Methyl Iodide MATERIAL SAFETY DATA SHEET CAS No 74-88 …

1 SECTION 1: Identification of the substance/mixture and of the identifiersProduct name: Methyl IodideCAS-No. identifieduses of the substance or mixture and uses advised againstIdentified uses:Laboratorychemicals, Industrial & for professional use of the supplier of the SAFETY data sheetCompany:Central Drug House (P) Ltd7/28 Vardaan HouseNew Delhi-10002 INDIAT elephone:+91 11 49404040(9:00am-6:00 pm) [Office hours]SECTION 2: Hazards of the substance or mixtureClassification according to Regulation (EC) No 1272/2008 Carcinogenicity (Category 2), H351 Acute toxicity, Dermal (Category 4), H312 Acute toxicity, Inhalation (Category 3), H331 Acute toxicity, Oral (Category 3), H301 Specific target organ toxicity-single exposure (Category 3), H335 Skin irritation (Category 2), H315 For the full text of the H-Statements mentioned in thisSection, see Section elementsLabelling according Regulation (EC) No 1272/2008 PictogramSignal wordDangerPage 1 of 7 Methyl IodideCAS No74-88-4 MATERIAL SAFETY DATA SHEETSDS/MSDSH azard statement(s)H301 Toxic if in contact with skin if cause respiratory of causing statement(s)P261 Avoid breathing protective gloves/ protective + P310IF SWALLOWED.

2 Immediately call a POISON CENTER or a POISON CENTER or doctor/ hazardsVesicant., Rapidly absorbed through 3:Composition/information on : Methyl iodideFormula:CH3 IMolecular weight:141,94 g/molCAS-No.: 74-88 -4EC-No.:200-819-5 Index-No.:602-005-00-9 Hazardous ingredients according to Regulation (EC) No 1272/2008 ComponentClassificationConcentrationMeth yl Tox. 3; Acute Tox. 4;<= 100 % Irrit. 2; Resp. Sens. 1; Sens. 1; Carc. 2; STOTSE 3; H301, H331, H312,H315, H334, H317, H351,H335 For the full text of the H-Statements mentioned in this Section, see Section 4: First aid of first aid measuresGeneral adviceConsult a physician. Show this SAFETY data SHEET to the doctor in inhaledIf breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a case of skin contactWash off with soap and plenty of water.

3 Take victim immediately to hospital. Consult a case of eye contactRinse thoroughly with plenty of water for at least 15 minutes and consult a swallowedNever give anything by mouth to an unconscious person. Rinse mouth with water. Consult a 2 of important symptoms and effects, both acute and delayedThe most important known symptoms and effects are described in the labelling (see section ) and/or insection of any immediate medical attention and special treatment neededNo data availableSECTION 5: Firefighting mediaSuitable extinguishing mediaUse water spray, alcohol-resistant foam, dry chemical or carbon hazards arising from the substance or mixtureCarbon oxides, Hydrogen for firefightersWear self-contained breathing apparatus for firefighting if informationNo data availableSECTION 6: Accidental release precautions, protective equipment and emergency proceduresWear respiratory protection.

4 Avoid breathing vapours, mist or gas. Ensure adequate personnel to safe personal protection see section precautionsPrevent further leakage or spillage if safe todo so. Do not let product enter and materials for containment and cleaning upSoak up with inert absorbent MATERIAL and dispose of as hazardous waste. Keep in suitable, closedcontainers for to other sectionsFor disposal see section 7: Handling and for safe handlingAvoid contact with skin and eyes. Avoid inhalation of vapour or precautions see section for safe storage, including any incompatibilitiesStore in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which areopened must be carefully resealed and kept upright to prevent sensitive. Moisture end use(s)Apart from the uses mentioned in section no other specific uses are stipulatedSECTION 8: Exposure controls/personal parametersComponents with workplace control parametersPage 3 of controlsAppropriate engineering controlsAvoid contact with skin, eyes and clothing.

5 Wash hands before breaks and immediately after handlingthe protective equipmentEye/face protectionTightly fitting SAFETY goggles. Faceshield (8-inch minimum).Use equipment for eye protectiontested and approved under appropriate government standards such as NIOSH (US) or EN166 (EU).Skin protectionHandle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose ofcontaminated gloves after use in accordance with applicable laws and good laboratory and dry ProtectionComplete suit protecting against chemicals, The type of protective equipment must be selectedaccording to the concentration and amount of the dangerous substance at the specific protectionWhere risk assessment shows air-purifying respirators are appropriate use a full-face respiratorwith multi-purpose combination (US) or type AXBEK (EN 14387) respirator cartridges as a backup toengineering controls.

6 If the respirator is the sole means of protection, use a full-face supplied airrespirator. Use respirators and components tested and approved under appropriate governmentstandards such as NIOSH (US) or CEN (EU).Control of environmental exposurePrevent further leakage or spillage if safe to do so. Do not let product enter 9: Physical and chemical on basic physical and chemical propertiesa) AppearanceForm: liquidb) OdourNo data availablec) Odour ThresholdNo data availabled) pHNo data availablee) Melting point/freezingMelting point/range:-64 )Initial boiling point and41-43 Cboiling rangeg) Flash pointNo data availableh) Evaporation rateNo data availablei)Flammability (solid, gas) No data availablePage 4 of 7j)Upper/lowerflammability orexplosive limitsk) Vapour pressurel)Vapour densitym) Relative densityn) Water solubilityo) Partition coefficient: n-octanol/waterp) Auto-ignitiontemperatureq) Decompositiontemperaturer)Viscositys) Explosive propertiest)Oxidizing SAFETY informationRelative vapour densityUpper explosionlimit: 66 %(V)Lower explosion limit.

7 8,5 %(V)544 hPa at 20 hPa at 55 C4,90-(Air = )2,28 g/cm3 at 25 C14 g/l at 20 Clog Pow: 1,5 at 20 CNo data availableNo data availableNo data availableNo data availableNo data available4,90-(Air = )SECTION 10: Stability and ReactivityNo data stabilityStable under recommended storage the following stabiliser(s):Silver ( %) Possibility of hazardousreactionsNo data Conditions to avoidNo data Incompatible materialsStrong oxidizing agents, Strong bases, Hazardous decomposition productsOther decomposition products-No data availableIn the event of fire: see section 5 SECTION 11: Toxicological on toxicological effectsAcute toxicityLD50 Oral-Rat-76 mg/kgLC50 Inhalation-Rat-4 mg/m3LD50 Dermal-Guinea pig-800 mg/kgSkin corrosion/irritationSkin-RabbitResult: Causes severe burns.(Draize Test)Page 5 of 7 Serious eye damage/eye irritationEyes-RabbitResult: Risk of serious damage to eyes.

8 (Draize Test)Respiratory or skin sensitisationGerm cell mutagenicityNo data availableCarcinogenicityThis product is or contains a component that has been reported to be possibly carcinogenic based on itsIARC, ACGIH, NTP, or EPA evidence of carcinogenicity in animal studiesIARC:3-Group3: Not classifiable as to its carcinogenicity to humans ( Methyl Iodide )Reproductive toxicityNo data availableSpecific target organ toxicity-single exposureMay cause respiratory target organ toxicity-repeated exposureNodata availableAspiration hazardNo data availableAdditional InformationRTECS: Not availableNausea, Dizziness, Headache, Blurred vision, Weakness, Drowsiness, Ataxia., Confusion., Convulsions,narcosis, Pulmonary edema. Effects may be 12: Ecological data and degradabilityBiodegradabilityaerobic-Exp osure time 28 dResult: 16 %-Not readily biodegradable.

9 (Closed Bottle test) potentialNo data Mobility in soilNo data of PBT and vPvB assessmentPBT/vPvB assessment not available as chemical SAFETY assessment not required/not adverse effectsNo data availableSECTION 13: Disposal Waste treatment methodsProductOffer surplus and non-recyclable solutions to a licensed disposal 6 of 7 Contaminated packagingDispose of as unused 14: Transport UN numberADR/RID: 2644 IMDG: 2644 IATA: UN proper shipping nameADR/RID: Methyl IODIDEIMDG: Methyl IODIDEIATA: Methyl iodidePassenger Aircraft: Not permitted for transportCargo Aircraft: Not permitted for hazard class(es)ADR/RID: : : Packaging groupADR/RID: IIMDG: Environmental hazardsADR/RID: noIMDG Marine pollutant: noIATA: Special precautions for userNo data availableSECTION15: Regulatory informationThis SAFETY datasheet complies with the requirements of Regulation (EC) No.

10 453 , health and environmental regulations/legislation specific for the substance or SAFETY AssessmentFor this product a chemical SAFETY assessment was not carried outSECTION 16: Other informationFull text of H-Statements referred to under sections 2 and if in contact with skin cause an allergic skin if cause allergy or asthma symptoms or breathing difficulties if cause respiratory of causing Drug House (P) LtdanditsAffiliatesshallnotbeheldliablef oranydamageresultingfrom 7 of 7