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MATERIAL SAFETY DATA SHEET - belchimusa.com

PRODUCT NAME: IMIDASHOT DF MSDS No. I137004 PAGE 1 of 4 Updated on: 10/01/13 MATERIAL SAFETY data SHEET Section 2: COMPOSITION /INFORMATION ON INGREDIENTS Ingredients CAS No. Content (%w/w) 1. Imidacloprid 138261-41-3 2. Other Ingredients Total Section 3: HEALTH HAZARD INFORMATION CAUTION Keep out of reach of children Harmful if swallowed or absorbed through skin. Avoid contact with eyes, skin or clothing Section 4: FIRST AID MEASURES IF SWALLOWED Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person. IF IN EYES :Hold eye open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. IF ON SKIN OR CLOTHING : Take off contaminated clothing.

PRODUCT NAME: IMIDASHOT DF MSDS No. I137004 PAGE 1 of 4 Updated on: 10/01/13 MATERIAL SAFETY DATA SHEET Section 2: COMPOSITION /INFORMATION ON INGREDIENTS Ingredients CAS No. Content (%w/w)

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Transcription of MATERIAL SAFETY DATA SHEET - belchimusa.com

1 PRODUCT NAME: IMIDASHOT DF MSDS No. I137004 PAGE 1 of 4 Updated on: 10/01/13 MATERIAL SAFETY data SHEET Section 2: COMPOSITION /INFORMATION ON INGREDIENTS Ingredients CAS No. Content (%w/w) 1. Imidacloprid 138261-41-3 2. Other Ingredients Total Section 3: HEALTH HAZARD INFORMATION CAUTION Keep out of reach of children Harmful if swallowed or absorbed through skin. Avoid contact with eyes, skin or clothing Section 4: FIRST AID MEASURES IF SWALLOWED Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person. IF IN EYES :Hold eye open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. IF ON SKIN OR CLOTHING : Take off contaminated clothing.

2 Rinse skin immediately with plenty of water for 15 to 20 minutes. Call a poison control center or doctor for treatment advice. Section 1: CHEMICAL IDENTITY AND USE Trade Name: IMIDASHOT DF Product Name: Imidacloprid 70 % WG Active ingredient: Imidacloprid Chemical Classification: Chloronicotinyl Formula: C9H10 ClN5O2 CAS No.: 138261-41-3 Molecular weight: USE of product: Agrochemical Manufacturer: Sulphur Mills Limited, 604/605, Business Point, 6th floor, Plot No. 349, Western Express Highway, Andheri (E), Mumbai 400 069, INDIA Tel : +91-22-43452222 Fax : +91-22-43452245 PRODUCT NAME: IMIDASHOT DF MSDS No. I137004 PAGE 2 of 4 Updated on: 10/01/13 Section 5: FIRE AND EXPLOSION HAZARD Flash point: Not Applicable Flammable limits: Upper explosive limit (UEL) : Not Applicable Lower explosive limit (LEL) : Not applicable Extinguishing media: Water, carbon dioxide, Dry Chemical, Foam Special fire fighting procedures: Keep out of smoke, cool exposed containers with water spray.

3 Fight fire from upwind position. Use self-contained breathing equipment. Avoid runoff by diking to prevent entry into sewers or waterways. Protective equipment: Wear suitable protective clothing to avoid contact with skin. Wear self-contained respiratory protective device. Section 7: HANDLING AND STORAGE PRECAUTION Store in the closed, original container in a well -ventilated area and as cool as possible. Keep away from heat, sparks, open flame and incompatible materials. Do not store near any MATERIAL intended for use or consumption by human or animals. Section 8: PERSONAL ENGNEERING PROTECTION Engneering control: Eyeswash and washing facilities must be readily available. For decontamination clothes and equipment have soap and water on hand. USER SAFETY RECOMMENDATIONS Users should : Wash hands before eating, drinking, chewing gum, using tobacco, or using the toilet. Remove clothing immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing.

4 Remove PPE immediately after handling this product. Wash the outside of gloves before removing. As soon as possible, wash thoroughly and change into clean clothing. Long sleeved shirt and long pants. Section 6: ACCIDENTAL RELEASE MEASURES Steps to be taken: Stop leak, if safe to do so. Contain spillage. Absorb in sawdust or sand for disposal. Eliminate sources of ignition. Use personal protective equipment. Stay upwind. Cordon off the area. Personal Precautions: Avoid contact with spilled product or contaminated surfaces. Remove all sources of ignition. Use personal protective equipment. Environmental Precautions: Do not allow to get into surface water, drains and ground water. Method of cleaning Waste Disposal: Local regulations should be adhered to. Incineration in controlled furnace. Destroy the empty containers in a safe and authorized place. If burnt avoid inhalation of smoke (if burning permitted). Never re-use empty packs. PRODUCT NAME: IMIDASHOT DF MSDS No.

5 I137004 PAGE 3 of 4 Updated on: 10/01/13 Chemical resistant gloves made of any waterproof MATERIAL such as, barrier laminate, butyl rubber, nitrile rubber, neoprene rubber, natural rubber, polyethylene, polyvinylchloride (PVC) or viton. Shoes plus socks. Section 9: PHYSICAL AND CHEMICAL INFORMATION Appearance: Brown coloured granules Suspensibility: min 70 % w/w Wet sieve test (%retention on 75 m sieve ): Max. % Wettability: Max. 60 second Water solubility : dispersible Oxidizing Properties : Non oxidizing Explosive properties: Non explosive Non flammable Section 10: STABILITY & REACTIVITY data Self ignition : not self heating Hazardous Reactions No hazardous reactions when stored and handled according to prescribed instructions. Stable under recommended storage conditions. Incompatible with other MATERIAL : None known Hazardous reaction product: HCl, HCN, CO. Section 11: TOXICITY INFORMATION Acute toxicity Oral: 500 mg/kg Dermal: >2000 mg/kg Inhalation: mg/L air Eye irritation: Non irritant.

6 Skin irritation: Non irritant. Skin sensitization: Non sensitizer. Mutagenic potential: Non mutagenic. Teratogenecity: Non teratogenic. Carcinogenic potential: Non carcinogenic at normal doses. Section 12: ECOLOGICAL INFORMATION Bees: 24 and 48-hour contact LD50 values were g/bee and g/bee, Birds: Acute oral LD50 for Japanese quail mg/kg For fishes- Danio rerio : 96-hour LC50 value was mg/L For Daphnia: LC50 (48 h) mg/L Algae 72-hour EC50 : mg/L Earthworm 14-day LC50: mg/kg of artificial soil Section 13: WASTE DISPOSAL CONSIDERATIONS Product: In accordance with current regulations and, if necessary, after consultation with the site operator and/or with the responsible authority, the product may be taken to a waste disposal PRODUCT NAME: IMIDASHOT DF MSDS No. I137004 PAGE 4 of 4 Updated on: 10/01/13 site or incineration plant. Contaminated packaging: Not completely emptied packaging should be disposed of as hazardous waste.

7 Waste key for the unused product: agrochemical waste containing dangerous substances Section 14: TRANSPORT INFORMATION Type of chemical: Brown coloured granules State of chemical: Solid UN Number: NA IMDG Page Code: NA Section 15: REGULATORY INFORMATION CUATION Harmful if swallowed or absorbed through skin. Avoid contact with eyes, skin or clothing SAFETY phrases: S2 Keep out of the reach of children. S22 Do not breathe dust S24 Avoid contact with skin S25 Avoid contact with eyes S29 Do not empty into drains S7/9 Keep container tightly closed and in a well-ventilated place S20/21 When using do not eat, drink or smoke S36/37/39 Wear suitable protective clothing, gloves and eye/face protection S56 Dispose of this MATERIAL and its container to hazardous or special waste collection point. Section 16: OTHER INFORMATION --------------- DISCLAIMER Information contained in this MATERIAL SAFETY data SHEET is believed to be reliable but no representation, guarantee or warranties of any kind are made as to its accuracy, suitability for a particular application or results to be obtained from them.

8 It is up to the User/Distributor to ensure that the information contained in the MATERIAL SAFETY data SHEET is relevant to the product manufactured/handled or sold by him as the case may be, Sulphur Mills Ltd. makes no warranties, expressed or implied, in respect of the adequacy of this document for any particular purpose.


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