Pacific Scientific Energetic Materials Co ...

1 Pacific Scientific Energetic Materials Co.< < < < < MATERIAL SAFETY DATA SHEET > > > > > product AND COMPANY IDENTIFICATIONPRODUCT name :FIREX CARTRIDGE ASSEMBLYTRADE name (S) / SYNONYM(S):UH-1N fire extinguisher cartridge;UH-1H electric squib assemblyNATIONAL STOCK NUMBER (NSN):1377-00-918-8533 product NUMBER(S):13083-5 MSDS NUMBER / SPECIFYING LETTER:00015 A (CIVILIAN VERSION - UN0323, )REVISION DATE:9 March 2000 SHIPPING REFERENCE NUMBER:US DOT Competent Authority: EX-8611120 MANUFACTURER: TELEPHONE NUMBERS:Danaher Corporation -(520) 796-1100 [6am-4pm MST] Pacific Scientific Energetic Materials Co.(520) 796-2024 FAX7073 West Willis Road, #5002(800) 535-5053 Infotrac [24-hr]Chandler, Arizona 85226-5111 [website - ] / INFORMATION ON INGREDIENTSHAZARDOUS INGREDIENTS(* - below required reporting levels per OSHA, 29 CFR )COMPONENT name / CAS NUMBER:cyclonite (RDX) / 121-82-4 WEIGHT PERCENTAGE:< 1 %*COMPONENT name / CAS NUMBER:zirconium, metal powder / 7440-67-7 WEIGHT PERCENTAGE:< 1 %*COMPONENT name / CAS NUMBER:potassium nitrate [KNO3] / 7757-79-1 WEIGHT PERCENTAGE:< 1 %*COMPONENT name / CAS NUMBER:silicon, amorphous powder / 7440-21-3 WEIGHT PERCENTAGE:< %*COMPONENT name / CAS NUMBER:boron, amorphous powder / 7440-42-8 WEIGHT PERCENTAGE:< %*COMPONENT name / CAS NUMBER:potassium perchlorate (KP) / 7778-74-7 WEIGHT PERCENTAGE:< %*COMPONENT name / CAS NUMBER:(red) ironIII oxide [Fe2O3] / 1309-37-1 WEIGHT PERCENTAGE:< %*COMPONENT name / CAS NUMBER:diatomaceous earth / 68855-54-9 WEIGHT PERCENTAGE.

2 < %*NET EXPLOSIVE WEIGHT (NEW):200 mgPacific Scientific Energetic Materials Co.< < < < < MATERIAL SAFETY DATA SHEET > > > > > product :fire extinguisher cartridgeMSDS NUMBER:00015 PAGE 2 OF 9 REVISION: 9 March IDENTIFICATIONEMERGENCY OVERVIEWWARNING: Explosive product ! Do not attempt to manually fight fires. Productmay be sensitive to shock, impact, friction, electrostatic discharge, high pressure orhigh temperature. product may ignite and explode if exposed to any of theseconditions, releasing toxic fumes, heat, shock waves and container HEALTH EFFECTS (ACUTE AND CHRONIC)EYES: The product is sealed preventing exposure to the hazardous ingredientsinside. If product seal ruptures exposing hazardous ingredients inside, discard productavoiding contact with the eyes. Exposure to ignition products may cause eye : The product is sealed preventing exposure to the hazardous ingredients inside. If product seal ruptures, discard product avoiding contact with the skin.

3 Poses little orno immediate hazard. Exposure to ignition products may cause skin : The product is sealed preventing exposure to the hazardousingredients inside. Exposure to ignition products may cause respiratory irritation. Ignition products will contain boron, zirconium and iron compounds, plus nitrogenoxides and potassium chloride : Not a hazard in normal industrial use. If product seal ruptures, discardproduct using proper protection. Some ingredients are highly poisonous by CONDITIONS AGGRAVATED BY EXPOSURE: Pre-existing pulmonary diseasessuch as emphysema, asthma, etc. may be aggravated by overexposure to ignition (CANCER) LISTING STATUSOSHA, NTP and NIOSH: Neither the product nor any components listedIARC:3 - Human Limited Evidence (ironIII oxide)AGCIH:A4 - Inadequate Evidence (ironIII oxide, cyclonite)REFER TO SECTION 11, TOXICOLOGICAL INFORMATION, FOR ADDITIONAL AID MEASURESEYES: If exposed to container fragmentation, bandage eyes and transport.

4 If exposed toignition products, remove contact lenses immediately, flush with water for at least 15minutes, occasionally lifting upper and lower eyelids. Seek medical attention if : Wash off any residue with soap and warm water. Seek medical attention if : Remove to fresh air. If breathing has stopped, give artificial respiration. Ifbreathing is difficult, administer oxygen. Seek immediate medical : Seek immediate medical TO PHYSICIAN: Supportive care. product ignition produces small quantities ofboron, zirconium and iron compounds, plus nitrogen oxides and potassium chloride dust. Treatment based on judgement of the physician in response to reactions of the Scientific Energetic Materials Co.< < < < < MATERIAL SAFETY DATA SHEET > > > > > product :fire extinguisher cartridgeMSDS NUMBER:00015 PAGE 3 OF 9 REVISION: 9 March FIGHTING MEASURESFLAMMABLE PROPERTIESFLASH POINT:not applicableMETHOD USED:not applicableLOWER FLAMMABLE LIMIT:self-oxidizingUPPER FLAMMABLE LIMIT:self-oxidizingAUTOIGNITION TEMPERATURE:> 400 F (> 205 C) [RDX]FIRE AND EXPLOSION HAZARD: WARNING - Explosive product !

5 product may besensitive to shock, impact, friction, electrostatic discharge, high pressure or high temperature. Must not be confined if burning. product may deflagrate or detonate if exposed releasingtoxic fumes, heat, shock waves and container MEDIA: Permanently-installed, automatic water sprinkler / deluge systemis FIGHTING INSTRUCTIONS: Do not attempt to manually fight fires. In case of fire,personnel should immediately evacuate the area, using as much protective cover as possibleand activate deluge and alarm COMBUSTION PRODUCTS: Extreme heat and toxic gases containing boron,zirconium and iron compounds, plus nitrogen oxides and potassium chloride dust may beemitted during RELEASE MEASURESSMALL SPILL: If product seal ruptures, barricade area, eliminate ignition sources, use asoft bristle brush and a conductive rubber pan or rubber shovel to clean-up spills. Useconductive containers and ground all containers when transferring the spilled material.

6 Referto Section 9 for the proper desensitizing agent to wet and desensitize the spilled SPILLSOIL SPILL: Remove all contaminated soil to dispose of as hazardous RELEASE: Not applicableWATER SPILL: Flush with copious amounts of water. Collect water to dispose of ashazardous SPILL: If product seal ruptures, barricade area and eliminate ignitionsources. Refer to SMALL SPILL AND STORAGEHANDLING: Handling and use of explosives and related dangerous Materials must belimited to personnel who are specifically authorized and trained in this area. Refer to theDepartment of Defense (DOD) Contractors Safety Manual number , includingsources listed within, and any other appropriate information for detailed instructions regardingproper handling, storage, use and disposal of explosives and related dangerous Scientific Energetic Materials Co.< < < < < MATERIAL SAFETY DATA SHEET > > > > > product :fire extinguisher cartridgeMSDS NUMBER:00015 PAGE 4 OF 9 REVISION: 9 March 2000 STORAGE: Store in approved storage magazines only.

7 Storage and handling must conformto appropriate quantity / distance requirements, barricading, grounding and personnelmaterial limits. Keep product cool and dry in CONTROLS/PERSONAL PROTECTIONPERSONAL PROTECTIVE EQUIPMENT (PPE)EYE PROTECTION: Industrial safety glasses or goggles must be worn whenhandling any type of explosive PROTECTIONGLOVES: Impervious, static-dissipative gloves are recommended whenexposure to hazardous ingredients or ignition products is : High cotton-content clothing and underclothing, as well asconductive shoes or legstat(s), wristat(s) and a static-dissipative coat, arerecommended to avoid static electricity WASH FACILITY: Eye washing capability is PROTECTION: Appropriate NIOSH / MSHA-approved respiratoryprotection is recommended if exposed to particulate matter, and, for protection againsttoxic gaseous ignition products, but should not be necessary with normal handling. OTHER PROTECTION: None indicatedENGINEERING CONTROLS: Effective shielding is recommended for personnel whenhandling these devices.

8 Humidity control ( higher relative humidity, > 60% asrecommended by DOD) reduces or prevents static electricity build-up. Explosion-proofequipment is required when operating with exposed explosive : Not : Explosion-proof electrical is required, where : General-coverage, moderate-flow, is recommended for particulateand ignition product GUIDELINES:COMPONENT: cyclonite (cyclotrimethylenetrinitramine, RDX)OSHA TWA:not foundOSHA STEL:not foundACGIH mg/m3 (skin)ACGIH STEL:not foundOTHER:NIOSH-TWA: mg/m3 NIOSH-STEL: 3 mg/m3 (skin) Pacific Scientific Energetic Materials Co.< < < < < MATERIAL SAFETY DATA SHEET > > > > > product :fire extinguisher cartridgeMSDS NUMBER:00015 PAGE 5 OF 9 REVISION: 9 March 2000 COMPONENT: zirconium, metal powder [Zr]OSHA TWA:5 mg/m3 OSHA STEL:not foundACGIH TWA:5 mg/m3 (as zirconium, Zr)ACGIH STEL:10 mg/m3 (as zirconium, Zr)OTHER:NIOSH-TWA: 5 mg/m3 NIOSH-STEL: 10 mg/m3 IDLH: 50 mg/m3 (as zirconium, Zr)COMPONENT:diatomaceous earthOSHA mg/m3 (based on % silica)OSHA STEL:not foundACGIH TWA:10 mg/m3 [inhalable particulate], 3 mg/m3 [repirable particulate] (PNOC)ACGIH STEL:not foundOTHER:NIOSH-TWA: 6 mg/m3 (as silica, amorphous)IDLH: 3000 mg/m3 COMPONENT:(red) ironIII oxide [Fe2O3]OSHA TWA:10 mg/m3 (as iron, Fe, dust & fume)OSHA STEL:not foundACGIH TWA:5 mg/m3 (as iron, Fe, dust & fume)ACGIH STEL:not foundOTHER:NIOSH-TWA: 5 mg/m3 (as iron, Fe, dust & fume)IDLH: 2500 mg/m3 (as iron, Fe, dust & fume)COMPONENT:silicon, amorphous powder [Si]OSHA TWA.

9 15 mg/m3 [total dust] 5 mg/m3 [respirable fraction]OSHA STEL:not foundACGIH TWA:10 mg/m3 ACGIH STEL:not foundOTHER:NIOSH-TWA: 10 mg/m3 [total dust], 5 mg/m3 [respirable dust fraction] Pacific Scientific Energetic Materials Co.< < < < < MATERIAL SAFETY DATA SHEET > > > > > product :fire extinguisher cartridgeMSDS NUMBER:00015 PAGE 6 OF 9 REVISION: 9 March 2000 COMPONENTS:potassium nitrate [KNO3]boron, amorphous powder [B]potassium perchlorate [KClO4]OSHA TWA:15 mg/m3 [total dust], 5 mg/m3 [respirable fraction] (PNOR)OSHA STEL:not foundACGIH TWA:10 mg/m3 [inhalable particulate], 3 mg/m3 [respirable particulate] (PNOC)ACGIH STEL:not foundOTHER:none AND CHEMICAL PROPERTIESAPPEARANCE:metallic ordnance hardwareODOR:odorlessPHYSICAL STATE:solidpH @ 25 C:not determinedVAPOR PRESSURE:not applicable, sealed productVAPOR DENSITY:not applicable, sealed productBOILING POINT:not applicableMELTING POINT:not applicableSOLUBILITY IN H2O:negligibleSPECIFIC GRAVITY (H2O=1):greater than 1 BULK DENSITY:greater than 1.

10 Identical to specific gravityCHEMICAL FAMILY:not applicableMOLECULAR WEIGHT:not applicableMOLECULAR FORMULA:not applicableVISCOSITY:not applicableEVAPORATION RATE:not applicable, sealed productDECOMPOSITION TEMP:> 400 F (> 205 C) by auto-ignition [RDX]DESENSITIZING AGENT:CAUTION: The product may only be desensitized if largevolumes of water or mineral oil come in contact with theexplosive components inside. Sealed units should beshunted and disposed of in accordance with Section AND REACTIVITYCHEMICAL STABILITY: This explosive product is stable if handled properly. Avoidconditions listed TO AVOID: Shock, impact, friction, electrostatic discharge, high pressure,high temperature, open flame and chemical or physical Scientific Energetic Materials Co.< < < < < MATERIAL SAFETY DATA SHEET > > > > > product :fire extinguisher cartridgeMSDS NUMBER:00015 PAGE 7 OF 9 REVISION: 9 March 2000 INCOMPATIBILITY WITH OTHER Materials : The product is sealed preventing exposureto the hazardous ingredients inside.