Transcription of MATERIAL SAFETY DATA SHEET Page: 1 SIFCO Process …
1 Date Created: 1 Page: SIFCO Process Solution cadmium LHEMATERIAL SAFETY data SHEET30006/30/200412/06/201112/21/2010 Revision:Supercedes Revision:12/06/2011 Printed:X*300 InstabilitySpecial HazardHealthFlammabilityHEALTHFLAMMABILI TYPPEPHYSICAL1. Product and Company Identification5070 Product Code: SIFCO Process Solution cadmium LHEP roduct Name:Manufacturer InformationSIFCO Applied Surface Concepts Company Name:Division of SIFCO Industries, E. Schaaf RoadIndependence, OH 44131(216)524-0099 Phone Number:(216)524-6331 Fax Number:CHEMTREC (United States) (800)424-9300 Emergency Contact:CHEMTREC ( International-Collect) +1 (703)527-3887 Information: Web site Email address:2. Hazards IdentificationEmergency OverviewLight yellow liquid with no characteristic ! Toxic. Harmful by inhalation, in contact with skin and if swallowed. Causes burns. May causesensitisation by inhalation and skin contact.
2 May cause cancer. Toxic to aquatic organisms, may cause long-termadverse effects in the aquatic environment. Severe Marine Pollutant. Emergency ResponseGuidebook #154 Inhalation? Yes Skin? Yes Eyes? Yes Ingestion? YesRoute(s) of Entry:Potential Health Effects (Acute and Chronic)EYE: Causes eye irritation, burns CONTACT: Causes skin irritation, may cause burns and possible allergic : May cause sneezing, nasal discharge, coughing, headaches, dizziness, nausea, fatigue ordifficulty in breathing. May cause sensitization of respiratory : Irritating to mouth, throat, and stomach. May cause liver damage with jaundice, kidney andgastrointestinal EFFECTS: Prolonged or repeated exposure may cause damage to skin, eyes, respiratory system andteeth. May cause severe and delayed health effects such as inflammation of the lungs and chemical increase possibility of prostate and Symptoms Of ExposureDependant on route(s) of entry.
3 See section above for Conditions Generally Aggravated By ExposurePreexisting skin and eye conditions; respiratory system disorders; preexisting sensitization to to SIFCO Applied Surface ConceptsANSI :12/06/2011 Printed: 2 Page: SIFCO Process Solution cadmium LHEMATERIAL SAFETY data SHEET12/21/2010 Supercedes Revision:3. Composition/Information on Components (Chemical Name)Borate(1-), tetrafluoro-, cadmium (2:1)14486-19-2 CAS # %ConcentrationFormulaRTECS # % % First Aid MeasuresEmergency and First Aid ProceduresFirst aid providers must take proper precautions for their own SAFETY before entering contaminated areas to assistchemical accident victims and handling their contaminated clothing and equipment. Another person shouldimmediately call the Emergency Medical Service, 911-Operator, Hospital, Physician, Ophthalmologist or PoisonControl Center, as applicable. Give the following information: Location of the accident, your phone number,description of the accident, name of chemical agent and product, number and condition of casualties, what isbeing done for the victims.
4 Stay on the phone until the other party hangs up! Remove victim from contaminatedarea to a clean, quiet, ventilated area. Calm and reassure him, keep him : Hold eyelids apart and flush eyes with plenty of water for at least 15 : Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothingand shoes. Thoroughly decontaminate (or discard) clothing and : Remove to fresh air. Lay victim down, legs raised. Loosen tight clothing, cover with a not breathing, give artificial : DO NOT induce vomiting, unless advised by EMS. Give large quantities of water to drink. Nevergive anything by mouth to an unconscious Fire Fighting MeasuresMaterial Will Not BurnFlammability Classification:NAFlash Pt:LEL: None UEL: NoneExplosive Limits:NAAutoignition Pt:Fire Fighting InstructionsUse NIOSH/MSHA approved positive-pressure self-contained breathing apparatus. Structural fire fighters'protective clothing may not provide adequate Properties and HazardsSpecific Hazards: Toxic gases/vapors/fumes of Carbon monoxide (CO).
5 Carbon dioxide (CO2).Containers can build up pressure and burst if exposed to heat (fire). Water runoff can cause environmentaldamage. Dike area for later Combustion ProductsSuitable Extinguishing MediaAllUnsuitable Extinguishing Media6. Accidental Release MeasuresSteps To Be Taken In Case MATERIAL Is Released Or SpilledDo not touch or walk through spilled MATERIAL . Isolate hazard area and keep people away. Notify your facilityemergency coordinator. Eliminate all sources of ignition. Provide maximum ventilation. Do not release into soil,sewers, or natural bodies of water. Wear proper personal protective equipment (PPE). Carefully mop up orvacuum spill and triple rinse with water into suitable plastic container. Release of a reportable quantity (RQ)requires notification of proper authorities. Dispose of according to local, state, and federal to SIFCO Applied Surface ConceptsANSI :12/06/2011 Printed: 3 Page: SIFCO Process Solution cadmium LHEMATERIAL SAFETY data SHEET12/21/2010 Supercedes Revision:7.
6 Handling and StoragePrecautions To Be Taken in HandlingUSAGE PRECAUTIONSA void spilling, skin and eye contact. Avoid breathing vapours. Use with adequate exhaust ventilation. Useapproved respirator if air contamination is above accepted level. Thoroughly wash hands. Triple rinse containerclean before discarding. Put nothing else in this To Be Taken in StoringKeep container tightly closed in upright position. Store at 60-90 F away from incompatible materials andphysical hazards. Do not remove or deface container Exposure Controls/Personal mg/m3 Hazardous Components (Chemical Name)ACGIH TLVB orate(1-), tetrafluoro-, cadmium (2:1)14486-19-2 CAS #OSHA PELO ther Limits ppm10 PPM25 mg/m3 Ethylenediamine107-15-3 Equipment (Specify Type)If engineering controls are not feasible, the respiratory protection program must comply with OSHA 29 ProtectionFace shield and SAFETY glasses w/side shields or splash-proof chemical goggles.
7 Do not wear contact lenses. Eyewash station, SAFETY shower, washing facilities near work GlovesNitrile, neoprene, vinyl, latex gloves. Impervious boots, apron, protective clothing as required by job Protective ClothingEngineering Controls (Ventilation etc.)Local exhaust ventilation is required to meet the permissible exposure limits (PEL) during the use of this PracticesDO NOT SMOKE IN WORK AREA! Wash at the end of each work shift and before eating, smoking and usingthe toilet. Promptly remove any clothing that becomes contaminated. Wash promptly with soap & water if skinbecomes contaminated. Use appropriate skin cream to prevent drying of skin. When using do not eat, drink Physical and Chemical Properties[ ] Gas [ X ] Liquid [ ] SolidPhysical States:<= F ( C)Freezing Point:>= F ( C)Boiling Point:NAAutoignition Pt:NAFlash Pt:LEL: None UEL: NoneExplosive - Gravity (Water = 1):Vapor Pressure (vs.)
8 Air or mm Hg):Vapor Density (vs. Air = 1):< 1 Evaporation Rate (vs ButylAcetate=1):CompleteSolubility in Volatile:Licensed to SIFCO Applied Surface ConceptsANSI :12/06/2011 Printed: 4 Page: SIFCO Process Solution cadmium LHEMATERIAL SAFETY data SHEET12/21/2010 Supercedes - :Appearance and OdorLight yellow liquid with no characteristic Stability and ReactivityUnstable [ ] Stable [ X ]Stability:Conditions To Avoid - InstabilityStable under normal ambient - Materials To AvoidStrong acids, Decomposition Or ByproductsNitrous Oxides, Carbon Oxides, Diatomic Flourine, CadmiumWill occur [ ] Will not occur [ X ]Possibility of Hazardous Reactions:Conditions To Avoid - Hazardous ReactionsAvoid contact with acids and oxidising Toxicological InformationNot AvailableChronic Toxicological EffectsCarcinogenicity/Other InformationACGIH Known Human Carcinogen (Class A)A21 YesHazardous Components (Chemical Name)Borate(1-), tetrafluoro-, cadmium (2.
9 1)14486-19-2 CAS #KnownNTPIARCACGIHOSHA Yes IARC Monographs? Yes OSHA Regulated? YesCarcinogenicity:12. Ecological InformationNot Available13. Disposal ConsiderationsWaste Disposal MethodShip to approved treatment/disposal facility. Dispose of according to local, state, and federal the applicable regulations for disposal of empty containers and rinsate. The disposal information appliesto the MATERIAL as manufactured. Contamination may affect the disposal requirements. The responsibility forproper waste disposal is with the generator of the Waste ID Code:Additional Disposal InformationD00214. Transport InformationLAND TRANSPORT (US DOT)UN2922, Corrosive Liquid, Toxic, ( cadmium Fluoroborate, Ethylenediamine) 8, , PG II - ERG 154 DOT Proper Shipping Name8, DOT Hazard Class:CORROSIVE, POISON DOT Hazard Label:UN2922 UN/NA Number:II Packing Group:Licensed to SIFCO Applied Surface ConceptsANSI :12/06/2011 Printed: 5 Page: SIFCO Process Solution cadmium LHEMATERIAL SAFETY data SHEET12/21/2010 Supercedes Revision:AIR TRANSPORT (ICAO/IATA)2922 UN Number:8, - CORROSIVE, POISON Hazard Class:II Packing Group:8, IATA Classification:MARINE TRANSPORT (IMDG/IMO)2922 UN Number:8, - CORROSIVE, POISON Hazard Class:II Packing Group:Yes - Serious Marine Pollutant:Additional Transport Information15.
10 Regulatory InformationUS EPA SARA Title IIINoNoNoHazardous Components (Chemical Name)Borate(1-), tetrafluoro-, cadmium (2:1)14486-19-2 CAS # (EHS) (TRI) 5000 LBNoEthylenediamine107-15-3 Yes 10000 LB No EPA CAA, CWA, TSCAI nventoryNoNoHazardous Components (Chemical Name)Borate(1-), tetrafluoro-, cadmium (2:1)14486-19-2 CAS #HAP, ODC ()EPA CAAEPA CWA NPDESEPA TSCACA PROP 65 HAP, ODC () HAP, ODC () (Superfund Amendments andReauthorization Act of 1986) Lists:EPA SARA Title III Section 302 Extremely Hazardous Chemical with TPQ. * indicates 10000LB TPQ if not volatile. :EPA SARA Title III Section 304: CERCLA Reportable + with Reportable Quantity. **indicates statutory RQ. :EPA SARA Title III Section 313 Toxic Release Inventory. Note: -Cat indicates a member of achemical category. :EPA SARA 110 Superfund Site Priority Contaminant List :TSCA (Toxic Substances ControlAct) Lists:Chemical Listed in the TSCA Inventory.