MATERIAL SAFETY DATA SHEET OLEUM - …

1 MATERIAL SAFETY data SHEETCI O001 Page 1 of 4 OLEUM1. :Substance Company Address Emergency Telephone Number : : :Fuming Sulphuric Acid CHEMICAL INITIATIVES (Pty) Limited, Private BagX137, Bryanston, Gauteng, 2025(011) 608-3300 or Toll free 0800-11444552. Composition and Ingredients :COMPONENTS ulphuric AcidFree Sulphur Trioxide ::CONCENTRATION103 - 106%20 to 40% 3. Hazards :May cause corrosion to skin, eyes and respiratory of fumes at high concentration may be react with organic compounds to cause and First Aid : Immediate TreatmentInhalation Skin Contact Eye Contact Ingestion Further Professional Medical Assistance : : : : : Remove patient from exposure, keep warm and atrest.

2 Obtain immediate medical contaminated clothing. Wash skin withwater. Obtain immediate medical irrigate with clean water, holding eyelidsapart, for at least 20 minutes. Obtain immediatemedical out mouth with water and give 200-300ml (halfa pint) of water to drink. Do not inducevomiting. Obtain immediate medical attention. Symptomatic treatment and supportive therapy severe exposure, the patient should bekept under medical review for at least 24 hours asdelayed lung oedema may Fire :FLASH POINT: - AUTOIGNITION TEMP: LEL: UEL: May cause reaction that could cause and assist and for Extinguishing MediaCombustion Products :: CO2, Dry powder and water fumes of the oxides of SAFETY data SHEETCI O001 Page 2 of 4 OLEUM 6.

3 Accidental Release :Personal Protection Environmental PrecautionMethods for claning up: ::As a minimum, use chemical -resistant gloves,eye/face and breathing evacuation may be spillages by damming or construction ofbarriers. Neutralise with alkali (eg. soda ash). Ifpossible absorb with earth or non-organic absorbentmaterial then shovel or pump into dry well-labelledcontainers for disposal or recovery. Wash spillagearea with large amounts of Handling and Storage :Handling Storage: :Avoid contact with skin and eyes. Do not breathfumes. Provide adequate in stainless steel or glass, in well ventilatedarea, away from sunlight and moisture. Keep awayfrom strong bases and organic Exposure and Personal Protection :TLV-TWA: 1mg/m3 (as sulphuric acid) TLV-STEL : 3mg/m3 (as sulphuric acid) (ACGIH 92 to 93)As a minimum use chemical-resistant gloves, apron, eye protection and breathing Physical and Chemical Properties :AppearanceOdourBoiling PointFreezing PointDensity (g/ml)Solubility (water)::::::Colourless to cloudy viscous fumes100 to 140 C-9 to 30 C1,8 at 20 C0,001 at 20 C10.

4 Stability and Reactivity :Hazardous reaction Decomposition/combustion products: :May react violently if in contact with strong bases,water, organic compounds and base oxides of sulphur and hydrogen when in reactionwith SAFETY data SHEETCI O001 Page 3 of 4 OLEUM11. Toxicology :Inhalation Skin ContactEye contact Ingestion Long Term Exposure: :: : :May cause corrosion, pain, vomiting, burns to themouth and throat and perforation of the of the fumes may cause build up onthe lung (pulmonary oedema) up to 24 hours afterexposure, which could prove cause severe and third degree cause corrosion and permanent damage if eyeis not immediately except those secondary to tissue contact may cause redness,cracking and dermatitis of the Ecology :Users should ensure that they comply with local, provincial and national environmental fate and mobility.

5 May be very dangerous if allowed to enter drinking water , degradation, bio-accumulation: Fish toxcity critical conc. = 10mg/l (7,34mg/l/48 hrs-Lymnaea Palustris 0-100% mortality). on treatment : Harmful to aquatic life in low Disposal :Disposal should be in accordance with relevant not dispose of waste into the sewer Transport :Hazchem CodeUN ClassPacking GroupProper Shipping Name:::::4WE18318 ( )ISulphuric Acid (fuming)15. Regulations :Users should ensure that they comply with relevant Substances Directive 67/548/ECCCR14R35R37S26 S30::::: :CorrosiveReacts violently with waterCauses severe burnsIrritating to respiratory case of contact with eyes, rinse immediately withplenty of water and seek medical add water to this SAFETY data SHEETCI O001 Page 4 of 4 OLEUM16.

6 Other :DISCLAIMER:Chemical Initiatives (PTY) Ltd provides the information contained herein in good faith but makes norepresentation as to its comprehensiveness or accuracy. This document is intended only as a guide tothe appropriate precautionary handling of the MATERIAL by a proper-trained person using this receiving the information must exercise their independent judgement in determining itsappropriateness for a particular purpose. Chemical Initiatives (PTY) Ltd makes no representations orwarranties, either express or implied, including without limitation any warranties ofmerchantability, for a particular purpose with respect of the information set forth hereinor the product to which the information refers.

7 Accordingly, Chemical Initiatives (PTY) Ltd willnot be responsible for damages resulting from use of or reliance upon this by:Technical Department, Chemical Initiatives (PTY) Ltd, Private Bag X137, Bryanston 2025, RSA