MATERIAL SAFETY DATA SHEET - Vance Brothers

1 HMIS HAZARD RATING2 HEALTH0 FIRE0 REACTIVITYMATERIAL SAFETY data SHEET5201 Brighton, Box 300107 Kansas City, MO 64130 Phone: 816-923-4325/ 800-821-8549 FAX: 816-923-6472 Emergency Phone Number (CHEMTREC): 800-424-9300I. PRODUCT INFORMATIONTRADE NAMECOAL TAR / PROTECTAR NUMBERM ixtureSYNONYMSP rotecTar, Driveway SealerPRODUCT CODE NUMBER709-717II. PHYSICAL DATABOILING POINT @ 760 MM Hg212 F% VOLATILES BY VOLUME50-64%SOLUBILITY IN H20 BY WEIGHT %MiscibleSPECIFIC @60 FMELTING POINTNot ApplicableEVAPORATION RATE (BUTYL ACETATE = 1)SlowerVAPOR DENSITY (AIR = 1)> PRESSURE25 mm Hg @ 70 FAPPEARANCE AND ODORGray to Black MATERIAL withMothball OdorIII. HAZARDOUS NUMBERMATERIAL OR COMPONENT%HAZARD DATA65996-93-2[1] Refined Coal Tar20-33 TLV/TWA-1mg/m3as benzene mg/m3for benzene solubles7732-18-5[2] Water50-64 Not applicableIV.

2 HEALTH HAZARD mg/m3 TLV/ mg/m3 ODOR THRESHOLD LIMITNot ApplicableROUTES OF EXPOSURE AND EFFECTS AS REQUIRED BY tar vapors released during the curing process have been shown to cause irritation tothe human respiratory acute toxicity of coal tar is considered to be moderate. Symptoms of systemicpoisoning from ingestion may include salivation, vomiting, respiratory difficulties,dizziness, and headache, loss of pupillary reflexes, cyanosis, hypothermia and mildconvulsions. Fatal dose is g/kg body weight for ABSORPTIONSkin absorption may occur through normal skin contact and/or through wounds exposed tocoal tar products. Effects include irritation and minor burns (which may leadto benignskin growths or skin cancer). Health effects can be minimized if proper personal safetyand hygiene is CONTACTCoal tar and coal tar vapors (released duringthe curing process) may cause burning,itching, pigmentation changes, skin eruptions, and skin photosensitization.

3 Pre-existingskin disorders may be aggravated by CONTACTP roduct in direct contact with the eyes may cause inflammation, discomfort, conjunctivitis,corneal abrasion, and tissue burns. Exposure to vapors can result in irritation and burningsensations. Contact lenses should not be worn when exposed to this OVEREXPOSURECoal tar vapors, released during the curing process, have been shown to cause irritation tothe human respiratory tract. Skin effects include irritation and minor burns (which may leadto benign or cancerous skin growths). Overexposure to vapors may result in symptomsnoted in theINGESTION section OVEREXPOSUREP ersons with pre-existing skin or respiratory conditions have increased risk whenoverexposed. Chronic health effects are not expected if proper personal SAFETY andhygiene is observed.

4 However, prolonged or repeated exposure may lead to various typesof skin disorders and possible skin EMERGENCY AND FIRST AID PROCEDURESINHALATIONIf breathing is difficult, move person to fresh air or administer oxygen. If breathing hasstopped, give artificial respiration. Seek immediate medical person is conscious, induce vomiting to prevent absorption. Syrup of ipecac or saltwater is recommended for this purpose. After vomiting, take two tablespoons of USPgrade activated charcoal in water. If respirationis shallow, give oxygen. Seek immediatequalified medical assistance. WARNING: Never give anything by mouth to an CONTACTF lush area withwater to cool. Wash affected area with waterless hand cleaner, followedby water and a mild detergent. DO NOT use solvents!

5 For relief from irritation, apply topicalskin creams. If irritation persists, seek medical CONTACTF lush eyes with water for 15 minutes while holding eyelids open. If subject is wearing contact lenses, immediately seek anophthalmologist EMULSION MSDS Page 2 of4VI. SPECIAL PROTECTION INFORMATIONVENTILATIONCare must be taken to assure that the TLV/TWA oil mist is not exceeded. Normal exteriorapplication should not require the need for mechanicalventilation. Application must be made downwind PROTECTIVEEQUIPMENTRESPIRATORYPROTECTION If needed, use an approved OSHA/NIOSH particulate andorganic vapor canister respirator, or a positive atmospheresupplied air respirator as described in 29 CFR VAPORRESPIRATOREYE PROTECTIONG oggles and full-face shield are recommended when handlingthis MATERIAL .

6 Contact lenses should not be worn whenhandling this SHIELDSKIN PROTECTIONF lannel-lined Neoprene or Nitrile gloves are RESISTANTGLOVESOTHER PPER ubber orleather footwear is recommended. Long pants anda long-sleeved shirt, buttoned at the collar should be clothing saturated with this product should be SHIRTVII. FIRE AND EXPLOSION DATAFLASH POINTNot ApplicableAUTOIGNITION TEMPERATURENot ApplicableLOWER FLAMMABLE LIMITU nknownEXTINGUISHING MEDIAThis product contains water and will not burn until all moisture has been fire should occur, extinguish with foam, carbon dioxide or dry chemical FIRE FIGHTING PROCEDURESFire fighters should wear fullprotective equipment and self-contained breathing FIRE AND EXPLOSION HAZARDSW ater sprayed on burning product may cause frothing, steam, and REACTIVITY DATACONDITIONS CONTRIBUTING TO INSTABILITYS ince this is a water-based emulsion, settling will occur.

7 The settling rate is dependent onthe dilution and storage temperature. NOTE: Care should be taken to prevent this materialfrom MATERIAL is incompatible with strong acids and bases. DO NOT heat above 212 F. Alladditives should be evaluated before use in the DECOMPOSITION PRODUCTSI rritating or toxic vapors may be released when this MATERIAL is CONTRIBUTING TO HAZARDOUS POLYMERIZATIONNone EMULSION MSDS Page 3 of 4IX. SPILL AND LEAK PROCEDURESSPILL CONTROL PROCEDUREIf possible, stop source of leak. Dike and contain to eliminate environmental small spills, squeegee into thin layer and cover with dirt or aggregate. If MATERIAL entersa Waterway, notify police, local EPA and the National Response Center (1-800-424-8802)NEUTRALIZING CHEMICALSDO NOT use water.

8 This MATERIAL is highly miscible and water will increase the volume ofthe spill. If appropriate, pump MATERIAL into holding vessel and bind with sand or lime DISPOSALIf disposal is necessary, contact your state environmental agency for guidance withdisposal methods and waste receiving locations in your SPECIAL PRECAUTIONSENVIRONMENTAL1. This product is considered an oil under EPA-CWA Section 311. Spills into watersources must be reported to If this product becomes a waste MATERIAL , refer to 40 CFR (RCRA) forlatest waste disposal regulations and waste stream This product is listed in the EPA/TSCA inventory (40 CFR 700 to end).LABELING1. "KEEP FROM FREEZING" labels are This MATERIAL is not regulated by the Department of REFERENCES1. NIOSH CRITERIA FOR A RECOMMENDED STANDARD,6.

9 HYGIENE AND SANITATION, VOLUME 33 OCCUPATIONAL EXPOSURE TO COAL TAR NFPA 325M, 7042. CLINICAL TOXICOLOGY AND APPLIED PHARMACOLOGY, VOLUME JOURNAL OF INDUSTRIAL HYGIENE #123. DOCUMENATION OF THRESHOLD LIMIT VALUES, 4TH EDITION9. 29 CFR, 40 CFR AS NOTED WITHIN4. DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS, 6TH REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES5. EPA/CWA SECTION 311 NOTE: This MATERIAL SAFETY data SHEET is intended as a source of information for persons involved in any and all phases of handling this MATERIAL , from production to final application,as required by 29 CFR The health data provided is based on the nature of the raw constituents. This MATERIAL is a mixture and thehealth effects as such have not ENVIRONMENTAL INFORMATION1.

10 THIS PRODUCT CONTAINS THE FOLLOWING EXTREMELY HAZARDOUS SUBSTANCE (S)4. THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS(SECTION 302 AND 304):COMPONENTTPQ(LBS)RQ(BLS)(SECTION 313):COMPONENTCAS#WEIGHT %N/AN/AN/AAnthracene120-12-7< THIS PRODUCT CONTAINS THE FOLLOWING CERCLA HAZARDOUS SUBSTANCE (S)Biphenyl92-52-4< (SECTION302 AND 304):COMPONENTRQ(LBS)WEIGHT %Dibenzofuran132-64-9< < < :NTPIARC MONOGRAPHSOSHA3. THIS PRODUCT HAS THE FOLLOWING HAZARDS (SECTION 311 AND 312):NONONOYESNOIMMEDIATEXDELAYEDXFIREXP RESSUREXREACTIVITYXThe information provided in this MATERIAL SAFETY data SHEET has been obtained and compiled from sources believed to be reliable. This information relates to thespecific materialdesignated and may not be valid for such MATERIAL used in combination with any other MATERIAL or in any process.