MATERIAL SAFETY DATA SHEET - Castle Chemicals …

1 MATERIAL SAFETY data SHEETIONOL LC1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANYP roduct name: Ionol LCIntended Use AntioxidantSupplierCastle Chemicals Ltd, Peak House6 Oxford Road, Altrincham, Cheshire WA14 2 DYTel: +44 161 608 8800 Fax: +44 161 608 1910 Email: HAZARD IDENTIFICATIONC lassification of the substance or mixtureClassification according toRegulation (EC) No 1272/2008 Aquatic Chronic 4 H413 May cause long lasting harmful effects to aquatic according toDirective 67/548/EEC orDirective 1999/45/ECR53: May cause long-term adverse effects in the aquatic according toRegulation (EC) No 1272/2008 The substance is classified and labelled according to the CLP pictograms VoidSignal word VoidHazard statementsH413 May cause long lasting harmful effects to aquatic statementsP261 Avoid breathing dust/fume/gas/mist/ Avoid release to the Use personal protective equipment as Keep away from alkaline Keep away from oxidising agents and acidic IF exposed or if you feel unwell.

2 P314 Get medical advice/attention if you feel Collect of 8P401 Store in accordance with local/regional/national/international +P404 Store in a dry place. Store in a closed Dispose of contents/container in accordance with local/regional/national/ international of PBT and vPvB assessmentPBT: Not COMPOSITION INFORMATION ON INGREDIENTSC hemical characterization SubstancesCAS No. Description68610-51-5 Butylated reaction product of p-cresol and dicyclopentadieneIdentification number(s)EINECS Number - 271-867-24. FIRST AID MEASURESG eneral informationPersonal protection for the First remove any clothing soiled by the affected persons out of danger area and lay and transport stably in side respiration with respiration bag or respiratorAfter inhalationTake affected persons into fresh air and keep medical treatment in case of skin contactImmediately wash with water and soap and rinse thoroughly.

3 If skin irritation continues, consult a eye contactRinse opened eye for several minutes under running water. In case of irritation consult an occulist .After swallowingRinse out mouth and then drink plenty of vomiting only, if affected person is fully , possible danger of aspiration, keep breathing passages free Seek medical for doctorIf indication of any immediate medical attention and special treatment needed treat symptomatically5. FIREFIGHTING MEASURESS uitable extinguishing agentsCO2, powder or water spray. Fight larger fire with alcohol resistant hazards arisingfrom the substance or mixture Carbon monoxide and carbon dioxide, not combusted Hydrocarbons.

4 Danger of forming toxic pyrolysis for firefightersProtective equipmentWear fully protective suit. Do not inhale explosion gases or combustion gases. Wear self-contained respiratory protective informationCollect contaminated fire fighting water separately. It must not enter the sewage of 86. ACCIDENTAL RELEASE MEASURESP ersonal precautions,protective equipment andemergency proceduresUse respiratory protective device against the effects of fumes/dust/aerosol. Wear protective equipment. Keep unprotected persons away. Keep away from ignition precautionsDamp down dust with water spray.

5 Do not allow to enter sewers/ surface or ground and MATERIAL forcontainment and cleaning up Pick up mechanically. Dispose contaminated MATERIAL as waste according to item 13. Ensure adequate to other sections See Section 7 for information on safe Section 8 for information on personal protection Section 13 for disposal HANDLING AND STORAGEH andlingPrecautions for safe handling Ensure good ventilation/exhaustion at the and deposition of dust has to be about fire -and explosion protectionKeep ignition sources away - Do not smoke.

6 Protect against electrostatic charges. Dust can combine with air to form an explosive to be met bystorerooms and receptacles Store only in the original about storage inone common storage facility Heating in presence of strong mineral acids will liberate information aboutstorage conditionsStore in cool, dry conditions in well sealed receptacle in a well ventilated area. Protect from humidity and storage temperatureAt 15 C to 25 C8. EXPOSURE CONTROLS/PERSONAL PROTECTIONC ontrol parametersIngredients with limit valuesthat require monitoring at theworkplaceNot informationThe lists valid during the making were used as protective equipment:General protective andhygienic measuresDo not inhale gases / fumes / aerosols / remove all soiled and contaminated clothing.

7 Avoid contact with the eyes and protectionUse suitable respiratory protective device in case of 3 of 8insufficient ventilation. In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective filter devicefor short term useFilter FFP2 Protection of handsProtective glovesMaterial of glovesNitrile rubber, NBRR ecommended MATERIAL strength: mmPenetration time ofglove materialPenetration time 8 hThe exact break trough time has to be found out by the manufacturer of the protective gloves and has to be suitable are glovesmade of the following materials Leather gloves, Strong MATERIAL glovesEye protectionSafety glasses9.

8 PHYSICAL AND CHEMICAL PROPERTIESA ppearanceFormFlakes, PowderColourLight beigeOdourOdourlesspH-value (111 g/l) at 20 C~ 7 - 8 Change in conditionMelting point/Melting range ~ 105-120 CBoiling point/Boiling CFlash CIgnition temperature380 C (BAM Germany)Decomposition temperature 300 C (T-onset, DSC)Vapour pressure at 20 C< mm Hg (US-EPA-HPV-Report)Density at 20 C~ g/cm Bulk density at 20 C~ 300-400 kg/m Solubility in / Miscibility withwater at 20 C g/lOther informationVOC European Union %0 %VOC Swiss 0 % VOCV STABILITY AND REACTIVITYC hemical stabilityThermal decomposition /conditions to be avoidedNo decomposition if used according to of hazardousreactionsRisk of dust explosion.

9 Reacts with strong acids, alkalines and oxidizing decompositionproductsCarbon monoxide and carbon dioxide, HydrocarbonsDanger of forming toxic pyrolysis of 811. TOXICOLOGICAL INFORMATIONA cute toxicity:LD/LC50 values relevant for classification:68610-51-5 Butylated reaction product of p-cresol and dicyclopentadieneOral LD50 > 5000 mg/kg (Rat ( Ratte ))IUCLID, US-EPA HPV-ReportDermal LD50 > 5000 mg/kg (Rabbit (Kaninchen))IUCLID, US-EPA HPV-ReportInhalative LC50/1,0h > 163 mg/ltr. (Rat ( Ratte ))External MSDSP rimary irritant effect:on the skinNo irritant the eyeNo irritating effect.

10 Mechanical irritation possibleSensitizationSensitising of people disposed to that may toxicityInhalation of the dusts should be avoided as even inert dusts may impair respiratory organ to chronic toxicity:68610-51-5 Butylated reaction product of p-cresol and dicyclopentadieneOral ED05 740 mg/kg/day (Rat ( Ratte ))BMD (Benchmark Dose) - substance shows a slight increase in the incidence of common fetal skeletal 25 mg/kg/day (Rat ( Ratte ))USA HPV-Program - Repeated Dose Toxicity - Subchronic 90-Day feeding study - Increased liver wt and increased adrenal wt (females only) at 1500 ppm mg/kg/day (Rat (Ratte))USA HPV-Program - Maternal ToxAdditional toxicologicalinformationNot a teratogenic HPV-Program12.