MSDS - Material Safety Data Sheet - beckmfg.com

1 Page 1 of 7 Form #0321 Friday, June 16, 2006. msds - Material Safety data Sheet Product Name: P-6 PVC Cement PICOMA PRODUCT ID# MVC9922, MVC9923, MVC9924, MVC9925, MVC9941P, MVC9961P, msds No.: 018150 MVC9962, MVC9963, MVC9964, MVC9965. Part Numbers Covered: 018094-12 018169 018187-12 018352-12. 018095-12 018170-12 018188-12 018353-12. 018096-24 018171-12 018190 018390. 018150-24 018172 018191 018391. 018151-24 018173-12 018192 018392. 018152 018174-12 018193-12 018393. 018153-24 018175-12 018194-12 018395. 018157-24 018176 018207 018450-24. 018158 018177-12 018208 018890. 018159 018178-12 018209 018953. 018160-24 018180-12 018253 018954. 018161-24 018181-12 018254 018958. 018163-24 018182-12 018258 018997. 018164-24 018183-12 018259 018998. 018166 018184 018260 018999. 018167-24 018185 018350-24 099983. 018168-12 018186 018351-24. 1. Basic Information: Manufacturer: William H. Harvey Company Address: 4334 South 67th Street 4. City, ST Zip: Omaha, NE 68117-1019.

2 2 0. Emergency Contact: CHEMTREC. Emergency Telephone Number: (800)424-9300. Contact: Information Telephone Number Information Telephone Number: (800)228-9681. 2. Last Update: 04/21/2006 Expiration Date: 4. Chemical State: X Liquid Gas Solid 0. Chemical Type: Pure X Mixture G. 2. Ingredients: Trade Secret EHS IARC SARA. 313 OSHA ACGIH Other CAS No. Chemical Name % Range NTP SUB Z PEL TLV Limits 108-94-1 CYCLOHEXANONE 5 - 15 25 PPM 25 PPM NI. 112945-52-5 FUMED SILICA 1-5 5 mg/m3 3 mg/m3 NI. 78-93-3 METHYL ETHYL KETONE 40 - 50 200 PPM 200 PPM NI. 9002-86-2 PVC RESIN 10 - 20 X X 15 mg/m3 10 mg/m3 NI. 109-99-9 TETRAHYDROFURAN 25 - 35 200 PPM 50 PPM NI. 3. Hazardous Identification: Hazard Category: X Acute X Chronic X Fire Pressure Reactive 7/14/06. Revision 1. Page 2 of 7 Friday, June 16, 2006. msds - Material Safety data Sheet Product Name: P-6 PVC Cement msds No.: 018150. Hazardous Identification Information: HAZARDS OVERVIEW: Clear to slightly cloudy liquid with a distinct and penetrating odor.

3 Extremely flammable liquid and vapor. Vapors may cause flash fire. May cause eye and skin irritation. Inhalation of vaors or mists may cause respiratory irritation and central nervous system effects. Ingestion may cause irritation, nausea, vomiting, diarrhea and kidney and liver disorders. May be fatal if swallowed. Aspiration hazard. Symptoms may be delayed. 4. First Aid Measures: Route(s) of Entry: EYES: Liquid causes severe irritation. Vapors cause slight to moderate irritation. SKIN: Liquid or vapors may cause severe irritation. INHALATION: May cause nose and throat irritation, headache, nausea, vomiting, drowsiness and incoordination. INGESTION: Swallowing may cause irritation, nausea, vomiting, diarrhea and kidney and liver disorders. May be fatal if swallowed. TARGET ORGANS: Eyes, Skin, Lungs, Kidney, Liver, Central Nervous System. Health Hazards (Acute and Chronic): ACUTE: Severe skin irritant. Fast skin penetrant. Not expected to be a sensitizer.

4 Eye irritant. Inhalation hazard. Overexposure may cause coughing, shortness of breath, dizziness, vomiting, central nervous system depression, intoxication, and collapse. Ingestion hazard. May produce symptoms of nervous system depression including headache, dizziness, nausea, loss of sense of balance, drowsiness, and visual disturbances. CHRONIC: Prolonged or repeated eye contact may cause conjunctivitis. Prolonged or repeated skin contact may cause defatting and dermatitis. May cause liver and kidney damage. May cause reproductive and fetal effects May cause lung damage. Narcotic in high concentrations. Signs and Symptoms: See HEALTH HAZARDS above. Medical Conditions Generally Aggravated by Exposure: AGGRAVATION OF EXISTING CONDITIONS: Persons with pre-existing skin disorders or eye problems or impaired liver or kidney function may be more susceptible to the effects of the substance. Emergency and First Aid Procedures: Page 3 of 7 Friday, June 16, 2006.

5 msds - Material Safety data Sheet Product Name: P-6 PVC Cement msds No.: 018150. FOR EMERGENCY FIRST AID HELP CALL 1-303-623-5716 COLLECT. SKIN CONTACT: Immediately wash skin with soap and water while removing contaminated clothing and shoes. Remove dried cement with HARVEY'S POWER SCRUB HAND CLEANER or baby oil. Launder clothing before reuse. Seek medical attention if irritation persists. EYES: Liquid: Immediately flush with plenty of water for 5 minutes. Remove contacts if present and continue flushing with water while holding eyelids open with thumb and index finger for 15 minutes. Seek medical attention if irritation develops or persists. Vapors: If vapors cause irritation, move to fresh air and flush eyes as above. Seek medical attention if irritation develops or persists. INHALATION: Move to fresh air. Give oxygen if breathing is difficult. Give artificial respiration if required. Call a physician or poison control center (1-303-623-576 collect) immediately.

6 INGESTION: DO NOT INDUCE VOMITING. Rinse mouth with water. Never give anything by mouth to a person who is unconscious or drowsy. Get immediate medical attention by calling a Poison Control Center (1-303-623-5716 Collect), or hospital emergency room. If medical advice cannot be obtained, then take the person and product to the nearest medical emergency treatment center or hospital. Other Health Warnings: NI. 5. Fire Fighting Measures: Flash Point: 0 - 6 F Lower Explosive Limit: %by vol. Upper Explosive Limit: %by vol Method: TCC. Fire Extinguishing Media: Use dry chemical, CO2, or foam to extinguish fire. Cool fire exposed container with water. Water may be ineffective as an extinguishing agent. Special Fire Fighting Procedures: Firefighters should wear positive pressure self contained breathing apparatus and full protective clothing for fires in areas where chemicals are used or stored. Unusual Fire and Explosion: Extremely flammable liquid. Keep away from heat and all sources of ignition including sparks, flames, lighted cigarettes and pilot lights.

7 Containers may rupture or explode in the heat of a fire. Vapors are heavier than air and may travel to a remote ingition source and flash back. This product contains tetrahydrofuran that may form explosive organic peroxides when exposed to air or light or with age. Combustion will produce toxic and irritating vapors including carbon monoxide and carbon dioxide. 6. Accidental Release Measures: Steps to be Taken in Case Material is Released or Spilled: Remove all sources of ignition and ventilate area. Stop leak if it can be done without risk. Prevent liquid from entering watercourses, natural waterways, drainage collection areas or sewers. Personnel cleaning up the spill should wear appropriate personal protective equipment, including respirators if vapor concentrations are high. Soak up spill with an iner absorbent such as sand, earth or other non-combusting Material . Put spent absorbent Material in covered, labeled metal containers. See Section 13 for disposal information.

8 Report releases to proper authorities as required. 7. Handling and Storage: Precautions to be Taken: Page 4 of 7 Friday, June 16, 2006. msds - Material Safety data Sheet Product Name: P-6 PVC Cement msds No.: 018150. HANDLING: Avoid contact with eyes, skin and clothing. Avoid breathing vapors or mists. Use with adequate ventilation (equivalent to outdoors). Wash thoroughly after handling. do not eat, drink or smoke in the work area. Keep product away from heat, sparks, flames and all other sources of ignition. No smoking in use or storage areas. Keep containers closed when not in use. STORAGE: Store in a cool, dry, well ventilated area away from incompatable materials. Keep containers closed when not in use. Other Precautions: "Empty" containers can retain product residue and can be hazardous. Follow all msds precations in handling empty containers. Do not cut or weld on or near empty or full containers. Prevent prolonged or repeated breathing of vapors released during application process.

9 Reports have associated repeated and prolonged overexposure to solvents with permanent brain damage and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. 8. Exposure Controls/Personal Protection: Ventilation Requirements: GENERAL MECHANICAL: Exhaust ventilation capable of maintaining emissions at the point of use below OSHA PEL. LOCAL EXHAUST: Open doors & windows. If used in an enclosed area, use exhaust fans. Exhaust fans should be explosion-proof or set up in a way that flammable concentrations of vapors are not exposed to electrical fixtures or hot surfaces. Personal Protective Equipment: RESPIRATORY PROTECTION: For operations where the exposure limits may be exceeded, a NIOSH approved organic vapor respirator or supplied air respirator is recommended. Equipment selection depends on the contaminant type and concentration. Select in accordance with 29 CFR. and good industrial hygiene practice.

10 For firefighting, use self-contained breathing apparatus. EYE PROTECTION: Safety glasses with side shields or Safety goggles. SKIN PROTECTION: Rubber gloves are adequate for normal use of the product. For long exposures to the substance, chemical resistant gloves may be required to avoid prolonged exposure. OTHER PROTECTION: An eye wash and Safety shower should be available in the work area. 9. Physical and Chemical Properties: Boiling Point: 155 F Melting Point: NA. Evaporation Rate (Butyl Acetate = 1): - Vapor Pressure (mm Hg.): ~ 157. Specific Gravity (H20 = 1): Vapor Density (AIR = 1): ~ Solubility In Water: Negligible Appearance and Odor: Clear to slightly cloudy liquid with Ether-like odor Other Information: Specific Gravity = ~.912. 10. Stability and Reactivity: Stability: Stable. Incompatibility (Materials to Avoid): Page 5 of 7 Friday, June 16, 2006. msds - Material Safety data Sheet Product Name: P-6 PVC Cement msds No.: 018150. Oxidizing agents, alkalis, amines, ammonia, acids, chlorine compounds, chlorinated inorganics (potassium, calcium and sodium hypochlorite) and hydrogen peroxides.