MATERIAL SAFETY DATA SHEET TH-18u Make-Up Ink

1 MATERIAL SAFETY data SHEETMATERIAL SAFETY data SHEETTH-18u Make-Up InkTH-18u Make-Up InkTTH I SH I S M MA T E R I A LA T E R I A L S SA F E T YA F E T Y D DA T AA T A S SH E E TH E E T C O N F O R M SC O N F O R M S T OT O T H ET H E R E Q U I R E M E N T SR E Q U I R E M E N T S O FO F A N S I Z 4 0 0 . 1 . A N S I Z 4 0 0 . 1 .TTH I SH I S M S D S M S D S C O M P L I E SC O M P L I E S W I T HW I T H 2 9 C F R 1 9 1 0 . 1 2 0 0 ( O S H A H 2 9 C F R 1 9 1 0 . 1 2 0 0 ( O S H A HA Z A R DA Z A R D C CO M M U N I C A T I O NO M M U N I C A T I O N S ST A N D A R DT A N D A R D) .) .IIM P O R T A N TM P O R T A N T: R: RE A DE A D T H I ST H I S M S D S M S D S B E F O R EB E F O R E H A N D L I N GH A N D L I N G O RO R D I S P O S I N GD I S P O S I N G O FO F T H I ST H I S P R O D U C TP R O D U C I PRODUCT & COMPANY IDENTIFICATIONSECTION I PRODUCT & COMPANY IDENTIFICATIONMANUFACTURER / DISTRIBUTORH itachi America, Ltd50 Prospect AvenueTarrytown, NY 10591 PRODUCT NAMETH-18u Make-Up InkMATERIAL USESI ndustrial coding applications.

2 Ink Jet PrintersPRODUCT CODE X (22, 45, 53) 0374 NON-EMERGENCY PHONE914-524-6685 EMERGENCY PHONECHEMTREC (800) 424-9300 SECTION II COMPOSITION / INFORMATION ON INGREDIENTSSECTION II COMPOSITION / INFORMATION ON INGREDIENTSINGREDIENTCAS#PERCENT RANGE (%)Methyl Ethyl Ketone78-93-360 - 100 Acetone67-64-11 - 5 SECTION III - HAZARDS IDENTIFICATIONSECTION III - HAZARDS IDENTIFICATIONHAZARDOUS MATERIAL IDENTIFICATION SYSTEM (HMIS)HEALTHHEALTH11 FLAMMABILITYFLAMMABILITY33 REACTIVITYREACTIVITY00 PERSONALPERSONAL PROTECTIONPROTECTIONBBNOTICE: THESE RATINGS ARE FOR GENERAL RAPID INTERPRETATION. THE END-USER IS RESPONSIBLE FOR DETERMINING THE PROPER PROTECTIVE OVERVIEWW arning! Flammable Liquid and Vapor. Skin, Eye and Mucous Membrane Irritant. Do not use near fire or flame.

3 May be fatal or cause blindness if swallowed. Avoid contact with skin, eyes and mucous membranes. If skin contact occurs, wash skin with mild soap and water. If splashed in eyes, flush with water. If inhaled, remove to fresh air. In medical emergency contact Poison Control Center (USA ). Read MSDS before EFFECTS AND RELATED SYMPTOMSMETHYL ETHYL KETONEM inor embryotoxic/fetotoxic effects have been observed in laboratory rats exposed to methyl ethyl ketone by inhalation at levels greater than 1000 ppm (5 times the OSHA-PEL/TWA) for most of the gestation period. Methyl ethyl ketone may potentiate (shorten the time of onset) peripheral neuropathy, but methyl ethyl ketone, by itself, has not been shown to cause peripheral skin and severe eye irritant.

4 Experimental reproductive effects. Narcotic in high STATEMENTSR11 Highly FlammableR36/37/38 Irritating to eyes, respiratory system and skinR66 Repeated exposure may cause skin dryness or crackingR67 Inhalation of vapors can provoke sleepiness and dizzinessSAFETY STATEMENTSS2 Keep away from container tightly closedS16 Keep away from sources of ignition - No Smoking!S25 Avoid contact with eyesS36/37 Wear suitable protective clothing and glovesS45In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible)SECTION IV - FIRST AID MEASURESSECTION IV - FIRST AID MEASURESORAL INGESTIONDo not induce vomiting unless directed to do so by medical personnel. Seek immediate medical CONTACTF lush with water for 15 minutes and seek medical CONTACTWash with soap and water.

5 Wash contaminated clothing before reuse. Seek immediate medical to fresh air, if not breathing, give artificial respiration and seek medical 1 of 4F - Highly FlammableXi - IrritantSECTION V - FIREFIGHTING MEASURESSECTION V - FIREFIGHTING MEASURESEXTINGUISHING MEDIAA lcohol Resistant foam or dry chemicalHAZARDOUS COMBUSTION PRODUCTSC arbon Monoxide, Carbon DioxideFIRE FIGHTING PROCEDURESWear self-contained breathing apparatus with full facepiece operated in the positive pressure demand VI - ACCIDENTAL RELEASE MEASURESSECTION VI - ACCIDENTAL RELEASE MEASURESKeep away all sources of ignition from spill. If spill is indoors, ventilate areas of spill and soak up the spill with absorbent MATERIAL . Do not let spilled or leaking MATERIAL enter VII - HANDLING AND STORAGESECTION VII - HANDLING AND STORAGEHANDLINGA void contact with eyes.

6 Wash hands thoroughly with soap and water after handling. Utilize proper grounding with containers of from freezing. Overheating may cause container to rupture. Covered storage in a cool, dry place out of direct sunlight is preferable. Keep container tightly sealed until ready for use. Store away from ignition VIII - EXPOSURE CONTROLS / PERSONAL PROTECTIONSECTION VIII - EXPOSURE CONTROLS / PERSONAL PROTECTIONRESPIRATORY PROTECTIONIf workplace exposure limit(s) of product or any other component is exceeded, a NIOSH/OSHA approved respirator is advised. (See your SAFETY equipment supplier for specific details.)VENTILATIONP rovide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below PEL/ GLOVESWear chemical resistant gloves.

7 (Consult your SAFETY equipment supplier.)EYE PROTECTIONWear chemical splash goggles in compliance with OSHA regulations. However, OSHA regulations also permit other types of SAFETY PROTECTIVE EQUIPMENTWear impervious clothing and boots to prevent prolonged EXPOSURE LIMITS:INGREDIENTACGIH TLV*OSHA PEL*Methyl Ethyl Ketone200200 Acetone750750 SECTION IX - PHYSICAL & CHEMICAL PROPERTIESSECTION IX - PHYSICAL & CHEMICAL PROPERTIESPHYSICAL STATEL iquidCOLORC learODORS olvent odorBOILING RANGE80 CMELTING RANGE- 86 CSPECIFIC GRAVITY (WATER=1) (lbs / gal) RATE (N-BUTYL ACETATE=1)~ 6 PERCENT VOLATILE BY VOLUME (%)100%VAPOR PRESSURE85 mm of Hg @ 20 CVAPOR DENSITY (AIR=1)Greater than airFLASH POINT (TCC)- 4 CAUTO IGNITION TEMPERATURE515 CUPPER FLAMMABLE LIMIT (%BY VOL.)

8 FLAMMABLE LIMIT (%BY VOL.) IN WATERM iscibleSOLUBILITY IN ORGANIC SOLVENTSM isciblePHNot ApplicableSECTION X - STABILITY & REACIVITYSECTION X - STABILITY & REACIVITYCONDITION OF INSTABILITYNone KnownCONDITIONS OF REACTIVITYNot applicableINCOMPATIBILITYS trong oxidizing agentsHAZARDOUS DECOMPOSITION PRODUCTSC arbon Monoxide, Carbon DioxideEXPLOSION data (SENSITIVE TO MECHANICAL IMPACT)NoEXPLOSION data (SENSITIVE TO STATIC DISCHARGE)YesPage 2 of 4 SECTION XI - TOXICOLOGICAL INFORMATIONSECTION XI - TOXICOLOGICAL INFORMATIONINGREDIENTTOXICOLOGICAL INFORMATION**Methyl Ethyl KetoneLD50 Oral (rat) - 2737 mg / kgLC50 Inhalation (rat) - 23,500 mg / m3 / 8 hrLD50 Intraperitoneal (rat) - 607 mg / kgLD50 Skin (rabbit) - 6480 mg / kgLDLo Intraperitoneal (guinea pig)

9 - 2 g / kgAcetoneLD50 Intravenous (rat) 5500 mg / kgLD50 Oral (rat) - 5800 mg / kgLC50 Inhalation (rat) - 50,000 mg / m3 / 8 hrLDLo Oral (dog) 8 g / kgLD50 Oral (rabbit) - 5340 mg / kgLD50 Skin (rabbit) - 20 g / kgSECTION XII - ECOLOGICAL INFORMATIONSECTION XII - ECOLOGICAL INFORMATIONECOTOXICITYNot AvailablePERSISTANCE / DEGRADABILITYNot AvailableHEAVY METALSC oncentration of lead, mercury, cadmium and hexavalent chromium [Cr(VI)] < 100 ppmNo other ecological information is available for this XIII - DISPOSAL CONSIDERATIONSSECTION XIII - DISPOSAL CONSIDERATIONSA bsorb in vermiculite, floor absorbent or other non-combustible absorbent MATERIAL and dispose in licensed facility. Observe all federal, state and local XIV - TRANSPORT INFORMATIONSECTION XIV - TRANSPORT INFORMATIONDOT / TDG UN NUMBER & PROPER SHIPPING NAMEUN1210 PRINTING INKDOT / TDG HAZARD CLASS3 DOT / TDG LABELFLAMMABLE LIQUIDPACKING GROUPIIEMERGENCY RESPONSE GUIDEBOOK NUMBER129 SECTION XV - REGULATORY INFORMATIONSECTION XV - REGULATORY INFORMATIONTSCAAll chemicals used are listed on the TSCA following product(s) is (are) listed by CERCLA:Methyl Ethyl Ketone (60 - 100%)Acetone (1 - 5%)SARA 313 The following product(s) is (are) listed on SARA 313.

10 Methyl Ethyl Ketone (60 - 100%)California Prop 65 This product contains the following ingredients that the State of California has found to cause cancer, birth defects, or other reproductive harm, which requires a warning under the statute:Toluene ( )International RegulationsThe components of this product are listed on the chemical inventories of the following countries:Australia, Canada, Europe (EINECS), Japan, Korea, United KingdomPage 3 of 4 SECTION XVI - OTHER INFORMATIONSECTION XVI - OTHER INFORMATIONISSUE DATEA pril 2007 REVISION NUMBER1 SUPERCEDESn/aPREPARED BYChris Jordan,Product SpecialistDISCLAIMERE very effort has been made to ensure that the information in this MSDS is accurate and as complete as reasonably possible and of course all data herein are given in good faith.