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Mechanism of Electron Transfer Reactions – Types; Outer ...
The mechanism by which the electron transfer occurs in transition metal complexes can be classified into two types as given below. Outer Sphere Electron Transfer Mechanism In this mechanism, there is a direct transfer of electrons from the reductant to oxidant and the coordination sphere remains intact.
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π-Bonding and Molecular Orbital Theory
www.dalalinstitute.comHence, the crystal field splitting Δ o increases and the bond between the ligand and the metal strengthens when metal to ligand bonding takes place. 3. When ligand π-orbitals are empty as well as filled: There are many ligands, like I–, which have both filled p-orbitals as well as vacant d-orbitals of π symmetry.
Entropy Changes in Reversible and Irreversible Processes
www.dalalinstitute.comEntropy Changes in Reversible Processes Suppose that the heat absorbed by the system and heat lost by the surrounding are under completely reversible conditions. In other words, q. rev. is the heat absorbed and lost by the surrounding at temperature T, then we can say that the entropy change in the system will be given by the following relation.
Quantum Mechanical Operators and Their Commutation …
www.dalalinstitute.comVolume 1 by Mandeep Dalal”, and is the intellectual property of the Author/Publisher. The content of this document is protected by international copyright law and is valid only for the ... Quantum Mechanical Operators and Their Commutation Relations ...
Molecular Orbital Theory – Octahedral, Tetrahedral or ...
www.dalalinstitute.commolecular orbital. After the formation of molecular orbitals, both electrons occupy σ-orbital. Now, if the energy of σ-orbital is closer to ϕA, it will have more ϕA character and hence the electron density of both of the electrons will be concentrated more on atom A than B. Similarly if the energy of σ-orbital is closer to ϕB, it will have
Schrodinger Wave Equation for a Particle in One ...
www.dalalinstitute.comEntropy Changes in Reversible and Irreversible Processes ..... 87 Variation of Entropy with Temperature, Pressure and Volume ..... 92 Entropy Concept as a Measure of Unavailable Energy and Criteria for the Spontaneity of Reaction
Jahn-Teller Effect - Dalal Institute
www.dalalinstitute.comCFSE due to distortion = Energy of the distorted complex (E2) − Energy of the complex without distortion (E1) E1o) E1o E2o – δ2/3) E2o – δ2/3 CFSE due to distortion = E2 – E1 = –δ2/3 Hence, the crystal field stabilization due to z-out distortion is –δ1/3. Moreover, it is worthy to note that this
Orgel and Tanabe-Sugano Diagrams for Transition Metal ...
www.dalalinstitute.comcomplex may have some allowance of d-d transitions. vibrations where the molecule is asymmetric and the absorption of light at that moment is then possible. Both of these effects (vibronic coupling or six dissimilar ligands) generally mixes the d and p-orbitals of the transition metal so that the transitions are no longer purely d-d in nature.
Schrodinger Wave Equation for Hydrogen Atom: Separation …
www.dalalinstitute.comSchrodinger Wave Equation for Hydrogen Atom: Separation of Variable in Polar Spherical Coordinates and Its Solution In the first section of this chapter, we derived and discussed the Schrodinger wave equation for a particle in a three-dimensional box. In this section, we will apply the procedure to an electron that exits around the nucleus.
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