MATERIAL SAFETY DATA SHEET (MSDS) - …

1 MATERIAL SAFETY data SHEET ( msds )TROY INTERNATIONALM ergal 186 8 Vreeland Road FOR msds INFORMATION: 1-973-589-2500 (USA)Product Code:30204X Florham Park, NJ 07932 24 HOUR EMERGENCY PHONE NUMBERE ffective Date:June 16, 2004 USA CHEMTREC 1-703-527-3887 (USA)Replaces:October 29, & COMPANY IDENTIFICATION PRODUCT NAMEM ergal 186 MANUFACTURERTroy Chemical ON INGREDIENTS(The listed components are considered to be hazardous)CHEMICAL NAMECAS#%AGENCYEXPOSURE LIMITS4,4 dimethyloxazolidine51200-87-468 Not applicableNone IDENTIFICATIONEMERGENCY OVERVIEWM ergal 186 is a clear amber liquid with an amine odor. Highly alkaline, pH=11. Combustible liquid. May cause severe eye irritation withirreversible corneal damage as well as respiratory irritation. Excessive heat will result in decomposition to ammonia and, at temperatures inexcess of 140 C (284 F), to formaldehyde.

2 Avoid contact with brass, copper, or aluminum. This MATERIAL is toxic to OF ENTRYI ngestion, skin contact, eyes, inhalationINGESTIONI ngestion may cause gastrointestinal irritation, nausea, and cause moderate skin CONTACTMay cause severe eye irritation and irreversible corneal damage if not washed from eyes cause respiratory EFFECTST here are no known chronic ORGANSNone knownCARCINOGENICITYThis product (or component) is not listed as a carcinogen according to OSHA, NTP, IARC, and CONDITIONS AGGRAVATED BY EXPOSURET here are no known conditions aggravated by exposure to this AID MEASURESINGESTIONCall poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Donot induce vomiting unless told to do so by the poison control center or doctor. Do not give anything by mouth to anunconscious CONTACTTake off contaminated clothing.

3 Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control centeror doctor for treatment CONTACT Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5minutes, then continue rinsing eye. Call a poison control center or doctor for treatment person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferablymouth-to-mouth, if possible. Call a poison control center or doctor for further treatment TO PHYSICIAN4,4 dimethyloxazolidine is highly alkaline, pH=11. Probable mucosal damage may contraindicate use of gastric against circulatory shock, respiratory depression, and convulsion may be the product container or label with you when calling a poison control center or doctor, or going for FIGHTING MEASURESFLASH POINT52 C (125 F)(ASTM D3278-96 Setaflash Closed-Cup)FLAMMABLE LIMITSNot determinedAUTOIGNITION TEMPERATURENot determinedFLAMMABILITY CLASSC ombustible liquid - Class IIHAZARDOUS PRODUCTS Carbon monoxide, carbon dioxide, ammonia and formaldehyde.

4 OF COMBUSTIONFIRE EXTINGUISHING MEDIADry chemical, carbon dioxide, water spray, or alcohol-resistant FIGHTING INSTRUCTIONSMove container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposedto flames until well after fire is out. Avoid breathing vapors, keep upwind. Positive pressure self-contained breathingapparatus with full facepiece and structural firefighters' protective clothing will provide limited FIRE & EXPLOSIONS olvent vapors are heavier than air and may travel along the ground or be moved by ventilation and ignited by HAZARDS flames and ignition sources. Contact may cause burns to skin and eyes. Runoff to sewer may create fire orexplosion hazard. Runoff from fire control or dilution water may cause pollution. Never use welding or cuttingtorch on or near drum (even empty) because product (even residue) can ignite explosively.

5 Excessive heat inexcess of 140 C (284 F) will result in decomposition to ammonia and RELEASE MEASURESKeep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Positive pressure self-contained breathingapparatus and structural firefighters' protective clothing will provide limited protection. Shut off ignition sources; no flares, smoking, or flames inhazard area. Do not touch or walk through spilled MATERIAL . Stop leak if you can do it without risk. For small spills, absorb with vermiculite or othernoncombustible absorbent MATERIAL and place into containers for later disposal. For large spills, dike far ahead of liquid spill for later disposal. Ifwater pollution occurs, notify the appropriate all Federal, State, and Local regulations regarding notifications of accidental 1 of 2 MATERIAL SAFETY data SHEET ( msds )TROY INTERNATIONALM ergal 186 8 Vreeland Road FOR msds INFORMATION: 1-973-589-2500 (USA)Product Code:30204X Florham Park, NJ 07932 24 HOUR EMERGENCY PHONE NUMBERE ffective Date:June 16, 2004 USA CHEMTREC 1-703-527-3887 (USA)Replaces:October 29, & STORAGEA void contact with skin, eyes, or clothing.

6 Avoid breathing vapor or mist. Wash thoroughly after handling. Keep container tightly closed. Useonly with adequate ventilation. "Empty" containers retain product residue (liquid and/or vapor) and can be dangerous. DO NOTPRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATICELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Empty drums should becompletely drained, properly bunged and promptly returned to a drum reconditioner, or properly disposed of. Store away from incompatiblesubstances in a cool, dry, ventilated area. Do not store at freezing temperatures or above 60 C (140 F) for extended periods. Avoid contactwith brass, copper, or aluminum. Store in accordance with Substances with low electroconductivity, which may be ignited byelectrostatic sparks, should be stored in containers which meet the bonding and grounding guidelines in NFPA77, Recommended Practiceon Static Electricity.

7 Do not contaminate water, food, or feed by storage or drums are non-conductive and, appropriate SAFETY measures must be taken to prevent possible ignition when filling or dispensingflammable or combustible all Federal, State, and Local regulations when storing or disposing of this PROTECTION/EXPOSURE CONTROLSVENTILATIONP rovide local exhaust or process enclosure ventilation to minimize PROTECTIONIf potential for contact with liquid exists, use splash-proof SAFETY goggles and a PROTECTIONWear impervious gloves and apron to prevent skin contact. Wear impermeable suit if exposure is possible to alarge portion of the PROTECTIONIf exposure may exceed recommended limits, an approved respirator should be used based on exposure levelsfound in the and SAFETY shower should be available within the immediate work area for emergency AND CHEMICAL PROPERTIESAPPEARANCEC lear, pale amber liquidSPECIFIC GRAVITY AT 25 C.

8 (Water=1) odorWATER SOLUBILITY100%INITIAL BOILING POINT101 C (214 F) - PRESSURE AT 20 mm HgEVAPORATION RATE (Butyl acetate=1)>1 VAPOR DENSITY (Air=1)>1% VOLATILES BY WEIGHT100%VISCOSITY (Gardner) AT 25 (g/l) & REACTIVITYREACTIVITYS table under normal temperatures and pressures. CONDITIONS TO AVOIDA void heat or sources of contact with strong acids, bases, and DECOMPOSITIOND ecomposition may release carbon monoxide, carbon dioxide, ammonia, and POLYMERIZATIONH azardous polymerization does not INFORMATIONLD50 (oral, rat-male) - 1009 mg/kg., LD50 (oral, rat-female) - 974 mg/kg., LC50 (rat,4 hr) - mg/kg. LD50 (dermal, rabbit) >2000 mg/kg; Moderateirritant (dermal, rabbit). Severe eye irritation and corrosive (rabbit). Corneal damage may be irreversible if not washed from eyes INFORMATIONThis product is toxic to fish and may cause adverse environmental impact. INFORMATIOND isposal procedures must be in accordance with local INFORMATIONIATASHIPPING NAMEUN2920, Corrosive liquid, flammable (contains: dimethyloxazolidine), 8, PG II, EMS# 8 FLABELS REQUIREDC orrosive, Flammable liquidIMDGSHIPPING NAMEUN2920, Corrosive liquid, flammable (contains: dimethyloxazolidine), 8, PG II, EMS# F-E, S-CLABELS REQUIREDC orrosive, Flammable INFORMATIONCHEMICAL INVENTORIESThe ingredients of this product are all on the following Chemical Substance Inventories, are exempt from the Inventories, or are otherwise compliant with inventoryrequirements of the governing , by:Environmental and Regulatory Affairs msds has been revised in the following sections.

9 (revisions indicated in left border)Replaces Troysan 186-IIThe information contained in this msds is believed to be accurate and reliable as of issue date, but no representation, guarantee, or warranty, express orimplied is made to the accuracy, reliability, or completeness of the information. It is provided for the purpose of complying with hazard communicationregulations. It is not intended as performance information or specifications for the product. It is the user's responsibility to determine the suitability of theproduct for his own use. Troy does not assume legal responsibility for reliance on information herein. This msds is not intended for use in North Americaor Europe. LAST PAGEPage 2 of 2