ventilated contamination with reactive substances. After handling, always wash hands thoroughly with soap and VII. Handling and StorageEngineering ControlsPersonal Protection - The selection of personal protective equipment varies, depending upon conditions of normal application, special ventilation is not necessary.

4 If user's operations generate vapours or mist, use ventilation tokeep exposure to airborne contaminants below the exposure limit. Make-up air should always be supplied to balance airremoved by exhaust ventilation. Ensure that eyewash station and Safety shower are close to appropriate footwear to prevent product from coming in contact with feet and VIII. Exposure Controls/Personal ProtectionEyesBodyRespiratoryHandsFeetWe ar appropriate chemically protective gloves. When handling hot product ensure gloves are heat resistant and concentrations in air may exceed the occupational exposure limits given in Section 2 (and those applicable to yourarea) and where engineering, work practices or other means of exposure reduction are not adequate, NIOSH approvedrespirators may be necessary to prevent overexposure by appropriate clothing to prevent skin contact.

5 As a minimum long sleeves and trousers should be protection ( , Safety glasses, Safety goggles and/or face shield) should be determined based on conditions of use. Ifproduct is used in an application where splashing may occur, the use of Safety goggles and/or a face shield should IX. Physical and Chemical PropertiesPhysical State andAppearanceVolatilityBoiling PointVapour PressureOdour ThresholdDensityVapour DensityOil / Water Dist. viscous (w/w) to (Water = 1) (Air=1). mmHg @ 20 C (68 F).Soluble in water, methanol and diethyl PointPenetrationNot availablePour PointSoftening Point129 to 197 C (264 to 387 F)Ionicity (in water)Dispersion PropertiesNot availableNot availableNot availableStabilityCorrosivityThe product is availableReactive with oxidizing agents, acids X.

6 Stability and ReactivityIncompatibleSubstances /Conditions to AvoidDecompositionProductsMay release COx, smoke and irritating vapours whenheated to not occur under normal working LethalityRoutes of EntryEye contact and : 4700 mg/kg (oral/rat). [Ethylene Glycol]LD50: 9530 mg/kg (dermal/rabbit). [Ethylene Glycol]Section XI. Toxicological InformationChronic or Other Toxic EffectsChronic or Other Toxic EffectsDermal Route:Inhalation Route:Oral Route:Eye Irritation/Inflammation:Immunotoxicity:S kin Sensitization:Respiratory Tract Sensitization:Mutagenic:Not availableNot availableNot availableNot availableSlightly hazardous in case of eye contact (irritant).Extremely dangerous in case of hazardous in case of inhalation (lung irritant). Can cause nausea, headaches and hazardous in case of skin contact (irritant).

7 Continued on Next PageAvailable in FrenchANTIFREEZEPage Number: 3 Other ConsiderationsThe substance may be toxic to kidneys and liver. Repeated or prolonged exposure to the substance can producetarget organs damage. Repeated exposure to a highly toxic Material may produce general deterioration of healthby an accumulation in one or many human Toxicity:Teratogenicity/Embryotoxicity:C arcinogenicity (ACGIH):Carcinogenicity (IARC):Carcinogenicity (NTP):Carcinogenicity (IRIS):Carcinogenicity (OSHA):Not availableNot availableNot availableNot availableACGIH A4: not classifiable as a human and teratogenic in mice at levels below maternal availableSection XII. Ecological InformationEnvironmental FateNot availableBOD5 and CODP roducts ofBiodegradationPersistance/Bioaccumulat ionPotentialAdditional RemarksNot availableNot availableNot availableNo additional XIII.

8 Disposal ConsiderationsWaste DisposalPreferred waste management priorities are: (1) recycle or reprocess; (2) incineration with energy recovery; (3) disposal atlicensed waste disposal facility. Ensure that disposal or reprocessing is in compliance with government requirements andlocal disposal regulations. Consult your local or regional XIV. Transport InformationDOT ClassificationSpecial Provisionsfor TransportNot a DOT controlled Material (United States).Not XV. Regulatory InformationOtherRegulationsDSD/DPD (EEC)This product is acceptable for use under the provisions of WHMIS-CPR. All components of this formulation are listed on theCEPA-DSL (Domestic Substances List).All components of this formulation are listed on the US EPA-TSCA product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and theMSDS contains all of the information required by the contact Product Safety for more (Europe)(Pictograms)Not EVALUATED FOREUROPEAN TRANSPORTNON VALU POUR LETRANSPORT EUROP (Canada)D-2 ATDG (Canada)(Pictograms)ReferencesAvailable upon request.

9 * Marque de commerce de Petro-Canada - TrademarkSection XVI. Other InformationGlossaryACGIH - American Conference of Governmental Industrial HygienistsADR - Agreement on Dangerous goods by Road (Europe)ASTM - American Society for Testing and Materials (BOD5 - Biological Oxygen Demand in 5 daysCAN/CGA Installation CodeCAS - Chemical Abstract ServicesCEPA - Canadian Environmental Protection ActCERCLA - Comprehensive Environmental Response, Compensation andLiability ActCFR - Code of federal RegulationsCHIP - Chemicals Hazard Information and Packaging Approved Supply ListCOD5 - Chemical Oxygen Demand in 5 daysCPR - Controlled Products RegulationsDOT - Department of TransportDSCL - Dangerous Substances Classification and Labeling (Europe)DSD/DPD - Dangerous Substances or Dangerous Preparations Directives(Europe))

10 DSL - Domestic Substance ListEEC/EU - European Economic Community/European UnionEINECS - European Inventory of Existing Commercial Chemical SubstancesEPCRA - Emergency Planning and Community Right to Know ActIRIS - Integrated Risk Information SystemLD50/LC50 - Lethal Dose/Concentration kill 50%LDLo/LCLo - Lowest Published Lethal Dose/ConcentrationNAERG'96 - North American Emergency Response Guide Book (1996)NFPA - National Fire Prevention AssociationNIOSH - National Institute for Occupational Safety & HealthNPRI - National Pollutant Release InventoryNSNR - New Substances Notification Regulations (Canada)NTP - National Toxicology ProgramOSHA - Occupational Safety & Health AdministrationPEL - Permissible Exposure LimitRCRA - Resource Conservation and Recovery ActSARA - Superfund Amendments and Reorganization ActSD - Single DoseSTEL - Short Term Exposure Limit (15 minutes)TDG - Transportation Dangerous Goods (Canada)TDLo/TCLo - Lowest Published Toxic Dose/ConcentrationTLm - Median Tolerance LimitTLV-TWA - Threshold Limit Value-Time Weighted AverageTSCA - Toxic Substances Control ActUSEPA - United States Environmental Protection AgencyContinued on Next PageAvailable in FrenchANTIFREEZEPage Number: 4 Prepared by Product Safety - TAR on 7/3 entry by Product Safety - Canada, telephone: 403-296-4158; fax: 403-296-6551 Ontario & Central Canada, telephone: 1-800-668-0220.