n-Heptane (Pure Grade)

1 safety DATA SHEET n- heptane (Pure Grade) Version Revision Date 2016-01-21 SDS Number:100000067062 1/13 SECTION 1: Identification of the substance/mixture and of the company/undertaking Product information Product Name : n- heptane (Pure Grade) Material : 1099971, 1016082, 1099970, 1084145, 1061726, 1021845, 1028621, 1021842, 1021844, 1028384, 1028355, 1021843, 10455211 Company : Chevron Phillips Chemical Company LP Specialty Chemicals 10001 Six Pines Drive The Woodlands, TX 77380 Emergency telephone: Health: (North America) (International) Transport: CHEMTREC or (int'l) Asia: +800 CHEMCALL (+800 2436 2255) China:+86-21-22157316 EUROPE: BIG + (phone) or + (telefax) South America SOS-Cotec Inside Brazil: Outside Brazil: + Responsible Department : Product safety and Toxicology Group E-mail address : Website : SECTION 2: Hazards identification Classification of the substance or mixture This product has been classified in accordance with the hazard communication standard 29 CFR ; the SDS and labels contain all the information as required by the standard.

2 Emergency Overview Danger Form: Liquid Physical state: Liquid Color: Clear Odor: Sweet OSHA Hazards : Flammable Liquid, Moderate skin irritant, Aspiration hazard, Specific target organ systemic toxicity - single exposure Classification safety DATA SHEET n- heptane (Pure Grade) Version Revision Date 2016-01-21 SDS Number:100000067062 2/13 : Flammable liquids , Category 2 Skin irritation , Category 2 Specific target organ systemic toxicity - single exposure , Category 3 , Central nervous system Aspiration hazard , Category 1 Labeling Symbol(s) : Signal Word : Danger Hazard Statements : H225: Highly flammable liquid and vapor.

3 H304: May be fatal if swallowed and enters airways. H315: Causes skin irritation. H336: May cause drowsiness or dizziness. Precautionary Statements : Prevention: P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P261 Avoid breathing dust/fume/gas/mist/vapors/spray. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/ eye protection/ face protection.

4 Response: P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P312 Call a POISON CENTER or doctor/ physician if you feel unwell. P332 + P313 If skin irritation occurs: Get medical advice/ attention. P362 Take off contaminated clothing and wash before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. Storage: P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place.

5 Keep cool. P405 Store locked up. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Carcinogenicity: safety DATA SHEET n- heptane (Pure Grade) Version Revision Date 2016-01-21 SDS Number:100000067062 3/13 IARC No ingredient of this product present at levels greater than or equal to is identified as probable, possible or confirmed human carcinogen by IARC. NTP No ingredient of this product present at levels greater than or equal to is identified as a known or anticipated carcinogen by NTP. ACGIH No ingredient of this product present at levels greater than or equal to is identified as a carcinogen or potential carcinogen by ACGIH.

6 SECTION 3: Composition/information on ingredients Synonyms : Normal heptane Dipropilmetano n- heptane , 99% Molecular formula : C7H16 Component CAS-No. Weight % n- heptane 142-82-5 100 SECTION 4: First aid measures General advice : Move out of dangerous area. Show this material safety data sheet to the doctor in attendance. Symptoms of poisoning may appear several hours later. Do not leave the victim unattended. If inhaled : Move to fresh air. If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician. In case of skin contact : If skin irritation persists, call a physician. If on skin, rinse well with water.

7 If on clothes, remove clothes. In case of eye contact : Immediately flush eye(s) with plenty of water. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If swallowed : Keep respiratory tract clear. Do NOT induce vomiting. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. Take victim immediately to hospital. SECTION 5: Firefighting measures Flash point : -4 C (25 F) Method: Tag closed cup Autoignition temperature : C ( F) Suitable extinguishing media : Dry chemical. Carbon dioxide (CO2). Alcohol-resistant foam.

8 safety DATA SHEET n- heptane (Pure Grade) Version Revision Date 2016-01-21 SDS Number:100000067062 4/13 Unsuitable extinguishing media : High volume water jet. Specific hazards during fire fighting : Do not allow run-off from fire fighting to enter drains or water courses. Special protective equipment for fire-fighters : Wear self-contained breathing apparatus for firefighting if necessary. Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. For safety reasons in case of fire, cans should be stored separately in closed containments.

9 Use a water spray to cool fully closed containers. Fire and explosion protection : Do not spray on an open flame or any other incandescent material. Use only explosion-proof equipment. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapors). Keep away from open flames, hot surfaces and sources of ignition. Hazardous decomposition products : Carbon oxides. SECTION 6: Accidental release measures Personal precautions : Use personal protective equipment. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapors accumulating to form explosive concentrations.

10 Vapors can accumulate in low areas. Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Methods for cleaning up : Contain spillage, and then collect with non-combustible absorbent material, ( sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). SECTION 7: Handling and storage Handling Advice on safe handling : Avoid formation of aerosol. Do not breathe vapors/dust. Avoid exposure - obtain special instructions before use.