Material Safety Data Sheet - Homestead

1 - Continued -PM200-LatexMaterial Safety data SheetDocument Code: PM200-Latex Date of PreparationVersion: 01aOctober 15, 2001 Section 1 - product and Company IdentificationPRODUCT NAME & NUMBERS HMIS CODESPROMAR 200 Interior Latex FlatHealth 2*Pure White (B30W201) (Navajo White) B30W205 Flammability 0 Midtone Base (B30W202) Dover White B30W206 Reactivity 0 Deeptone Base B30W203 Luminous White B30W207 Antique White B30W204 Extra White B30W251 PROMAR 200 Interior Latex Eg-ShelPure White (B20W201) Navajo White B20W205 Midtone Base (B20W202) Dover White B20W206 Deeptone Base B20W203 Luminous White B20W207 Antique White B20W204 Extra White B20W251 PROMAR 200 Interior Latex Semi-GlossPure White (B31W201) Navajo White B31W205 Midtone Base (B31W202) Dover White B31W206 Deeptone Base B31W203 Luminous White B31W207 Antique White B31W204 Extra White B31W251 PROMAR 200 Interior Latex GlossPure White (B21W201) Luminous White B21W207 Midtone Base (B21W202) Extra White B21W251 Deeptone Base B21W203 MANUFACTURER'S NAME EMERGENCY TELEPHONE SHERWIN-WILLIAMS COMPANY (216)

2 566-2917101 Prospect Avenue INFORMATION TELEPHONE , OH 44115 (216) 566-2902 Section 2 Composition/Information on IngredientsCAS Number Ingredient Name CAS Number Ingredient Name------------------------------------ ---------------------------------------- Listed products may contain the following ingredients based upon obtain individual product MSDS or environmental data , call (216) Colors64742-54-7 Heavy Paraffinic Oil14808-60-7 Quartz14464-46-1 Cristobalite1332-58-7 Kaolin13463-67-7 Titanium Dioxide107-21-1 Ethylene Glycol14807-96-6 Talc1333-86-4 Carbon BlackEg-Shel Colors112-34-5 2-(2-Butoxyethoxy)-ethanol107-21-1 Ethylene Glycol14464-46-1 Cristobalite1332-58-7 Kaolin471-34-1 Calcium Carbonate13463-67-7 Titanium Dioxide14807-96-6 Talc1333-86-4 Carbon BlackPage2of6- Continued -PM200-LatexSection 2 Composition/Information on Ingredients (continued)CAS Number Ingredient Name CAS Number Ingredient Name------------------------------------ ---------------------------------------- Semi-Gloss Colors112-34-5 2-(2-Butoxyethoxy)-ethanol107-21-1 Ethylene Glycol14464-46-1 Cristobalite471-34-1 Calcium Titanium Dioxide1332-58-7 Kaolin14807-96-6 Talc1333-86-4 Carbon BlackGloss Colors64742-54-7 Heavy Paraffinic Oil112-34-5 2-(2-Butoxyethoxy)

3 -ethanol107-21-1 Ethylene Glycol14464-46-1 Cristobalite13463-67-7 Titanium Dioxide1332-58-7 Kaolin14807-96-6 Talc1333-86-4 Carbon Black% WT. CAS No. Ingredient Name------------------------------------ ---------------------------------------- max 1 64742-54-7 Heavy Paraffinic TLV 5 mg/m3 as MistOSHA PEL 5 mg/m3 as Mistmax 3 112-34-5 2-(2-Butoxyethoxy)-ethanolACGIH TLV Not Established mmOSHA PEL Not Establishedmax 6 107-21-1 Ethylene TLV 50 ppm CEILING mmOSHA PEL 50 ppm CEILINGmax 17 14808-60-7 QuartzACGIH TLV mg/m3 as Respirable DustOSHA PEL mg/m3 as Respirable Dustmax 3 14464-46-1 CristobaliteACGIH TLV mg/m3 as Respirable DustOSHA PEL mg/m3 as Respirable Dustmax 6 1332-58-7 KaolinACGIH TLV 2 mg/m3 as Respirable DustOSHA PEL 10 mg/m3 Total DustOSHA PEL 5 mg/m3 Respirable Fractionmax 19 471-34-1 Calcium TLV 10 mg/m3 as DustOSHA PEL 15 mg/m3 Total DustOSHA PEL 5 mg/m3 Respirable Fractionmax 28 13463-67-7

4 Titanium TLV 10 mg/m3 as DustOSHA PEL 10 mg/m3 Total DustOSHA PEL 5 mg/m3 Respirable Fraction<3% due 14807-96-6 Talcto tintingACGIH TLV 2 mg/m3 as Respirable DustOSHA PEL 2 mg/m3 as Respirable Dust<1% due 1333-86-4 Carbon tintingACGIH TLV mg/m3 OSHA PEL mg/m3 Page3of6- Continued - PM200-LatexSection 3 Hazards IdentificationROUTES OF EXPOSUREE xposure may be by INHALATION and/or SKIN or EYE contact, depending onconditions of use. To minimize exposure, follow recommendations for proper use,ventilation, and personal protective OF OVEREXPOSUREI rritation of eyes, skin and upper respiratory system. In a confined areavapors in high concentration may cause headache, nausea or AND SYMPTOMS OF OVEREXPOSURER edness and itching or burning sensation may indicate eye or excessive CONDITIONS AGGRAVATED BY EXPOSURENone generally INFORMATIONFOR COMPLETE DISCUSSION OF TOXICOLOGY data REFER TO SECTION 4 First Aid MeasuresIf INHALED: If affected, remove from exposure.

5 Restore warm and on SKIN: Wash affected area thoroughly with soap and contaminated clothing and launder before in EYES: Flush eyes with large amounts of water for 15 medical SWALLOWED: Do not induce vomiting. Get medical attention 5 Fire Fighting MeasuresFLASH POINT LEL UELNone CLASSIFICATIONNot ApplicableEXTINGUISHING MEDIAC arbon Dioxide, Dry Chemical, Alcohol FoamUNUSUAL FIRE AND EXPLOSION HAZARDSC losed containers may explode (due to the build-up of pressure) when exposed toextreme FIRE FIGHTING PROCEDURESFull protective equipment including self-contained breathing apparatus shouldbe used. Water spray may be ineffective. If water is used, fog nozzles arepreferable.

6 Water may be used to cool closed containers to prevent pressurebuild-up and possible autoignition or explosion when exposed to extreme 6 Accidental Release MeasuresSTEPS TO BE TAKEN IN CASE Material IS RELEASED OR SPILLEDR emove all sources of ignition. Ventilate and remove with inert 7 Handling and StorageDOL STORAGE CATEGORYNot ApplicablePRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGEKeep container closed when not in use. Transfer only to approvedcontainers with complete and appropriate labeling. Do not take out of the reach of Continued - PM200-LatexSection 8 Exposure Controls/Personal ProtectionPRECAUTIONS TO BE TAKEN IN USEUse only with adequate ventilation. Avoid breathing vapor and spray contact with skin and eyes.

7 Wash hands after coatings may contain materials classified as nuisance particulates(listed "as Dust" in Section 2) which may be present at hazardous levels onlyduring sanding or abrading of the dried film. If no specific dusts are listed inSection 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (totaldust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3(respirable fraction).Removing or disturbing old paint from interior or exterior surfaces by sanding,scraping, abrading or other means may produce dust, debris or fumes that containlead. Exposure to lead dust, debris or fumes may cause brain damage or otheradverse health effects, especially in children and pregnant women. Structuresbuilt before 1978 should be tested by a licensed inspector prior to removing ordisturbing old paint.

8 For more information, call the National Lead InformationCenter at 1-800-424-LEAD (in US) or contact your local health exhaust preferable. General exhaust acceptable if the exposure tomaterials in Section 2 is maintained below applicable exposure limits. Refer toOSHA Standards , , PROTECTIONIf personal exposure cannot be controlled below applicable limits byventilation, wear a properly fitted organic vapor/particulate respirator approvedby NIOSH/MSHA for protection against materials in Section sanding or abrading the dried film, wear a dust/mist respirator approvedby NIOSH/MSHA for dust which may be generated from this product , underlying paint,or the GLOVES & EYE PROTECTIONWear gloves recommended by glove supplier for protection against materials inSection 2.

9 Wear Safety spectacles with unperforated 9 Physical and Chemical PropertiesPRODUCT WEIGHT lb/gal EVAPORATION RATE Slower than EtherSPECIFIC GRAVITY VAPOR DENSITY Heavier than AirBOILING POINT 212-477 F MELTING POINT VOLUME 56-70 % SOLUBILITY IN WATER ORGANIC COMPOUNDS (VOC Theoretical) lb/gal Less Federally Exempt lb/gal Emitted VOCS ection 10 Stability and ReactivitySTABILITYS tableCONDITIONS TO AVOIDNone DECOMPOSITION PRODUCTSBy fire: Carbon Dioxide, Carbon MonoxideHAZARDOUS POLYMERIZATIONWill not occurPage5of6- Continued - PM200-LatexSection 11 Toxicological InformationCHRONIC HEALTH HAZARDSC rystalline Silica (Quartz, Cristobalite) is listed by IARC and NTP.

10 Long termexposure to high levels of silica dust, which can occur only when sanding orabrading the dry film, may cause lung damage (silicosis) and possibly Black is classified by IARC as possibly carcinogenic to humans (group2B) based on experimental animal data , however, there is insufficient evidence inhumans for its Glycol is considered an animal teratogen. It has been shown to causebirth defects in rats and mice at high doses when given in drinking water or bygavage. There is no evidence to indicate it causes birth defects in overexposure to solvent ingredients in Section 2 may cause adverseeffects to the liver and urinary exposed to titanium dioxide dust at 250 developed lung cancer,however, such exposure levels are not attainable in the DATACAS No.