Page 1/10 Material Safety Data Sheet acc. to …

1 Page 1/10 Material Safety data Sheetacc. to ISO/DIS 11014 Printing date 06/02/2005 Reviewed on 09/16/2004DR1 Identification of substance Product details Trade name: 39683 self etching primer Gray Article number:39683 Manufacturer/Supplier:SEM Products, Michael Wylie , NC 28217 USA(704)522-1006 Information department:24HR EMERGENCY CHEMTREC 800-424-93002 Composition/ data on components Chemical characterization Description:Mixture of the substances listed below with nonhazardous additions. Dangerous components:68476-86-8 Petroleum gases, liquefied, sweetened25-50%67-64-1 acetone10-25%110-19-0 isobutyl ethyl MODIFIED ROSIN CELLULOSE Solvent naphtha (petroleum), heavy n-butyl acetate propan-2-ol Quartz (SiO2) xylene Talc (Mg3H2(SiO3)4) tris(methylphenyl) phosphate dibutyl phthalate Hazards identification Hazard description:ToxicExtremely flammable Information pertaining to particular dangers for man and environment:The product has to be labelled due to the calculation procedure of international !

2 Pressurized cause cancer by cause harm to the unborn to eyes.(Contd. on page 2) USAPage 2/10 Material Safety data Sheetacc. to ISO/DIS 11014 Printing date 06/02/2005 Reviewed on 09/16/2004 Trade name: 39683 self etching primer Gray(Contd. of page 1)DRHarmful: possible risk of irreversible effects through inhalation, in contact with skin and if risk of harm to the unborn container: protect from sunlight and do not expose to temperatures exceeding 50 C, electriclights. Do not pierce or burn, even after % by mass of the contents are flammableKeep out of the reach of children. Classification system:The classification was made according to the latest editions of international substances lists, and expanded uponfrom company and literature data .

3 NFPA ratings (scale 0 - 4)240 Health = 2 Fire = 4 Reactivity = 0 HMIS-ratings (scale 0 - 4) HEALTH FIRE REACTIVITY*240 Health = *2 Fire = 4 Reactivity = 04 First aid measures After inhalation:Supply fresh air; consult doctor in case of complaints. After skin contact:Immediately rinse with water. After eye contact:Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. After swallowing:If symptoms persist consult Fire fighting measures Suitable extinguishing agents:CO2, sand, extinguishing powder. Do not use water. For Safety reasons unsuitable extinguishing agents:Water with full jet Protective equipment:Wear self -contained respiatory protective Accidental release measures Person-related Safety precautions:Wear protective equipment.

4 Keep unprotected persons away. Measures for environmental protection:Do not allow product to reach sewage system or any water respective authorities in case of seepage into water course or sewage not allow to enter sewers/ surface or ground water. Measures for cleaning/collecting:Dispose contaminated Material as waste according to item adequate not flush with water or aqueous cleansing agents USA(Contd. on page 3)Page 3/10 Material Safety data Sheetacc. to ISO/DIS 11014 Printing date 06/02/2005 Reviewed on 09/16/2004 Trade name: 39683 self etching primer Gray(Contd. of page 2)DR7 Handling and storage Handling: Information for safe handling:Ensure good ventilation/exhaustion at the and handle receptacle with care. Information about protection against explosions and fires:Do not spray on a naked flame or any incandescent ignition sources away - Do not against electrostatic respiratory protective device container: protect from sunlight and do not expose to temperatures exceeding 50 C, electriclights.

5 Do not pierce or burn, even after use. Storage: Requirements to be met by storerooms and receptacles:Store in a cool official regulations on storing packagings with pressurized containers. Information about storage in one common storage facility:Store away from oxidizing agents. Further information about storage conditions:Keep receptacle tightly not gas tight seal in cool, dry conditions in well sealed from heat and direct Exposure controls and personal protection Additional information about design of technical systems:No further data ; see item 7. Components with limit values that require monitoring at the workplace:68476-86-8 Petroleum gases, liquefied, sweetenedTLV Short-term value: 2950 mg/m , 1000 ppm67-64-1 acetonePELRELTLV2400 mg/m , 1000 ppm590 mg/m , 250 ppmShort-term value: 1782 mg/m , 750 ppmLong-term value: 1188 mg/m , 500 ppmBEI110-19-0 isobutyl acetatePELRELTLV700 mg/m , 150 ppm700 mg/m , 150 ppm713 mg/m , 150 ppm108-88-3 toluenePELRELTLVS hort-term value: C 300; 500* ppmLong-term value: 200 ppm*10-min peak per 8-hr shiftShort-term value: 560 mg/m , 150 ppmLong-term value: 375 mg/m , 100 ppm188 mg/m , 50 ppmSkin; BEI(Contd.)

6 On page 4) USAPage 4/10 Material Safety data Sheetacc. to ISO/DIS 11014 Printing date 06/02/2005 Reviewed on 09/16/2004 Trade name: 39683 self etching primer Gray(Contd. of page 3)DR141-78-6 ethyl acetatePELRELTLV1400 mg/m , 400 ppm1400 mg/m , 400 ppm1440 mg/m , 400 ppm78-93-3 butanonePELRELTLV590 mg/m , 200 ppmShort-term value: 885 mg/m , 300 ppmLong-term value: 590 mg/m , 200 ppmShort-term value: 885 mg/m , 300 ppmLong-term value: 590 mg/m , 200 ppmBEI123-86-4 n-butyl acetatePELRELTLV710 mg/m , 150 ppmShort-term value: 950 mg/m , 200 ppmLong-term value: 710 mg/m , 150 ppmShort-term value: 950 mg/m , 200 ppmLong-term value: 713 mg/m , 150 ppm67-63-0 propan-2-olPELRELTLV980 mg/m , 400 ppmShort-term value: 1225 mg/m , 500 ppmLong-term value: 980 mg/m , 400 ppmShort-term value: 984 mg/m , 400 ppmLong-term value.

7 492 mg/m , 200 ppm14808-60-7 Quartz (SiO2) * mg/m *Respirable dust( R) mg/m R1330-20-7 xylenePELRELTLV435 mg/m , 100 ppmShort-term value: 655 mg/m , 150 ppmLong-term value: 435 mg/m , 100 ppm(o-, m-, & p-isomers)Short-term value: 651 mg/m , 150 ppmLong-term value: 434 mg/m , 100 ppmBEI84-74-2 dibutyl phthalatePELRELTLV5 mg/m 5 mg/m 5 mg/m Additional information:The lists that were valid during the creation were used as basis. Personal protective equipment: General protective and hygienic measures:Keep away from foodstuffs, beverages and remove all soiled and contaminated hands before breaks and at the end of protective clothing contact with the contact with the eyes and skin.(Contd. on page 5) USAPage 5/10 Material Safety data Sheetacc.

8 To ISO/DIS 11014 Printing date 06/02/2005 Reviewed on 09/16/2004 Trade name: 39683 self etching primer Gray(Contd. of page 4)DR Breathing equipment:In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure userespiratory protective device that is independent of circulating air. Protection of hands:Protective glovesThe glove Material has to be impermeable and resistant to the product/ the substance/ the to missing tests no recommendation to the glove Material can be given for the product/ the preparation/ thechemical of the glove Material on consideration of the penetration times, rates of diffusion and the degradation Material of glovesThe selection of the suitable gloves does not only depend on the Material , but also on further marks of quality andvaries from manufacturer to manufacturer.

9 As the product is a preparation of several substances, the resistanceof the glove Material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove materialThe exact break trough time has to be found out by the manufacturer of the protective gloves and has to beobserved. Eye protection:Tightly sealed goggles9 Physical and chemical properties General InformationForm:AerosolColor:According to product specificationOdor:Characteristic Change in conditionMelting point/Melting point/Boiling range:< -17 C (< 1 F) Flash point:< -17 C (< 1 F) Ignition C (761 F) Auto igniting:Product is not selfigniting. Danger of explosion: Explosion limits: Vol % Vol % Vapor pressure at 20 C (68 F) hPa (175 mm Hg) Density at 20 C (68 F) g/cm Solubility in / Miscibility withWater:Not miscible or difficult to mix.

10 Solvent content:Organic %(Contd. on page 6) USAPage 6/10 Material Safety data Sheetacc. to ISO/DIS 11014 Printing date 06/02/2005 Reviewed on 09/16/2004 Trade name: 39683 self etching primer Gray(Contd. of page 5)DRVOC % g/l / lb/gl Solids %10 Stability and reactivity Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications. Dangerous reactionsNo dangerous reactions known. Dangerous products of decomposition:Carbon monoxide and carbon dioxideNitrogen oxides (NOx)Hydrocarbons11 Toxicological information Acute toxicity: LD/LC50 values that are relevant for classification:108-88-3 tolueneOralLD505000 mg/kg (rat)DermalLD5012124 mg/kg (rabbit)Inhalative LC50/4 h 5320 mg/l (mouse)84-74-2 dibutyl phthalateOralLD508000 mg/kg (rat)DermalLD5020000 mg/kg (rabbit) Primary irritant effect: on the skin:No irritant effect.