Page 1/11 SafetyDataSheet

1 Page1/11 SafetyDataSheetaccordingto1907/2006/EC(R EACH),1272/2008/EC(CLP), Tradename:PentofrostA3 Applicationofthesubstance/thepreparation Coolant/Anti-freeze. Manufacturer/ ,NJ08512(609)578-4100 :ChemTelInc.(800)255-3924,+1(813)248-058 52 Hazardsidentification ClassificationaccordingtoRegulation(EC)N o1272 ClassificationaccordingtoDirective67/548 /EECorDirective1999/45/ECXn;HarmfulR22 ;IrritantR36:Irritatingtoeyes. Informationconcerningparticularhazardsfo rhumanandenvironment:Theproducthastobela belledduetothecalculationprocedureofthe" GeneralClassificationguidelineforprepara tionsoftheEU"inthelatestvalidversion. Classificationsystem:Theclassificationis accordingtothelatesteditionsoftheEU-list s, ,andissupplementedbyinformationfromtechn icalliteratureandbyinformationprovidedby thecompany.

2 LabellingaccordingtoRegulation(EC)No1272 /2008 Theproductisclassifiedandlabelledaccordi ngtotheCLPregulation.( )Page2/11 SafetyDataSheetaccordingto1907/2006/EC(R EACH),1272/2008/EC(CLP), :PentofrostA3( ) HazardpictogramsGHS07 SignalwordWarning Hazard-determiningcomponentsoflabelling: ethanediol2,2'-oxybisethanol PrecautionarystatementsP101 Ifmedicaladviceisneeded, +P351+P338 , +P313 Ifeyeirritationpersists: +P352 Hazarddescription: WHMIS-symbols:D2B-Toxicmaterialcausingot hertoxiceffects NFPA ratings(scale0-4)210 Health=2 Fire=1 Reactivity=0 HMIS-ratings(scale0-4) HEALTH FIRE REACTIVITY210 Health=2 Fire=1 Reactivity=0 HMISLongTermHealthHazardSubstancesNoneof theingredientsislisted.( )Page3/11 SafetyDataSheetaccordingto1907/2006/EC(R EACH),1272/2008/EC(CLP), :PentofrostA3( ) ResultsofPBTandvPvBassessment PBT:Notapplicable.

3 Description:Mixtureofsubstanceslistedbel owwithnonhazardousadditions. Dangerouscomponents:CAS:7732-18-5 EINECS:231-791-2water,distilled,conducti vityorofsimilarpurity50-100%CAS:107-21-1 EINECS:203-473-3 ,H30225-50%CAS:111-46-6 EINECS:203-872-2 Indexnumber:603-140-00-62,2' ,H302<10%CAS:1310-58-3 EINECS:215-181-3 Indexnumber:019-002-00-8potassiumhydroxi deCR35; , ,H302<0,5% Generalinformation:Symptomsofpoisoningma yevenoccurafterseveralhours;thereforemed icalobservationforatleast48hoursafterthe accident. Afterinhalation:Supplyfreshair;consultdo ctorincaseofcomplaints. ,consultadoctor. ,consultadoctor. ;callformedicalhelpimmediately. ,bothacuteanddelayedCrampThirstHeadacheD izziness( )Page4/11 SafetyDataSheetaccordingto1907/2006/EC(R EACH),1272/2008/EC(CLP), :PentofrostA3( ) HazardsNofurtherrelevantinformationavail able.

4 ' thyl , Suitableextinguishingagents:Usefireextin guishingmethodssuitabletosurroundingcond itions. Forsafetyreasonsunsuitableextinguishinga gents:None. , :Donotallowtoentersewers/surfaceorground water. :Absorbwithliquid-bindingmaterial(sand,d iatomite,acidbinders,universalbinders,sa wdust). Informationaboutfire-andexplosionprotect ion:Nospecialmeasuresrequired.( )Page5/11 SafetyDataSheetaccordingto1907/2006/EC(R EACH),1272/2008/EC(CLP), :PentofrostA3( ) ,includinganyincompatibilities Storage: Requirementstobemetbystoreroomsandrecept acles:Nospecialrequirements. Furtherinformationaboutstorageconditions :Storeincool,dryconditionsinwellsealedre ceptacles. (s) Additionalinformationaboutdesignoftechni calfacilities:Nofurtherdata;seeitem7.

5 Ingredientswithlimitvaluesthatrequiremon itoringattheworkplace:107-21-1ethanediol IOELV(EU)Short-termvalue:104mg/m ,40ppmLong-termvalue:52mg/m ,20ppmSkinTLV(USA)Short-termvalue:C100mg /m HEL(Canada)Short-termvalue:C100*20**mg/m ,C50**ppmLong-termvalue:10**mg/m *Aerosol;**Particulate;**Vapour111-46-62 ,2'-oxybisethanolWEEL(USA)Long-termvalue :10mg/m 1310-58-3potassiumhydroxideREL(USA)Long- termvalue:C2mg/m TLV(USA)Short-termvalue:C2mg/m EL(Canada)Short-termvalue:C2mg/m DNELsNofurtherrelevantinformationavailab le. PNECsNofurtherrelevantinformationavailab le. Additionalinformation:Thelistsvaliddurin gthemakingwereusedasbasis. Personalprotectiveequipment: , ( )Page6/11 SafetyDataSheetaccordingto1907/2006/EC(R EACH),1272/2008/EC(CLP), :PentofrostA3( ) ,respiratoryprotectionmaybeadvisable.

6 Protectionofhands:ProtectiveglovesTheglo vematerialhastobeimpermeableandresistant totheproduct/ ,ratesofdiffusionandthedegradation. MaterialofglovesTheselectionofthesuitabl eglovesdoesnotonlydependonthematerial, ,theresistanceoftheglovematerialcannotbe calculatedinadvanceandhasthereforetobech eckedpriortotheapplication. PenetrationtimeofglovematerialTheexactbr eakthroughtimehastobefoundoutbythemanufa ctureroftheprotectiveglovesandhastobeobs erved. Forthepermanentcontactglovesmadeofthefol lowingmaterialsaresuitable:Butylrubber,B RNeopreneglovesNitrilerubber,NBR Eyeprotection:Safetyglasses Limitationandsupervisionofexposureintoth eenvironmentNofurtherrelevantinformation available. GeneralInformation Appearance:Form:LiquidColour:Blue Odour:Light Odourthreshold:Notdetermined.

7 ( )Page7/11 SafetyDataSheetaccordingto1907/2006/EC(R EACH),1272/2008/EC(CLP), :PentofrostA3( ) pH-valueat20 C:7,9(50parcent) ChangeinconditionMeltingpoint/ :173 C Flashpoint:129 C Flammability(solid,gaseous):Notapplicabl e. Ignitiontemperature:>260 C Decompositiontemperature:Notdetermined. Self-igniting:Productisnotself-igniting. Dangerofexplosion:Productdoesnotpresenta nexplosionhazard. Explosionlimits:Lower:3,2 Vol%Upper:53,0 Vol% Vapourpressureat20 C:0,1hPa Densityat20 C:1,14g/cm RelativedensityNotdetermined. VapourdensityNotdetermined. EvaporationrateNotdetermined. Solubilityin/Miscibilitywithwater:Fullym iscible. Partitioncoefficient(n-octanol/water):No tdetermined. Viscosity: :Notdetermined.

8 Solventcontent:Organicsolvents:Notdeterm ined. Thermaldecomposition/conditionstobeavoid ed:Nodecompositionifusedandstoredaccordi ngtospecifications. ( )Page8/11 SafetyDataSheetaccordingto1907/2006/EC(R EACH),1272/2008/EC(CLP), :PentofrostA3( ) Acutetoxicity: LD/LC50valuesrelevantforclassification:1 07-21-1ethanediolOralLD505840mg/kg(rat)D ermalLD509530mg/kg(rabbit) Primaryirritanteffect: ontheskin:Slightirritanteffectonskinandm ucousmembranes. ontheeye:Irritatingeffect. Sensitization:Nosensitizingeffectsknown. Subacutetochronictoxicity:Vapourshavenar coticeffect. Additionaltoxicologicalinformation:Thepr oductshowsthefollowingdangersaccordingto thecalculationmethodoftheGeneralEUClassi ficationGuidelinesforPreparationsasissue dinthelatestversion:HarmfulIrritantToxic and/orcorrosiveeffectsmaybedelayedupto24 hours.

9 Aquatictoxicity:Nofurtherrelevantinforma tionavailable. Additionalecologicalinformation: (GermanRegulation)(Self-assessment):slig htlyhazardousforwaterDonotallowundiluted productorlargequantitiesofittoreachgroun dwater,watercourseorsewagesystem. PBT:Notapplicable. vPvB:Notapplicable.( )Page9/11 SafetyDataSheetaccordingto1907/2006/EC(R EACH),1272/2008/EC(CLP), :PentofrostA3( ) Uncleanedpackaging: Recommendation:Disposalmustbemadeaccordi ngtoofficialregulations. Recommendedcleansingagents:Water, DOT,ADR,ADN,IMDG,IATAN/A DOT,ADR,ADN,IMDG,IATAN/A (es) DOT,ADR,ADN,IMDG,IATA ClassN/A DOT,ADR,IMDG,IATAN/A : Marinepollutant:No UN"ModelRegulation":-( )Page10/11 SafetyDataSheetaccordingto1907/2006/EC(R EACH),1272/2008/EC(CLP), :PentofrostA3( ) ,healthandenvironmentalregulations/legis lationspecificforthesubstanceormixture UnitedStates(USA) SARA Section355(extremelyhazardoussubstances) :Noneoftheingredientsislisted.

10 Section313(Specifictoxicchemicallistings ):107-21-1ethanediol TSCA(ToxicSubstancesControlAct):Allingre dientsarelisted. Proposition65(California): Chemicalsknowntocausecancer:Noneoftheing redientsislisted. Chemicalsknowntocausereproductivetoxicit yforfemales:Noneoftheingredientsislisted . Chemicalsknowntocausereproductivetoxicit yformales:Noneoftheingredientsislisted. Chemicalsknowntocausedevelopmentaltoxici ty:Noneoftheingredientsislisted. CarcinogenicCategories EPA(EnvironmentalProtectionAgency)Noneof theingredientsislisted. IARC(InternationalAgencyforResearchonCan cer)Noneoftheingredientsislisted. TLV(ThresholdLimitValueestablishedbyACGI H)107-21-1ethanediolA4 NIOSH-Ca(NationalInstituteforOccupationa lSafetyandHealth)Noneoftheingredientsisl isted.