Page 1/7 Safety data sheet according to …

1 Page 1/7 Safety data sheetaccording to 1907/ 2006 /EC, article 31 Printing date : number * SECTION 1: Identification of the substance/mixture and of the company/undertaking Product identifier Trade name: Zircate Prophy Paste Relevant identified uses of the substance or mixture and uses advised against Application of the substance / the mixtureTooth cleanserPolishing paste Uses advised againstNo further relevant information available. Details of the supplier of the Safety data sheet Manufacturer/Supplier:DENTSPLY DeTrey GmbHDe-Trey-Str. 1D-78467 KonstanzGERMANYTel.

2 : +49-(0)7531-583-0 Fax: +49-(0)7531-583-104email: Further information obtainable from:- Departement Research & Development for technical information- Departement Marketing & Sales for distribution of the Safety data sheets Emergency telephone number:+49-(0)7531-583-0 8:00 - 17:00 (GMT + 1:00)* SECTION 2: Hazards identification Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Acute Tox. 4 H332 Harmful if Irrit. 2 H315 Causes skin Irrit. 2H319 Causes serious eye SE 3H335 May cause respiratory irritation.

3 Label elements Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. Hazard pictogramsGHS07 Signal wordWarning Hazard-determining components of labelling:Zizconium Silicate Hazard statementsH332 Harmful if Causes skin Causes serious eye May cause respiratory irritation. Precautionary statementsP261 Avoid breathing dust/fume/gas/mist/ protective gloves/protective clothing/eye protection/face +P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, ifpresent and easy to do.

4 Continue treatment (see on this label).P405 Store locked of contents/container in accordance with local/regional/national/internationalreg ulations.(Contd. on page 2) GB Page 2/7 Safety data sheetaccording to 1907/ 2006 /EC, article 31 Printing date : number 4 Trade name: Zircate Prophy Paste(Contd. of page 1) Additional information:As this product is a medical device in the meaning of Directive 93/42/EEC and intended for use by the endconsumer and is applied in an invasive manner or body contact, it is exempt from the labelling requirementsaccording to regulation 1272/2008.

5 Other hazards Results of PBT and vPvB assessment PBT:Not applicable. vPvB:Not applicable.* SECTION 3: Composition/information on ingredients Chemical characterisation: Mixtures Description:Mixture of substances listed below with nonhazardous additions. Dangerous components:CAS: 10101-52-7 Zizconium Silicate Acute Tox. 4, H332; Skin Irrit. 2, H315; Eye Irrit. 2, H319; STOT SE 3,H33550-100%CAS: 18282-10-5 EINECS: 242-159-0tin dioxidesubstance with a Community workplace exposure <10%CAS: 56-81-5 EINECS: 200-289-5glycerolsubstance with a Community workplace exposure <10% Additional informationFor the wording of the listed hazard phrases refer to section 4: First aid measures Description of first aid measures After inhalationSupply fresh air; consult doctor in case of complaints.

6 After skin contactImmediately wash with water and soap and rinse with warm water. After eye contactRinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. After swallowingIf symptoms persist consult out mouth and then drink plenty of water. Most important symptoms and effects, both acute and delayedNo further relevant information available. Information for doctorNo further relevant information available. Indication of any immediate medical attention and special treatment neededNo further relevant information 5: Firefighting measures Extinguishing media Suitable extinguishing agentsCO2, powder or water spray.

7 Fight larger fires with water spray or alcohol resistant foam. For Safety reasons unsuitable extinguishing agentsWater with full jet. Special hazards arising from the substance or mixtureNo further relevant information available. Advice for firefighters Protective equipment:Self-contained respiratory protective 6: Accidental release measures Personal precautions, protective equipment and emergency proceduresWear protective clothing. Environmental precautions:Do not allow to enter sewers/ surface or ground water.(Contd. on page 3) GB Page 3/7 Safety data sheetaccording to 1907/ 2006 /EC, article 31 Printing date : number 4 Trade name: Zircate Prophy Paste(Contd.)

8 Of page 2) Methods and material for containment and cleaning up:Ensure adequate up mechanically. Reference to other sectionsSee Section 7 for information on safe handlingSee Section 8 for information on personal protection Section 13 for disposal 7: Handling and storage Precautions for safe handlingObserve normal care for working with chemicals. HandlingProduct is intended for dental use only. Information about fire - and explosion protection:No special measures required. Conditions for safe storage, including any incompatibilities Storage Requirements to be met by storerooms and receptacles:Store only in the original receptacle.

9 Information about storage in one common storage facility:Not required. Further information about storage conditions:Keep receptacle tightly sealed. Specific end use(s)No further relevant information available.* SECTION 8: Exposure controls/personal protection Additional information about design of technical facilities:No further data ; see item 7. Control parameters Ingredients with limit values that require monitoring at the workplace:CAS: 18282-10-5 tin dioxideWEL Short-term value: 4 mg/m Long-term value: 2 mg/m as SnCAS: 56-81-5 glycerolWEL Long-term value: 10 mg/m Regulatory informationWEL: EH40/2011 Additional information:The lists valid during the making were used as basis.

10 Exposure controls Personal protective equipment General protective and hygienic measuresKeep away from foodstuffs, beverages and remove all soiled and contaminated clothingWash hands before breaks and at the end of contact with the eyes and skin. Respiratory protection:In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposureuse self-contained respiratory protective necessary if room is well-ventilated. Protection of hands:Protective glove material has to be impermeable and resistant to the product/ the substance/ the to missing tests no recommendation to the glove material can be given for the product/ the preparation/the chemical mixture.