MATERIAL SAFETY DATA SHEET PIPERAZINE - Delamine

1 MATERIAL SAFETY DATA SHEET . PIPERAZINE . 1. CHEMICAL PRODUCT & COMPANY IDENTIFICATION. Chemical Name: PIPERAZINE Manufacturer Information: Delamine Barchman Wuytierslaan 10. 3818 LH Amersfoort PO Box 473. 3800 AL Amersfoort, The Netherlands Tel: +31 33 4676897. FOR EMERGENCIES, CONTACT CHEMTREC 1-800-424-9300 OR 1-703-527-3887. 2. COMPOSITION/INGREDIENT DESCRIPTION. OSHA. Chemical Name CAS # Hazardous(Y/N) Concentration (%). PIPERAZINE 110-85-0 Y approx. 100. 3. HAZARDS IDENTIFICATION. EMERGENCY OVERVIEW: CORROSIVE TO EYES, SKIN, AND RESPIRATORY TRACT. HARMFUL IF SWALLOWED. MATERIAL WILL ABSORB WATER FROM THE AIR. CHEMICALS. OF THIS TYPE MAY CAUSE SENSITIZATION BY INHALATION OR SKIN CONTACT.

2 Physical Appearance and Odor: Colorless to white flakes or crystals, ammonia-like odor POTENTIAL HEALTH EFFECTS: Acute Eye: Corrosive to eyes. May cause permanent damage and blindness. Vapors can cause a non- permanent vision problem of seeing halos or a blue haze . Acute Skin: Corrosive to skin. Chemicals of this type may cause sensitization upon prolonged or repeated exposure. Acute Inhalation: May cause severe irritation to respiratory tract, with coughing, nausea and sore throat. May produce respiratory sensitization, causing asthma. Acute Ingestion: Ingestion may cause nausea, vomiting, diarrhea and allergic reactions. Ingestion of large amounts may cause muscle weakness, dizziness, confusion and difficulties in speech.

3 Chronic Effects: None known. 4. FIRST AID MEASURES. Eye Contact: Hold eyelids open and flush with a steady, gentle stream of water for at least 15 minutes. Seek immediate medical attention. PIPERAZINE MATERIAL SAFETY DATA SHEET US Version Date Prepared: June 30, 2008 Supercedes: None (Page 1 of 6). 4. FIRST AID MEASURES (continued). Skin Exposure: Remove contaminated clothing and shoes. Wash with plenty of soap and water, for at least 15 minutes. Seek immediate medical attention. Launder contaminated clothing and shoes before re-use. Destroy leather shoes, if contaminated. Inhalation: If respiratory irritation or distress occurs, remove victim to fresh air. Seek medical attention if respiratory irritation or distress continues.

4 Ingestion: Do not induce vomiting. If victim is conscious and alert, give 1-2 glasses of water to drink. Do not give anything by mouth to an unconscious person. Seek immediate medical attention. Do not leave victim unattended. Medical Conditions Possibly Aggravated by Exposure: Skin contact may aggravate existing skin disease. Notes to Physician: All treatments should be based on observed signs and symptoms of distress in the patient. Consideration should be given to the possibility that overexposure to materials other than this product may have occurred. Treat symptomatically. No specific antidote available. 5. FIRE FIGHTING MEASURES. Flash point: 151F (66C). Autoignition Temperature: 644F (340C).

5 Flammability limits (vol/vol%): Lower: 4% Upper: 14%. Extinguishing Media: water spray, fog, dry chemical, foam, CO2. Special Fire Fighting Procedures: Firefighters should wear NIOSH/MSHA-approved self-contained breathing apparatus and full protective clothing. Cool containers exposed to fire with water. Unusual Fire and Explosion Hazards: Closed containers may rupture due to buildup of pressure when exposed to extreme heat. Like all organic and most dry chemicals, as a powder or dust, this product (when mixed with air in critical proportions and in the presence of an ignition source) may present an explosion hazard. Hazardous Decomposition Materials Under Fire Conditions: Oxides of carbon, oxides of nitrogen, ammonia 6.

6 ACCIDENTAL RELEASE MEASURES. Evacuation Procedures and SAFETY : Wear appropriate protective gear for the situation. (See Personal Protection information in Section 8). Cleanup and Disposal of Spill: Extinguish or remove all sources of ignition. Sweep up, using non- sparking tools, and place in an appropriate closed container for disposal and/or incineration, avoiding contact with spilled MATERIAL . Clean up residual MATERIAL by washing area with water. Collect washings for disposal. Environmental and Regulatory Reporting: Do not flush to drain. Spills may be reportable to the National Response Center (800-424-8802) and to state and/or local agencies. PIPERAZINE MATERIAL SAFETY DATA SHEET US Version Date Prepared: June 30, 2008 Supercedes: None (Page 2 of 6).

7 7. HANDLING AND STORAGE. Storage Temperature: Minimum 131F (55C), Maximum 149F (65C). Handling: Persons with a history of dermal or respiratory sensitization should not work with, or near, this MATERIAL . Avoid breathing dusts. Avoid direct or prolonged contact with skin and eyes. Transfer and handle product only in a closed system. Storage: MATERIAL absorbs water from the air. Store in tightly-closed, original container. Store in an area that is cool, dry, dark and well-ventilated. Do not re-use container. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION. Introductory Remarks: These recommendations provide general guidance for handling this product. Because specific work environments and MATERIAL handling practices vary, SAFETY procedures should be developed for each intended application.

8 Exposure Guidelines: The following limits apply to components of this MATERIAL . Chemical None Engineering Controls: General area dilution/exhaust ventilation. Respiratory Protection: When respirators are required, select NIOSH/MSHA approved equipment based on actual or potential airborne concentrations and in accordance with regulatory standards and/or industrial recommendations. Self-contained or supplied-air respiratory equipment is recommended. Eye/Face Protection: SAFETY glasses with side shields, goggles or face shield are recommended. Skin Protection: Skin contact should be minimized through the use of chemical-resistant gloves and boots, and suitable protective clothing.

9 Work Practice Controls: The following general measures should be taken when working or handling this MATERIAL : 1) Do not store, use, and/or consume foods, beverages, tobacco products, or cosmetics in areas where this MATERIAL is stored. 2) Wash hands and face carefully before eating, drinking, using tobacco, applying cosmetics, or using the toilet. 3) Wash exposed skin promptly to remove accidental splashes of contact with this MATERIAL . 9. PHYSICAL AND CHEMICAL PROPERTIES. Physical and Chemical properties here represent typical properties of this product. Contact the manufacturer for exact specifications. Physical Appearance: Colorless to white flakes or crystals Odor: Ammonia-like odor pH: 12 (@10% aq.

10 Specific Gravity: Water Solubility: Soluble Melting Point Range: 230F (110C). Boiling Point Range: 298F (148C). Freezing Point Range: Not determined. Vapor Pressure: kPa at 68F (20C). Vapor Density: (air = 1). PIPERAZINE MATERIAL SAFETY DATA SHEET US Version Date Prepared: June 30, 2008 Supercedes: None (Page 3 of 6). 10. STABILITY AND REACTIVITY. Chemical Stability: MATERIAL is hygroscopic, and readily absorbs water from air. Conditions to be Avoided: Heat, open flame, sparks, static conditions. Materials/Chemicals to be Avoided: Strong oxidizing agents, acids, acid anhydrides, chlorinated hydrocarbons, pure copper, pure nickel, cobalt-containing alloys. May react with metals, releasing hydrogen gas.