Material Safety Data Sheet - The Wall Street Journal

1 SDSUS / EN / 05 Version: Revision date: 08/18/2011 Initiator: 0001 150000014291 COPYRIGHT 2011 BY EASTMAN CHEMICAL company 1/14 Safety data Sheet SECTION 1: Identification of the substance/mixture and of the company /undertaking Product identifier Product name: Crude MCHM Product No.: EAN 972790. 18717-00, P1871700, P18717EA, P18717ET, P18717YZ Relevant identified uses of the substance or mixture and uses advised against Identified uses: Industrial chemical. gasoline blending Uses advised against: None known. Details of the supplier of the Safety data Sheet Manufacturer / Supplier Eastman Chemical company 200 South Wilcox Drive Kingsport, TN 37660-5280 US +14232292000 Visit our website at or email Emergency telephone number: For emergency health, Safety , and environmental information, call 1-423-229-4511 or 1-423-229-2000. For emergency transportation information, in the United States: call CHEMTREC at 800-424-9300 or call 423-229-2000.

2 SECTION 2: Hazards identification WARNING! HARMFUL IF SWALLOWED CAUSES SKIN AND EYE IRRITATION AT ELEVATED TEMPERATURES, VAPOR MAY CAUSE IRRITATION OF EYES AND RESPIRATORY TRACT SECTION 3: Composition/information on ingredients / Substances / Mixtures General information: Chemical name Concentration Additional identification Notes 4-methylcyclohexanemethanol 68 - 89% CAS-No.: 34885-03-5 EC No.: 609-038-8 4-(methoxymethyl)cyclohexanemethanol 4 - 22% CAS-No.: 98955-27-2 SDSUS / EN / 05 Version: Revision date: 08/18/2011 Initiator: 0001 150000014291 COPYRIGHT 2011 BY EASTMAN CHEMICAL company 2/14 water 4 - 10% CAS-No.: 7732-18-5 EC No.: 231-791-2 methyl 4-methylcyclohexanecarboxylate 5% CAS-No.: 51181-40-9 dimethyl 1,4-cyclohexanedicarboxylate 1% CAS-No.: 94-60-0 EC No.: 202-347-5 methanol 1% CAS-No.: 67-56-1 EC No.: 200-659-6 INDEX No.: 603-001-00-X # 1,4-cyclohexanedimethanol 1 - 2% CAS-No.

3 : 105-08-8 REACH Registration No.: 01-2119448337-34-0000 01-2119448337-34-0002 # * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. # This substance has workplace exposure limit(s). PBT: persistent, bioaccumulative and toxic substance. vPvB: very persistent and very bioaccumulative substance. SECTION 4: First aid measures Description of first aid measures Inhalation: Treat symptomatically. Move to fresh air. Get medical attention if symptoms persist. Eye contact: Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses. Get medical attention. In case of irritation from airborne exposure, move to fresh air. Get medical attention if symptoms persist. Skin contact: Immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately. Wash contaminated clothing before reuse.

4 Destroy or thoroughly clean contaminated shoes. Ingestion: Call a physician or poison control center immediately. Only induce vomiting at the instruction of medical personnel. Never give anything by mouth to an unconscious person. Not relevant, due to the form of the product. Most important symptoms and effects, both acute and delayed: No data available. Indication of any immediate medical attention and special treatment needed Hazards: No data available. Treatment: Treat symptomatically. SECTION 5: Firefighting measures General fire hazards: None known. SDSUS / EN / 05 Version: Revision date: 08/18/2011 Initiator: 0001 150000014291 COPYRIGHT 2011 BY EASTMAN CHEMICAL company 3/14 Extinguishing media Suitable extingishing media: Water spray. Dry chemical. Carbon Dioxide. Alcohol foam. Unsuitable extinguishing media: None known. Special hazards arising from the substance or mixture: None known. Advice for firefighters Special Fire Fighting Procedures: Fight fire from a protected location.

5 Special protective equipment for fire-fighters: Self-contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures: Wear appropriate personal protective equipment. Environmental precautions: Avoid release to the environment. Methods and Material for containment and cleaning up: Absorb spill with vermiculite or other inert Material , then place in a container for chemical waste. Large Spillages: Flush spill area with water spray. Prevent runoff from entering drains, sewers, or streams. Dike for later disposal. Notification Procedures: In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. SECTION 7: Handling and storage: Precautions for safe handling: Avoid breathing vapor from heated Material . Avoid contact with eyes, skin, and clothing.

6 Do not taste or swallow. Use only with adequate ventilation. Wash thoroughly after handling. Conditions for safe storage, including any incompatibilities: Keep container closed. Keep away from food, drink and animal feedingstuffs. Specific end use(s): Industrial chemical. gasoline blending SDSUS / EN / 05 Version: Revision date: 08/18/2011 Initiator: 0001 150000014291 COPYRIGHT 2011 BY EASTMAN CHEMICAL company 4/14 SECTION 8: Exposure controls/personal protection Control parameters Occupational exposure limits If exposure limits have not been established, maintain airborne levels to an acceptable level. Chemical name Type Exposure Limit values Source methanol TWA 200 ppm US. ACGIH Threshold Limit Values (01 2010) STEL 250 ppm US. ACGIH Threshold Limit Values (01 2010) PEL 200 ppm 260 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) (02 2006) Biological limit values Chemical name Exposure Limit values Source methanol (methanol: Sampling time: End of shift.)

7 15 mg/l (Urine) ACGIH BEL (01 2010) Exposure controls Appropriate engineering controls: Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment General information: Eye bath. Safety shower. Washing facilities. Eye/face protection: Wear Safety glasses with side shields (or goggles). Wear a full-face respirator, if needed. Skin protection Hand protection: Wear chemical-resistant gloves, footwear, and protective clothing appropriate for the risk of exposure. Contact health and Safety professional or manufacturer for specific information.

8 Other: No data available. Respiratory Protection: If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. In the United States of America, if respirators are used, a program should be instituted to assure compliance with OSHA Standard 63 FR 1152, January 8, 1998. Respirator type: Air-purifying respirator with an appropriate, government approved (where applicable), air-purifying filter, cartridge or canister. Contact health and Safety professional or manufacturer for specific information. SDSUS / EN / 05 Version: Revision date: 08/18/2011 Initiator: 0001 150000014291 COPYRIGHT 2011 BY EASTMAN CHEMICAL company 5/14 Hygiene measures: Observe good industrial hygiene practices. Environmental Controls: No data available. SECTION 9: Physical and chemical properties Information on basic physical and chemical properties Appearance Physical State: Liquid Form: Liquid Color: Colorless Odor: Alcohol Odor Threshold: No data available.

9 PH: No data available. Freezing Point: 0 C Boiling Point: 180 C Flash Point: C (Setaflash Closed Cup) Evaporation Rate: No data available. Flammability (solid, gas): No data available. Flammability Limit - Upper (%) : No data available. Flammability Limit - Lower (%) : No data available. Vapor pressure: No data available. Vapor density (air=1): No data available. Relative density: < 1 (estimated) Solubility(ies) Solubility in Water: Appreciable Solubility (other): No data available. Partition coefficient (n-octanol/water): No data available. Autoignition Temperature: No data available. Decomposition Temperature: Thermal stability not tested. Low stability hazard expected at normal operating temperatures. Viscosity: No data available. Explosive properties: No data available. Oxidizing properties: No data available. SECTION 10: Stability and reactivity Reactivity: Materials containing similar structural groups are normally stable.

10 Chemical stability: Not fully evaluated. Possibility of hazardous reactions: None known. Conditions to avoid: Excessive heat. SDSUS / EN / 05 Version: Revision date: 08/18/2011 Initiator: 0001 150000014291 COPYRIGHT 2011 BY EASTMAN CHEMICAL company 6/14 Incompatible materials: Strong oxidizing agents. Hazardous decomposition products: Carbon Dioxide. Carbon Monoxide. SECTION 11: Toxicological information Information on likely routes of exposure Inhalation: At elevated temperatures, vapor may cause irritation of eyes and respiratory tract. Ingestion: Harmful if swallowed. Skin contact: Causes skin irritation. Eye contact: Causes serious eye irritation. Information on toxicological effects Acute Toxicity Oral Product: Oral LD-50: (Rat): 825 mg/kg Dermal Product: Dermal LD-50: (Rat): > 2,000 mg/kg Inhalation Product: No data available. Specified substance(s) 4-methylcyclohexanemethanol No data available.